Effect of sterilization on non-woven polyethylene terephthalate fiber structures for vascular grafts

Non-woven polyethylene terephthalate (PET) fibers produced via melt blowing and compounded into a 6 mm diameter 3D tubular scaffold were developed with artery matching mechanical properties. This work compares the effects of ethylene oxide (EtO) and low temperature plasma (LTP) sterilization on PET surface chemistry and biocompatibility. As seen through X-ray photoelectron spectroscopy (XPS) analysis, LTP sterilization led to an increase in overall oxygen content and the creation of new hydroxyl groups. EtO sterilization induced alkylation of the PET polymer. The in vitro cytotoxicity showed similar fibroblastic viability on LTP- and EtO-treated PET fibers. However, TNF-α release levels, indicative of macrophage activation, were significantly higher when macrophages were incubated on EtO-treated PET fibers. Subcutaneous mice implantation revealed an inflammatory response with foreign body reaction to PET grafts independent of the sterilization procedure.     

Micellization Process in Poly(Ether Urethane) Solutions

Poly(ether urethane)s containing different hard segments were investigated by viscometry, fluorescence spectra, polarizing optical microscopy, and scanning electron microscopy. The polarity dependence of the vibrational structure of the pyrene emission spectrum indicated the formation of aggregates at concentrations that are significantly below the critical concentrations that define the separation of dilute‐semidilute domains. Unlike the sample with 4,4'‐methylene diphenylene diisocyanate, the sample with 2,4‐tolylene diisocyanate in hard segments gives a fluorescence spectra in which the pyrene excimer appears. Supermolecular structures associated with the form of spherulites or of spherical micelles were detected by scanning electron microscopy. The results are discussed in correlation with viscometric data and optical microscopy.     

Thermal behavior,decomposition mechanism by TG/MS/FTIR technique and theoretical study of some symmetric and asymmetric bent-core liquid crystals based on 2,7-dihydroxynaphthalene

Journal of Thermal Analysis and Calorimetry - The thermal stability of some symmetric and asymmetric bent-core liquid crystals derived from 2,7-dihydroxynaphthalene as well as the degradation...     

Comment on the paper “Contribution to the stability analysis of the dewetted Bridgman growth under microgravity conditions”

New considerations of the stability problem of dewetting, as addressed in the initial paper [Cryst. Res. Technol. 39 , 491 (2004)], show that, in the most general case, when dewetting occurs in microgravity it is necessarily stable. This explains why the phenomenon has been observed so many times during solidification of semiconductors in space. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Detection of Allergenic Lysozyme during Winemaking with an Electrochemical Aptasensor

In this work we investigate the performance of a simple, disposable electrochemical aptasensor for lysozyme and its usefulness for monitoring the allergen risk along wine production. The sensor relies on screen‐printed gold electrodes modified with gold nanoparticles as the electrochemical transducer, with detection by cyclic voltammetry. This simple method is characterized by a detection limit of 0.32 μg.mL^?1 lysozyme and a linear range of 1–10 μg.mL^?1, being appropriate for the analysis of lysozyme‐treated wines. Several white wines where sulphur dioxide was partially replaced by lysozyme were produced and analyzed with the aptasensor at critical stages during wine production. The results obtained with the aptasensor were moreover compared with those recorded in parallel by a standard method, high performance liquid chromatography (HPLC). The specific advantages brought by the use of nanomaterial and the limitations of the sensor are discussed. The sensor allowed evaluating the effect of various technological steps along wine production on the content of lysozyme.     

A Class of Multiplicative Lattices

Czechoslovak Mathematical Journal - We study the multiplicative lattices L which satisfy the condition a = (a : (a : b))(a : b) for all a, b ∈ L. Call them sharp lattices. We prove that every...     

Bank productivity and performance groups: A decomposition approach based upon the Luenberger productivity indicator

The purpose of this paper is twofold. First, in the framework of the strategic groups’ literature, it analyZes changes in productivity and efficiency of Spanish private and savings banks over an eight-year period (1998-2006). Second, by adapting the decomposition of the Malmquist productivity indices suggested by Färe et al. (1994), it proposes similar components decomposing the Luenberger productivity indicator. Initially, productivity is decomposed into technological and efficiency changes. Thereafter, this efficiency change is decomposed into pure efficiency, scale and congestion changes. Empirical results demonstrate that productivity improvements are partially due to technological innovation. Furthermore, it is shown how the competition between private and savings banks develops in terms of the analyzed productivity and efficiency components. While private banks enjoy better efficiency change, savings banks contribute more to technological progress. Consequently, the Luenberger components are used as cluster analysis inputs. Thus, economic interpretations of the resulting performance groups are made via key differences in productivity components. Finally, following the strategic groups’ literature, supplementary insights are gained by linking these performance groups with banking ratios.     

Photo-degradation of yperite over V, Fe and Mn-doped titania-silica photocatalysts

The photocatalytic decomposition of yperite (bis(2-chloroethyl)sulfide), a chemical warfare agent, was achieved by using titania-silica catalysts doped with several transition metal ions. The preparation of these catalysts was achieved by impregnation of a titania-silica mixed oxide previously synthesized using a sol-gel route with salts of the doping elements (vanadium, iron, manganese). The above catalysts were characterized using several spectroscopic techniques: FTIR, Raman, DR-UV-Vis, and XPS. The band gap energy was measured for each photocatalytic system. The reaction was carried out in two different types of reactors, i.e. naturally aerated and a closed quartz tube aerated under a constant flow, and using two types of irradiation, UV-Vis and Vis. The investigated systems proved to be extremely active, leading to an almost complete degradation of yperite in 2 h of irradiation. An excellent correlation between the photocatalytic performances and the band gap has been found. Based on the characterization data and on the temporal evolution of the reaction products, a reaction mechanism has been suggested. This mechanism considers two distinct pathways for the decomposition of yperite, namely the C-S bond cleavage and the S oxidation.