全文获取类型
收费全文 | 1841篇 |
免费 | 47篇 |
国内免费 | 15篇 |
专业分类
化学 | 1120篇 |
晶体学 | 5篇 |
力学 | 49篇 |
数学 | 425篇 |
物理学 | 304篇 |
出版年
2023年 | 13篇 |
2022年 | 19篇 |
2021年 | 40篇 |
2020年 | 37篇 |
2019年 | 26篇 |
2018年 | 23篇 |
2017年 | 20篇 |
2016年 | 61篇 |
2015年 | 36篇 |
2014年 | 41篇 |
2013年 | 91篇 |
2012年 | 78篇 |
2011年 | 147篇 |
2010年 | 73篇 |
2009年 | 54篇 |
2008年 | 104篇 |
2007年 | 106篇 |
2006年 | 102篇 |
2005年 | 65篇 |
2004年 | 60篇 |
2003年 | 64篇 |
2002年 | 40篇 |
2001年 | 17篇 |
2000年 | 21篇 |
1999年 | 16篇 |
1998年 | 18篇 |
1997年 | 22篇 |
1996年 | 23篇 |
1995年 | 17篇 |
1994年 | 27篇 |
1993年 | 26篇 |
1992年 | 15篇 |
1991年 | 9篇 |
1990年 | 14篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 12篇 |
1985年 | 18篇 |
1984年 | 14篇 |
1983年 | 14篇 |
1982年 | 17篇 |
1981年 | 18篇 |
1980年 | 16篇 |
1979年 | 15篇 |
1978年 | 13篇 |
1977年 | 8篇 |
1976年 | 8篇 |
1974年 | 9篇 |
1973年 | 8篇 |
1904年 | 10篇 |
排序方式: 共有1903条查询结果,搜索用时 15 毫秒
1.
2.
S. Mancini D. Vitali V. Giovannetti P. Tombesi 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,22(3):417-422
We show that the optomechanical coupling between an optical cavity mode and two movable cavity mirrors is able to entangle
two different macroscopic oscillation modes of the mirrors. This continuous variable entanglement is maintained by the light
bouncing between the mirrors and is robust against thermal noise. In fact, it could be experimentally demonstrated using present
technology.
Received 2 September 2002 / Received in final form 10 October 2002 Published online 7 January 2003 相似文献
3.
Gottfried Mayer Vitali Vogel Bas G. G. Lohmeijer Jean‐Franois Gohy Jacomina A. Van Den Broek Winfried Haase Ulrich S. Schubert Dieter Schubert 《Journal of polymer science. Part A, Polymer chemistry》2004,42(17):4458-4465
Micelles prepared from amphiphilic block copolymers in which a poly(styrene) segment is connected to a poly(ethylene oxide) block via a bis‐(2,2′:6′,2″‐terpyridine‐ruthenium) complex have been intensely studied. In most cases, the micelle populations were found to be strongly heterogeneous in size because of massive micelle/micelle aggregation. In the study reported in this article we tried to improve the homogeneity of the micelle population. The variant preparation procedure developed, which is described here, was used to prepare two “protomer”‐type micelles: PS20‐[Ru]‐PEO70 and PS20‐[Ru]‐PEO375. The dropwise addition of water to a solution of the compounds in dimethylformamide was replaced by the controlled addition of water by a syringe pump. The resulting micelles were characterized by sedimentation velocity and sedimentation equilibrium analyses in an analytical ultracentrifuge and by transmission electron microscopy of negatively stained samples. Sedimentation analysis showed virtually unimodal size distributions, in contrast to the findings on micelles prepared previously. PS20‐[Ru]‐PEO70 micelles were found to have an average molar mass of 318,000 g/mol (corresponding to 53 protomers per micelle, which is distinctly less than after micelle preparation by the standard method) and an average hydrodynamic diameter (dh) of 18 nm. For PS20‐[Ru]‐PEO375 micelles, the corresponding values were M = 603,000 g/mol (31 protomers per micelle) and dh = 34 nm. The latter particles were found to be identical to the “equilibrium” micelles prepared in pure water. Both micelle types had a very narrow molar mass distribution but a much broader distribution of s values and thus of hydrodynamic diameters. This indicates a conformational heterogeneity that is stable on the time scale of sedimentation velocity analysis. The findings from electron microscopy were in disagreement with those from the sedimentation analysis both in average micelle diameter and in the width of the distributions, apparently because of imperfections in the staining procedure. The preparation procedure described also may be useful in micelle formation from other types of protomers. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4458–4465, 2004 相似文献
4.
Daniele Cauzzi Roberto Giordano Enrico Sappa Antonio Tiripicchio Marisa Tiripicchio Camellini 《Journal of Cluster Science》1993,4(3):279-296
The title complex (complex1) was the first alkyne-substituted triruthenium dihydrido cluster to be reported and was characterized by spectroscopy as a triangular cluster with the alkyne parallel to a Ru-Ru edge. Recently, we have found that1 is a key intermediate in the homogeneous hydrogenation of diphenylacetylene catalyzed by tetrahedral Ru4 and FeRu3 clusters. Since the discovery of1, a great number of complexes with alkynes parallel to a cluster edge have been reported; at present this is the more common bonding mode for alkynes on trinuclear clusters. The structural features of1 allow a comparison with those of other ruthenium-containing derivatives and help to draw suggestions of the role of1 in hydrogenation catalysis. 相似文献
5.
4-Vinylphenols, useful compounds for industrial applications, were obtained by decarboxylation of 4-hydroxycinnamic acids under microwave irradiation in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as base and basic aluminum oxide as solid support. The reactions were fast (15-30 min). The selective extraction of the final products with ethyl acetate avoids chromatographic purifications. The conversions are quantitative and the yields are satisfactory. Only the unstable 4-vinylcatechol was obtained in moderate yield. This procedure was successfully extended to a natural sample of ferulic acid extracted from wheat bran to get the corresponding 4-vinylguaiacol, a FEMA GRAS (Flavor and Extract Manufacturer's Association; General Regarded as Safe) approved flavoring agent. 相似文献
6.
Nicola Arcozzi Enrico Casadio Tarabusi Fausto Di Biase Massimo A. Picardello 《Transactions of the American Mathematical Society》2006,358(6):2781-2798
We establish a potential theoretic approach to the study of twist points in the boundary of simply connected planar domains.
7.
Gabor Schmera Adi Bulsara David Pierson Frank Moss Enrico Di Cera 《Journal of statistical physics》1993,71(5-6):1179-1190
We consider the class of experiments which can be characterized by a Fokker-PIanck dynamics corresponding to the overdamped motion of a state point in a suitable stochastic potential. We assume that the general form of the potential is known (or can be guessed with reasonable accuracy), but that its parameters are to be determined experimentally by measurements made with a noisy instrument. This possible method for determining the potential parameters, which exploits the system's own internal stochastic motion in order to explore rapidly its available parameter space, is substantially more efficient than traditional methods involving time averages of single point measurements, and yet does not appear to have been previously considered. The method could be important when, for example, the experiment must be completed in a limited time owing either to the expense of the experimental materials or to the temporary stationarity of the preparation, situations which are commonly encountered in experimental biochemistry and biology. 相似文献
8.
9.
Giovanni Tartarini Alessandra Lena Davide Passaro Lorenzo Rosa Stefano Selleri Pier Faccin Enrico Maria Fabbri 《Optical and Quantum Electronics》2006,38(9-11):869-876
A comprehensive numerical tool has been developed for the evaluation of the performances of Radio over Fiber (RoF) links intended for wireless signal distribution.At the transmitter end an appropriate set of rate equations allows to model the optical source as a solitary laser or as an appropriately injection locked laser. The optical channel is modeled putting into account the combined effect of fiber dispersion, laser source non ideal performances (e.g. non-linear effects, frequency chirp), and quadratic detection of the receiving photodiode. The simulation model developed can be a useful tool at the design stage allowing a preliminary evaluation of the characteristics of real RoF links. 相似文献
10.
Maria Benedetta Fadda Nicoletta Curreli Raffaello Pompei Antonio Rescigno Augusto Rinaldi Enrico Sanjust 《Applied biochemistry and biotechnology》1994,44(3):263-270
A highly active thermostable β-glucosidase was purified to homogeneity from a strain ofTrichoderma sp. The enzyme was an extracellular glycoprotein and showed hydrolytic activity toward several β-glucosides.
Cellobiose was found to be the substrate of choice for this enzyme. This finding could suggest future technological applications
of the purified protein. 相似文献