全文获取类型
收费全文 | 112篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 72篇 |
晶体学 | 1篇 |
力学 | 9篇 |
数学 | 15篇 |
物理学 | 18篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2020年 | 1篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 3篇 |
2014年 | 2篇 |
2013年 | 3篇 |
2011年 | 5篇 |
2010年 | 5篇 |
2009年 | 7篇 |
2008年 | 5篇 |
2007年 | 8篇 |
2006年 | 8篇 |
2005年 | 4篇 |
2004年 | 10篇 |
2003年 | 5篇 |
2002年 | 3篇 |
2001年 | 1篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1975年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1939年 | 3篇 |
1937年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有115条查询结果,搜索用时 15 毫秒
1.
A parallel method for time discretization of parabolic equations based on Laplace transformation and quadrature 总被引:5,自引:0,他引:5
We consider the discretization in time of an inhomogeneous parabolicequation in a Banach space setting, using a representation ofthe solution as an integral along a smooth curve in the complexleft half-plane which, after transformation to a finite interval,is then evaluated to high accuracy by a quadrature rule. Thisreduces the problem to a finite set of elliptic equations withcomplex coefficients, which may be solved in parallel. The paperis a further development of earlier work by the authors, wherewe treated the homogeneous equation in a Hilbert space framework.Special attention is given here to the treatment of the forcingterm. The method is combined with finite-element discretizationin spatial variables. 相似文献
2.
Model compounds have been used in studies at 60° in connection with transfer to polymer during the copolymerization of vinyl acetate with esters of fumaric acid. Succinate esters were used to simulate the fumarate ester units and ethyl acetate the vinyl acetate units in the copolymers. The succinate esters are much more reactive than ethyl acetate in transfer reactions with polyvinyl acetate radicals. Methyl isobutyrate and methyl propionate were also examined to assess the difference in reactivity in transfer of tertiary and secondary hydrogen atoms. It is concluded that branching is a very important reaction in the preparation of high conversion copolymers of fumarate esters with vinyl acetate. 相似文献
3.
Ju-Chun Huang Chien Hong Cheng Shyang Roeng Sheen Zhi Ling Lee Chien Ming Lei Maw Kuen Wu 《中国化学会会志》1996,43(2):139-143
The synthesis of bulk Y2Ba4Cu7O15-δ superconductor at atmospheric oxygen pressure via solid state sintering is reported. Temperature ranging from 860 to 890 °C as well as time interval over 2 to 15 days were used to investigate the formation of the Y2Ba4Cu7O15-δ phase. A time-temperature profile characterizing the conditions for the preparation of Y2Ba4Cu7O15-δ phase suggests the optimal condition to be sintering at 890 °C for over 10 days. Detailed results of X-ray diffraction, electrical resistivity, iodometric titration and magnetization measurements are described. 相似文献
4.
S. H. Sheen J. G. Skofronick C. R. Mueller 《International journal of quantum chemistry》1975,9(5):817-824
The effects of orbiting resonances on elastic differential cross sections are investigated for the Lennard-Jones (12, 6) model potential. The elastic differential cross section consists of three terms: a resonance term, a potential scattering term and an interference term. The interference term has a significant effect only at small angles of the differential cross section. The importance of the potential scattering term depends proportionally upon the orbiting resonance energy. For the low-lying orbiting resonance states, the resonance term is the dominant term, but at higher energy it appears only in the backward differential cross sections. Generally, by fitting the large angle differential cross sections, the resonance orbital angular momentum can be estimated. 相似文献
5.
6.
Selective Growth and Structural Analysis of Regular MnO Nanooctapods Bearing Multiple High‐Index Surface Facets
下载免费PDF全文
![点击此处可从《化学:亚洲杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Although numerous morphologies of MnO nanostructures have been reported, an exact structural analysis and mechanistic study has been lacking. In the present study, the formation of regular MnO octapods was demonstrated in a simple procedure, comprising the thermal decomposition of manganese oleate. Because of their structural uniformity, an ideal three‐dimensional model was successfully constructed. The eight arms protruded from the cubic center with tip angles of 38° and surface facets of {311} and {533} with rounded edges. The concentrations of oleate and chloride ions were the determining factors for the octapod formation. Selective coordination of the oleate ions to the {100} faces led to edge growth along the <111> direction, which was then limited by the chloride ions bound to the high‐index surface facets. These structural and mechanistic analyses should be helpful for understanding the complex nanostructures and for tuning their structure‐related properties. 相似文献
7.
The total synthesis and evaluation of three key ramoplanin aglycon analogues are detailed. The first (5a) represents replacement of the labile depsipeptide ester with a stable amide (HAsn2 --> Dap2) with removal of the HAsn pendant carboxamide, and it was found to be slightly more potent than the natural aglycon in antimicrobial assays providing a new lead structure with an improved profile and a more stable and accessible macrocyclic template on which to conduct structure-function studies. In contrast, a second amide analogue 5b which contains a single additional methylene relative to 5a (HAsn2 --> Dab2) was found to be inactive in antimicrobial assays (>100-fold loss in activity). The third key analogue 5c in which the Asn1 lipid side chain was replaced with an acetyl group revealed that it contributes significantly to the antimicrobial activity (16-fold) of the ramoplanins, but is not essential. 相似文献
8.
Growth of poly(pseudorotaxane) on gold using host-stabilized charge-transfer interaction 总被引:1,自引:0,他引:1
A novel supramolecular polymer (poly(pseudorotaxane)) in which the repeating units are linked by host-stabilized charge-transfer interaction between the guest molecules is grown on gold and characterized. 相似文献
9.
We treat the time discretization of an initial-value problem for a homogeneous abstract parabolic equation by first using a representation of the solution as an integral along the boundary of a sector in the right half of the complex plane, then transforming this into a real integral on the finite interval , and finally applying a standard quadrature formula to this integral. The method requires the solution of a finite set of elliptic problems with complex coefficients, which are independent and may therefore be done in parallel. The method is combined with spatial discretization by finite elements.
10.
J. C. Huang C. H. Cheng Y. F. Chen S.R. Sheen Z. L. Lee H. Y. Shao M. K. Wu 《中国化学会会志》1999,46(2):173-178
A highly homogeneous and nearly monophasic PrBa2Cu4O8 compound has been synthesized at 1 atm of oxygen via a route employing polymeric ethylenediamine/citric acid precursors. The PrBa2Cu4O8 compound with a trace amount of BaCuO2 was synthesized for the first time by sintering the pellets at the temperature of 875 °C under ambient oxygen pressure. The temperature coefficient of the resistivity is positive below 190 K while above 190 K is negative. The superconducting transition was not detected down to 4.2 K. Samples were characterized by X-ray diffraction, scanning electron microscopy, thermal analysis, and transport and magnetic measurements. 相似文献