全文获取类型
收费全文 | 642篇 |
免费 | 41篇 |
国内免费 | 8篇 |
专业分类
化学 | 428篇 |
晶体学 | 3篇 |
力学 | 36篇 |
数学 | 118篇 |
物理学 | 106篇 |
出版年
2023年 | 5篇 |
2022年 | 20篇 |
2021年 | 35篇 |
2020年 | 20篇 |
2019年 | 11篇 |
2018年 | 12篇 |
2017年 | 13篇 |
2016年 | 31篇 |
2015年 | 24篇 |
2014年 | 20篇 |
2013年 | 45篇 |
2012年 | 51篇 |
2011年 | 59篇 |
2010年 | 32篇 |
2009年 | 24篇 |
2008年 | 41篇 |
2007年 | 41篇 |
2006年 | 39篇 |
2005年 | 25篇 |
2004年 | 17篇 |
2003年 | 39篇 |
2002年 | 12篇 |
2001年 | 9篇 |
2000年 | 4篇 |
1999年 | 8篇 |
1998年 | 7篇 |
1997年 | 4篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 6篇 |
1986年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1923年 | 1篇 |
排序方式: 共有691条查询结果,搜索用时 21 毫秒
1.
Fabiano Severo Rodembusch Ndya Pesce da Silveira Dimitrios Samios Leandra Franciscato Campo Valter Stefani 《Journal of Polymer Science.Polymer Physics》2003,41(4):341-350
The solution behavior of new copolymers of methyl methacrylate and benzazole dyes emitting fluorescence because of an intramolecular proton‐transfer mechanism in the electronically excited state has been investigated by static light scattering, fluorescence spectroscopy, ultraviolet–visible, and gel permeation chromatography. In the dilute regime, with tetrahydrofuran (THF) and chloroform as solvents, the copolymers behave as typical polydisperse linear chains in good solvents. The analysis of the osmotic modulus for concentrated solutions in THF (c ≥ 60 g L?1) indicates the existence of an interchain association mechanism. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 341–350, 2003 相似文献
2.
Dimitrios Tsikas Frank-Mathias Gutzki Jürgen C. Frölich 《Fresenius' Journal of Analytical Chemistry》1992,342(1-2):95-97
Summary A reversed-phase HPLC method for the determination of nitrite and nitrate in aqueous solutions, biological buffers and human urine is described. The method is based on the conversion of nitrite and nitrate into their 1-nitro-2,4,6-trimethoxybenzene (NTBM) derivatives by using 1,3,5-trimethoxybenzene and concentrated sulphuric acid. NTMB is extracted by benzene, the solvent evaporated, the residue reconstructed in methanol/water (3/4, v/v) and subsequently analyzed by reversed-phase HPLC and UV detection (360 nm). The specificity of the nitration reaction, good reproducibility (C.V. 6.2%) and high sensitivity (8.4 ng nitrite) show the applicability of this method to the quantitative analysis of nitrite and nitrate in several matrices including human urine. 相似文献
3.
Summary A reversed-phase high-performance liquid chromatographic (RP-HPLC) method with UV detection (270 nm) for the determination of nitrite as its pentafluorobenzyl derivative with and without ion-pair extraction is described. Ion-pair extraction of nitrite from aqueous solutions was performed by using a 1 mol/l solution of the liquid ion exchanger methyltrioctylammonium chloride in toluene. The residue of the ion-pair extraction or an aliquot of an aqueous nitrite solution or of a biological fluid (100 l) were treated with 400 l of acetone and 10 l of pentafluorobenzyl bromide. Nitrite was converted into its pentafluorobenzyl derivative by heating at 50°C for 90 min. After evaporation of acetone the aqueous phases were diluted with 100 to 400 l of methanol, and up to 100 l were injected into the RP-HPLC system. The method allows accurate analysis of nitrite in the presence of nitrate directly in aqueous solutions and biological fluids in concentrations down to 2.0 mg/l. The method is also applicable to the determination of nitrate following its reduction to nitrite by cadmium. 相似文献
4.
A capillary gas chromatographic method is described for the quantitative determination of liquid paraffin in blood. Paraffin is extracted from blood into n-heptane. After solvent evaporation and dissolution of the residue in 100–200 μl n-heptane one μl is injected into a gas chromatograph fitted with a fused silica capillary column (Permabond® OV-1-CB-0.1, 10 m × 0.32 mm i.d.) and flame ionization detector. Analysis is performed by using an oven program [50°C (3 min)?285°C (5 min), rise 10%min]. The sensitivity (1.5 ng hexadecane) and the reproducibility prove the applicability of the method for the determination of liquid paraffin in blood and for the study of the stability of the liquid paraffin hollow fiber membranes used in an extracorporeal liver support system. 相似文献
5.
Andreadou I Tasouli A Bofilis E Chrysselis M Rekka E Tsantili-Kakoulidou A Iliodromitis E Siatra T Kremastinos DT 《Chemical & pharmaceutical bulletin》2002,50(2):165-168
Novel indole derivatives containing a triazole moiety (1a-d, 2a-c) were synthesized as lead compounds with interesting pharmacological profiles. Their antioxidant activity was investigated on in vitro non-enzymatic rat hepatic microsomal lipid peroxidation. All compounds showed significant effect in the above assay. The effect depended mainly on the attachment position of the triazole moiety on the indole nucleus. The most potent antioxidant derivatives la, 1c and 1d were tested for their protective ability against the oxidative damage of the myocardium after ischemia-reperfusion, in male rabbits which were subjected to 30 min regional ischemia followed by reperfusion. The tested antioxidant compounds 1a, 1c and 1d were continuously infused for 30 min starting at 10th min of ischemia and lasted at 10th min of reperfusion. The concentration of malondialdehyde (MDA, a marker of lipid peroxidation) and hemodynamic parameters (blood pressure and heart rate) were measured in the baseline, at 20th min of the sustained ischemia, 1st and 20th min of reperfusion. It was found that the examined compounds la, 1c and 1d reduced significantly the level of MDA in rabbits under ischemia-reperfusion and proved to be promising substances for further evaluation of anti-ischemic properties. 相似文献
6.
Vilar RB da Silva R Schossler P Cataluña Veses R Piatnicki C Samios D Caramão EB 《Journal of chromatography. A》2003,985(1-2):367-373
This work reports preliminary studies on the characterisation of anhydrous ethanol (AEA) used as an automotive fuel mixed with gasoline in Porto Alegre (South Brazil). Pre-concentration of the impurities contained in 1000 ml of AEA was carried on through solid-phase extraction using XAD4 resin. The main compounds in the extract were identified by means of spectral data from the library of the equipment. The concentrate was then fractionated using a preparative liquid chromatographic column filled with activated silica gel and the elution procedure was carried out with, n-hexane, n-hexane-benzene (1:1, v/v) and dichloromethane. Prior to analysis by GC-MS, each fraction was reduced to 1 ml with a gentle stream of nitrogen. Saturated linear hydrocarbons and aromatic hydrocarbons eluted in the first fraction and oxygenated compounds such as aldehydes. ketones and alcohols, eluted in the second one. were the main compounds detected in the sample. 相似文献
7.
Linear systems whose associated block Jacobi iteration matrixB is weakly cyclic generated by the cyclic permutation = (1,2,...,
p
) in the spirit of Li and Varga are considered. Regions of convergence for the corresponding blockp-cyclic SOR method are derived and the exact convergence domains for real spectra, (B
p
), of the same sign are obtained. Moreover, analytical expressions for two special cases forp = 5 are given and numerical results are presented confirming the theory developed. The tools used for this work are mainly from complex analysis and extensive use of (asteroidal) hypocycloids in the complex plane is made to produce our results.This work was supported in part by AFOSR grant F49620-92-J-0069 and NSF grant 9202536-CCR. 相似文献
8.
Dimitrios P. CatsoulacosBarry R. Steele Georgios A. HeropoulosMaria Micha-Screttas Constantinos G. Screttas 《Tetrahedron letters》2003,44(24):4575-4578
DAB-dendr-(NH2)32 has been modified to produce two novel dendrimeric P,N-ligands, DAB-dendr-[1,2-(NCHC6H4PPh2)]32 and DAB-dendr-[1,2-(NHCH2C6H4PPh2)]32. These were both found to activate electron rich aryl bromides in the Heck reaction. The reactions seem to proceed better in a novel solvent system consisting of an equimolar mixture of a tertiary amine with acetic acid. A marked dependence of the conversion on the [equivalents of dendrimeric ligand]/[Pd] ratio has been observed with conversion decreasing as the ratio of dendrimer equivalents to Pd increases. This phenomenon is attributed to interactions of the arms bearing the metal with neighboring ones within the dendrimer. 相似文献
9.
Analytical methodology was developed and validated for the determination of spiroxamine residues in grapes, must, and wine by gas chromatography/ion trap-mass spectrometry (GC/IT-MS). Two extraction procedures were used: the first involved grapes, must, and wine extraction with alkaline cyclohexane-dichloromethane (9 + 1, v/v) solution, and the second grape extraction with acetone, dichloromethane, and petroleum ether. In both procedures, the extract was centrifuged, evaporated to dryness, and reconstituted in cyclohexane or 2,2,4-trimethylpentane-toluene (9 + 1, v/v), respectively. Spiroxamine diastereomers A and B were determined by GC/IT-MS, and a matrix effect was observed in the case of grapes but not in must and wine. Recovery of spiroxamine from fortified samples at 0.02 to 5.0 mg/kg ranged from 78-102% for grapes and must, with relative standard deviation (RSD) <13%; for red and white wines, recoveries ranged from 90 to 101% with RSD <9%. The limit of quantification was 0.02 mg/kg for grapes, must, and wine or 0.10 mg/kg for grapes, depending on the extraction procedure used. 相似文献
10.
Georgia‐Paraskevi Nikoleli Muhammad Q. Israr Nikolaos Tzamtzis Dimitrios P. Nikolelis Magnus Willander Nikolas Psaroudakis 《Electroanalysis》2012,24(6):1285-1295
The present article describes a miniaturized potentiometric urea lipid film based biosensor on graphene nanosheets. Structural characterization of graphene nanosheets for miniaturization of potentiometric urea lipid film based biosensors have been studied through atomic force microscopy (AFM) and transmission electron microscopy (TEM) measurements. UV‐Vis and Fourrier transform IR (FTIR) spectroscopy have been utilized to study the pre‐ and postconjugated surfaces of graphene nanosheets. The presented potentiometric urea biosensor exhibits good reproducibility, reusability, selectivity, rapid response times (~4 s), long shelf life and high sensitivity of ca. 70 mV/decade over the urea logarithmic concentration range from 1×10?6 M to 1×10?3 M. 相似文献