GaAs/AlGaAs量子阱材料的X射线形貌及其发光性能

本文介绍了用X射线双品形貌术研究MBE生长的GaAs/AlGaAs量子阱材料中的生长缺陷、位错及其对发光性能的影响。同时研究了低温下MBE生长的GaAs/AlGaAs量子阱材料的正交方向的位错。在有应变超品格过渡层高温生长的量子阱材料中,位错及光致发光性能有明显的改善。     

泛圈图方面的著名Bondy定理的简单证明

本文用极好的新方法给出泛图图方面的Bondy定理的简捷证明。     

A new mapping rule for RNA secondary structures with its applications

According to the characterization of RNA secondary structures, the RNA secondary structures are transformed into elementary sequences, namely characteristic sequences of RNA secondary structures, by representing A, U, G, C in A-U/ G-C pairs, as A′, U′, G′, C′. Based on the representation, three recurrences for mapping RNA secondary structures into 1-D graph, 2-D graph and 3-D graph are given, respectively. Furthermore, a frequency-based method for RNA secondary structures is given in terms of 1-D graph.     

Total Synthesis of Diverse Tetramic Acid Bearing cis-Decalin Natural Products

We report herein the first total syntheses of four natural antibiotics, vermisporin, PF1052/AB4015-A, AB4015-L, AB4015-B, and one hydrogenated natural product derivative, AB4015-A2, that all feature a tetramic acid bearing cis-decalin ring. The construction of the functionalized cis-decalin ring was achieved by a diastereoselective intramolecular Diels-Alder (IMDA) reaction, which proceeded via a rare endo-boat transition state. Through an intramolecular neighboring-group-oriented strategy, the sterically hindered epoxy group in vermisporin, PF1052/AB4015-A and AB4015-L was installed efficiently. A one-pot aminolysis/Dieckmann condensation cascade using l -amino acid derivatives afforded the desired tetramic acid structure. The total synthesis led to the unambiguous verification of the absolute configuration of these natural products.     

三维相位展开算法在精密运动测试中的应用

三维相位展开算法将基于空间的相位展开算法拓展到时间轴上,包含了一维时间和二维空间信息,适合于运动测试。通过建立一维时间相位展开算法的数学模型,分析了该算法运动测试的基本原理,讨论了在精密测试中的使用方法和适用范围,并对微谐振器的微结构进行运动测试。实验表明,算法在相位展开中引入时间信息,不仅消除了形变测量中需选取静止点为相位参考点或参考平面的限制,还可以同时测量物体表面某点纳米级的离面运动曲线和表面形变。     

Biodegradation of chemically modified wheat gluten-based natural polymer materials

Biodegradation of a series of chemically modified thermally processed wheat gluten (WG)-based natural polymers were examined according to Australian Standard (AS ISO 14855). Most of these materials reached 93-100% biodegradation within 22 days of composting, and the growth of fungi and significant phase deformation were observed during the process. Chemical crosslinking did slow down the rate or reduce the degree of the biodegradation with different behaviours for different modified systems. The segments containing structures derived from the reactions with additives such as tannin or epoxidised soybean oil remained in the degradation residues while the glycidoxypropyl trimethoxysilane agent produced ∼20% un-degraded residues containing silicon-crosslinking structures. The biodegradation rate of each component of the materials was also different with the protein and starch components degraded fast but lipid degraded relatively slowly.     

关于LIH KO-WEI猜想的证明

ＬｉｎＫｏ－Ｗｅｉ［１］提出猜想：如果Ｆ是由Ｂｎ中固定秩的不同元素生成的序理想,那么Ｆ是Ｓｐｅｒｎｅｒ系［１］,黄国泰就Ｆ是由Ｘ的子集Ｙ的所有相同秩的元素生成的序理想,证实了上述猜想［２］,本文完全证明了该猜想．本文使用的概念,符号见［２］．定理设ａ...     

微结构特性的光学测试平台

微结构是微机电系统的基本元件,其几何尺寸、运动特性、材料及力学特性直接影响微机电系统的整体性能。提出一种将计算机微视觉、米劳显微干涉、频闪成像和激光多普勒测振等技术充分融合的微结构静态和动态特性的光学测试平台,分别对微谐振器的平面和离面周期运动特性和微机械扭转镜的离面瞬时运动特性进行测试研究。实验结果表明,利用计算机微视觉和频闪成像技术能够实观微结构的平面位移、运动相位及喈振频率等周期运动参量的测试．位移的重复精度为30nm;利用显微干涉和频闪成像技术可实现微结构的离面位移及表面扭曲等周期运动参量的测试．位移的重复精度为3nm;激光多普勒测振技术具有在频域上对微结构瞬态运动进行分析的优点．是时域上周期运动测试的重要补充。     

Bulk plastic materials obtained from processing raw powders of renewable natural polymers via back pressure equal channel angular consolidation (BP-ECAC)

Renewable natural polymers wheat starch (WS) and wheat gluten (WG) were successfully processed into plastic bulk materials using back pressure equal channel angular consolidation (BP-ECAC) without using any additional plasticizers at relatively low temperatures. The strong shear deformation occurred during the process caused an effective deformation of WS or WG granular structures and resulted in an efficient gelatinization of starch or plasticization of gluten with the natural moisture content. Sufficient chain entanglement was formed in both WS and WG materials for achieving strong cohesion among the macromolecule matrixes. The mechanical strength of the obtained plastic materials was comparable to that of conventional polymers but stronger than the strength of thermoplastic WS or plasticized WG. The processing temperature played an important role in determination of morphologies and properties of the plastic materials. Increasing processing temperature would cause more effective gelatinization or plasticization of the natural polymers, enhance the interactions among different components in the systems, and form materials with improved mechanical properties. Thermal cross-linking might play a positive role in the improvement of mechanical properties when processing temperature was increased. However, thermal decomposition could also occur under such severe shearing especially at high temperatures. The optimum temperature for conducting such process was around 100-120 °C for WS and WG. The BP-ECAC method provides a potential to manufacture natural polymer based plastic materials efficiently on an industrial scale for various applications.     

ZnS晶体3C⇔2H结构转变的LAUE衍射图中“奇异点”的标定

在ZnS晶体3C⇔2H结构转变的X—射线Laue衍射分析中,为了解释一维无序造成的异常衍射现象,本文推导了Laue衍射图曲线晶带的“奇异点”计算公式。并应用此公式,计算了ZnSLaue衍射照片上数条晶带上的“奇异点”,计算值与实验值完全吻合。另外,本文还对“奇异点”的形成、特点、标定的意义以及计算公式适用范围进行了讨论。