全文获取类型
收费全文 | 150篇 |
免费 | 0篇 |
专业分类
化学 | 75篇 |
数学 | 32篇 |
物理学 | 43篇 |
出版年
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2014年 | 1篇 |
2013年 | 4篇 |
2012年 | 6篇 |
2011年 | 3篇 |
2010年 | 2篇 |
2009年 | 3篇 |
2008年 | 6篇 |
2007年 | 8篇 |
2006年 | 4篇 |
2005年 | 20篇 |
2004年 | 8篇 |
2003年 | 1篇 |
2002年 | 7篇 |
2001年 | 4篇 |
1999年 | 5篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 8篇 |
1991年 | 4篇 |
1990年 | 9篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1977年 | 3篇 |
1975年 | 2篇 |
1970年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有150条查询结果,搜索用时 46 毫秒
1.
The separation of the toxicologically important aldehyde acrolein from other carbonyl compounds by high performance liquid chromatography after derivatization to 2,4-dinitrophenylhydrazones is critically discussed on the basis of a selection of published methods. A method is proposed whereby the compounds acrolein, acetone, and propanal may be reproducibly separated to baseline by a reversed phase HPLC procedure employing a ternary mixture of methanol, water, and acetonitrile as mobile phase. 相似文献
2.
We developed a new method to measure the average aggregation number of large rod-like micelles using static fluorescence self-quenching of a solubilized fluorophore. The method is based on the increase of self-quenching of micelle-solubilized pyrene through excimer formation. We consider the effect of random distribution of pyrene in micelles and the micellar size distribution. The measured average aggregation <n> M is based on a new M-weighted raging similar to our exponential-weighted averaging in the transient decay method. We apply this method to study the effect of a large concentration of salt on the average aggregation behavior of sodium dodecyl sulfate (SDS) and cetyle tetraammonium bromide (CTAB). The sizes increase with increasing ionic concentrations. For SDS, we used the thermodynamic model developed by Missel et al. to calculate < n > M which we compare with experimental results. 相似文献
3.
Ichimura AS Dye JL Camblor MA Villaescusa LA 《Journal of the American Chemical Society》2002,124(7):1170-1171
Electrides are materials in which alkali metals (Li through Cs) ionize to form bound alkali cations and "excess" electrons. The electrons reside in large cavities or channels or both in the host lattice. We report here the first synthesis of thermally stable inorganic electrides with cation-to-electron ratios of 1:1 as in organic electrides. Although alkali metal adducts to alumino-silicate zeolites are well known, the cation-to-electron ratio is generally 3:1 or greater because these zeolites contain alkali cations prior to incorporation of the alkali metal. In this work, two pure silica zeolites, ITQ-4and ITQ-7, with pore diameters of approximately 7 A, absorb up to 40 wt % cesium from the vapor phase (even at room temperature). The other alkali metals (except Li) can also be introduced at elevated temperatures. The optical and magnetic properties of the cesium-loaded samples suggest ionization to form Cs+ and e- with substantial electron-spin pairing. The metal-loaded samples are stable to at least 100 degrees C and are able to reduce small aromatic molecules such as benzene and naphthalene to the radical anions within the pores of the zeolite. 相似文献
4.
R. H. Dye 《Geometriae Dedicata》1996,60(3):289-300
A cap on a quadric is a set of its points whose pairwise joins are all chords. A cap is complete if it is not part of a larger one. The only field for which all complete quadric caps are known is GF(2). Those caps are small; the biggest for each quadric is of order the dimension of the ambient space. Apart from information about ovoids in dimensions at most 7, little else is known. Here, the evidence is increased by providing caps over GF(2), odd, which, if >1, have size of order the dimension cubed. In particular, complete caps are obtained for the quadrics Q
2m
(8), Q
+
8k+7
(8), Q
-
8k+3
(8), Q
+
8k+1
(8) and Q
-
8k+5
(8). These caps on Q
+
8k+7
(8) and Q
-
8k+3
(8) are complete on any Q
n(8) of which their quadrics are sections; so is that that of Q
4+2(8) for any Q
2n
(8) of which Q
4+2(8) is a section with the same kernel. From the correspondence with Q
2n
(8) complete caps are obtained for symplectic polarities over GF(8). 相似文献
5.
Sensitive methods were developed for the analysis of dextromethorphan (I) and two metabolites, (+)-17-methyl-morphinan-3-ol (II) and (+)-morphinan-3-ol (III), in plasma as well as dextromethorphan and three metabolites II, III and (+)-3-methoxymorphinan (IV) in urine using high-performance liquid chromatography followed by detection with a fluorometer. Dextromethorphan and its metabolites were extracted from plasma and urine and separated in the reversed-phase mode. The practical lower limits of determination for I, II, and III in plasma were 0.5, 5, and 5 ng/ml, respectively; for I, II, III, and IV in urine, the limits were 20 ng/ml, 0.6 microgram/ml, 0.5 microgram/ml, and 15 ng/ml, respectively. The linearity of the calibration graphs was excellent (r varied from 0.9994 to 0.9999) over concentration ranges of two orders of magnitude. 相似文献
6.
A palladium bipyridyl complex anchored onto nanosized mesoporous silica MCM-41 catalyzed the cross-coupling of aryl iodides or bromides with Grignard reagents to provide the corresponding biaryls in high yields. The reaction proceeded smoothly with an equal molar amount of substrate and Grignard reagent in the presence of 0.2-0.02 mol % of catalyst in THF at 50 °C or under refluxing conditions. The catalyst prepared may be used in a very low percentage, recovered after reaction, and re-used. 相似文献
7.
Becker-Szendy R Bratton CB Cady R Casper D Dye ST Gajewski W Goldhaber M Haines TJ Halverson PG Jones TW Kielczewska D Kropp WR Learned JG LoSecco JM Matsuno S McGrew C Mudan MS Price L Reines F Schultz J Sobel HW Stone JL Sulak LR Svoboda R Wittel F 《Physical review D: Particles and fields》1991,43(4):1413-1415
8.
We investigated the aggregation behavior of rod-like micelles of sodium dodecyl sulfate (SDS) in concentrated NaCl solution by quasi-elastic light scattering (QLS) and viscosity measurement over a range of temperature (25 °C to 50 °C) and NaCl concentration. The reduced viscosity of aqueous SDS in the presence of NaCl has been measured by an Ubbelohde-type capillary viscometer. We show mean hydrodynamic radius of micelles can be determined from viscosity data. We also determined mean hydrodynamic radius using quasi-elastic light scattering. Micellar size decreases with increasing temperature, whereas it increases with increasing ionic strength. The results of viscosity and dynamic light-scattering measurements are interpreted as the extension of length of rod-like micelles. We compare viscosity and light scattering experimental results. 相似文献
9.
A transitive triple, (a,b,c), is defined to be the set {(a,b), (b,c), (a,c)} of ordered pairs. A directed triple system of order v, DTS(v), is a pair (D,β), where D is a set of v points and β is a collection of transitive triples of pairwise distinct points of D such that any ordered pair of distinct points of D is contained in precisely one transitive triple of β. An antiautomorphism of a Directed triple system, (D,β), is a permutation of D that maps β to β−1, where β −1 = {(c,b,a)|(a,b,c) E β}. In this article we give necessary and sufficient conditions for the existence of a Directed triple system of order v admitting an antiautomorphism consisting of a single cycle of length d and having v − d fixed points. Further, we give a more general result for partial Directed triple systems in which the missing ordered pairs are precisely those containing two fixed points. © 1996 John Wiley & Sons, Inc. 相似文献
10.
Hong-Ping Lin Yah-Ru Cheng Chung-Rong Lin Feng-Yin Li Chang-Lin Chen She-Tin Wong Soofin Cheng Shang-Bin Liu Ben-Zu Wan Chung-Yuan Mou Chin-Yuan Tang Ching-Yen Lin 《中国化学会会志》1999,46(3):495-507
We report a “delayed neutralization” process for the preparation of highly-ordered aluminosilicate MCM-41 molecular sieves with high thermal and hydrothermal stability, and sharp pore size distribution. However, the structural order and pore size are dependent on the carbon chain length. In the mixture surfactant systems, the pore size of the MCM-41 materials could be fine-tuned. The pore size can be extended from 2.5 to 4.5 nm by adding a suitable amount of hydrocarbons. The tubular morphology of the MCM-41 material of 0.3 to 10 micrometers diameter, where the wall consists of coaxial cylindrical pores of nanometers MCM-41, can be obtained by careful control of the surfactant-water content and the rate of condensation of silica. An optimum condition for automatic synthesis of the hierarchical TWT structure has been accomplished. The addition of 1-alkanols as cosurfactant would not only improve the order of the MCM-41 hexagonal structure but also promote the formation of micrometer-sized hierarchical materials, for example: tubules-within-tubule and uniform-sized hollow spheres of diameter 5.0 ± 1.0 μm. However, the inside of the micron spheres has intricate structures possessing various topological genus ranks. The MCM-41 is a good supporter for Molybdenum oxide catalysts. The rate of deactivation in the catalytic reaction of ethyl-benzene dehydrogenation to styrene increases in the order: MT < MP < SiO2. The physically mixed samples have higher catalytic activity than impregnated ones. 相似文献