Polarographic Behaviour and Determination of Stability Constants of Uranyl-Ascorbate Complex

The complex species of UO₂(HA)(H₂A)⁺ and UO₂(HA)₂ were identified in the ascorbic acid solution of uranyl ion at pH<2.1 and pH>2.1, respectively. Polarographic wave was proved to be the simultaneous reduction of UO₂⁺² and UO₂(HA)(H₂A)⁺ at pH <2.1. However, at pH>2.1, the wave is due to the reduction of U0₂(HA)₂ The stability constants of the two complex species were found to be 5.1×10⁺ and 1.0×10⁵, respectively. The hydrolysis constant of uranyl ion in the solution of ascorbic acid was determined.     

Controlled synthesis and magnetic properties of 2D and 3D iron azide networks infinity2[Fe(N3)2(4,4'-bpy)] and infinity3[Fe(N3)2(4,4'-bpy)

Controlled synthesis of transition metal complexes with mixed ligands has led to two new compounds with the same empirical formula [Fe(N3)2(4,4'-bpy)] (4,4'-bpy=4,4'- bipyridine). The compound 2D-[Fe(N3)2(4,4'-bpy)] (I) contains end-on (EO) bridging azido ligands. It crystallizes in the orthorhombic crystal system, space group Cmmm (No. 65): a=11.444(2) A, b=15.181(3) A, c=3.458(1) A, V=600.8(2) A(3), and Z=2. The compound 3D-[Fe(N3)2(4,4'-bpy)] (II) contains end-to-end (EE) azido bridges. It belongs to the tetragonal crystal system, space group P4(1)2(1)2 (No. 92): a=8.132(1) A, b=8.132(1) A, c=16.708(3) A, V=1104.9(5) A(3), and Z=4. Crystals of I and II have been grown by the diffusion method. Phase-pure samples of both compounds have been obtained by means of an optimal solution synthesis. Spontaneous long-range magnetic ordering was found in both I and II, with I being a metamagnet, and II being a ferromagnet. For I, in the low-field region, multiple transitions at TN1=20 K and TN2=5 K were observed, and these indicated the existence of Fe moment reorientation. Heat capacity measurements on II confirmed ferromagnetic transition at TC=20 K.     

Detection of Ni2+ by a dimethylglyoxime probe using attenuated total-reflection infrared spectroscopy.

A new analytical approach for the detection of Ni2+ utilizing an attenuated total reflection (ATR) technique is discussed in this paper. Nickel detection was accomplished on a silicon ATR parallelogram crystal uniformly coated by a ca. 1.5-microm Nafion film embedded with dimethylglyoxime (DMG) probe molecules. The detection of Ni2+ is based on the appearance of a unique infrared absorption peak at 1572 cm(-1) that corresponds to the C=N stretching mode in the nickel dimethylglyoximate, Ni(DMG)2, complex. The suitable operational pH range for the nickel infrared sensor is between 6 - 8. High alkalinity in the sample solution causes a leaching of Ni(DMG)2. The detection limit of the nickel infrared sensor is 1 ppm in a sample solution of pH = 8. Interference studies revealed that Cu2+ could compete with Ni2+ for the DMG sites in the Nafion matrix. The new nickel detection methodology can be potentially utilized, after further improvement, in field analysis to locate hot spots contaminated with a high ppm of Ni2+.     

Nonlinear two-point boundary value problems on time scales

This work gives a criterion for the existence of positive solutions for nonlinear second order ordinary differential equations with two-point boundary conditions on time scales. Moreover, for some source terms which are in the sense of sublinear or superlinear, we also formulate corollaries and examples for applications and we improve previous results related with the first eigenvalue discussed by Professor Li.     

Monitoring metal ion contamination onset in hydrofluoric acid using silicon-diamond and dual silicon sensing electrode assembly.

Potentiometric detection of trace levels of metallic contamination onset in hydrofluoric acid using a silicon-based sensor in conjunction with two non-contaminating reference electrode systems is presented in this paper. In the first case, conductive diamond was used as a non-contaminating reference electrode. Cyclic voltammetry and open-circuit potential experiments demonstrated the feasibility of using a conductive diamond film electrode as a quasi-reference electrode in the HF solution. In the second case, a dual silicon electrode system was used with one of the silicon-based electrodes protected with an anion permeable membrane behaving as the quasi-reference electrode. The dual silicon sensing electrode system possessed an additional operational advantage of being unaffected by the solution acidity. Though both sensing configurations were able to detect the metal ion contamination onsets at the parts-per-trillion to parts-per-billion levels, the dual silicon electrode design showed a greater compatibility for the on-line detection of metallic impurities in HF etching baths commonly used in semiconductor processing.     

Eigenvalue Intervals for 2mth Order Sturm—Liouville Boundary Value Problems

Values of λ are determined for which there exist positive solutions of the 2mth order differential equation on a measure chain, (-1)^m x ^?2m (t)=λa(t)f(u(σ(t))), y? [0,1], satisfying α _i+1 u ^?21(0)+0, γ _i+1 u ^?21(σ(1))=0, 0≤i≤m?1 with αi,βi,γi,δi≥0, where a and f are positive valued, and both lim _x-0+ (f(x)/x) and lim _x-0+ (f(x)/x) exist.     

Why are enterprise resource planning systems indispensable to supply chain management?

Supply chain design is becoming a core competency, and the enterprise resource planning (ERP) system is expected to be an integral component of supply chain management (SCM). Installing an ERP system is, however, expensive and risky. IT managers must decide how to use their limited resources and invest in the right product. Can an ERP system directly improve SCM competency? This study proposes a conceptual framework featuring the ERP benefits and SCM competencies, and examines the impacts of the former on the latter. The results confirm the operational, managerial, and strategic benefits of ERP for the SCM competencies, but not the IT infrastructure and organizational benefits as significant predictors of them. Moreover, more than 80% of respondents think it necessary to first adopt an ERP system as the backbone of company operations before deploying other enterprise systems (ES), such as the SCM system.     

Some Polynomial Systems Associated with a Certain Family of Differential Operators

The authors aim at presenting several (presumably new) classes of linear, bilinear, and mixed multilateral generating functions for some general systems of polynomials which are defined by means of a certain family of differential operators. Some of the generating functions considered here are associated with the Stirling numbers of the second kind. Many (known or new) consequences and applications of the results obtained in this paper are also indicated.     

α-Glycosylation by D-glucosamine-derived donors: synthesis of heparosan and heparin analogues that interact with mycobacterial heparin-binding hemagglutinin

Numerous biomolecules possess α-D-glucosamine as structural component. However, chemical glycosylations aimed at this backbone are usually not easily attained without generating the unwanted β-isomer. We report herein a versatile approach in affording full α-stereoselectivity built upon a carefully selected set of orthogonal protecting groups on a D-glucosaminyl donor. The excellent stereoselectivity provided by the protecting group combination was found independent of leaving groups and activators. With the trichloroacetimidate as the optimum donor leaving group, core skeletons of glycosylphosphatidyl inositol anchors, heparosan, heparan sulfate, and heparin were efficiently assembled. The orthogonal protecting groups were successfully manipulated to further carry out the total syntheses of heparosan tri- and pentasaccharides and heparin di-, tetra-, hexa-, and octasaccharide analogues. Using the heparin analogues, heparin-binding hemagglutinin, a virulence factor of Mycobacterium tuberculosis, was found to bind at least six sugar units with the interaction notably being entropically driven.