全文获取类型
收费全文 | 83篇 |
免费 | 2篇 |
专业分类
化学 | 27篇 |
力学 | 1篇 |
数学 | 30篇 |
物理学 | 27篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2016年 | 2篇 |
2015年 | 3篇 |
2014年 | 5篇 |
2013年 | 5篇 |
2012年 | 5篇 |
2011年 | 7篇 |
2010年 | 3篇 |
2009年 | 3篇 |
2008年 | 3篇 |
2007年 | 6篇 |
2006年 | 5篇 |
2005年 | 5篇 |
2004年 | 4篇 |
2003年 | 7篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 4篇 |
1998年 | 2篇 |
1996年 | 1篇 |
1992年 | 1篇 |
1982年 | 2篇 |
1925年 | 1篇 |
排序方式: 共有85条查询结果,搜索用时 31 毫秒
1.
Cheikh Birahim Ndiaye 《Journal of Functional Analysis》2007,251(1):1-58
Working in a given conformal class, we prove existence of constant Q-curvature metrics on compact manifolds of arbitrary dimension under generic assumptions. The problem is equivalent to solving a nth-order non-linear elliptic differential (or integral) equation with variational structure, where n is the dimension of the manifold. Since the corresponding Euler functional is in general unbounded from above and below, we use critical point theory, jointly with a compactness result for the above equation. 相似文献
2.
Ibra Gueye Dioum Jacques Vedel Bernard Tremillon 《Journal of Electroanalytical Chemistry》1982,137(2):219-226
Molten potassium tetrachlorogallate and potassium tetraiodogallate were studied in terms of halogenoacidity, based on X? ion-exchange. Titration of KX solution with GaX3 were achieved and characterized by the shift of cathodic voltammetric curves. Autodissociation constants Ki,X/mol2 kg?1 were determined: ?log Ki,Cl=4.25±0.05 and ?log Ki,I=2.6±0.05, as well as the solubility values of KX: 0.41±0.02 and 0.80±0.02 mol kg?1 for KCl and KI respectively. 相似文献
3.
4.
We study the problem of existence of conformal metrics with prescribed Q-curvature on closed four-dimensional Riemannian manifolds. This problem has a variational structure, and in the case of interest here, it is noncompact in the sense that accumulations points of some noncompact flow lines of a pseudogradient of the associated Euler–Lagrange functional, the so-called true critical points at infinity of the associated variational problem, occur. Using the characterization of the critical points at infinity of the associated variational problem which is established in [42], combined with some arguments from Morse theory, some algebraic topological methods, and some tools from dynamical system originating from Conley's isolated invariant sets and isolated blocks theory, we derive a new kind of existence results under an algebraic topological hypothesis involving the topology of the underling manifold, stable and unstable manifolds of some of the critical points at infinity of the associated Euler–Lagrange functional. 相似文献
5.
Azetidinium triflates were reacted in a one-pot two-steps sequence involving, generation of an azetidinium ylide, its alkylation with an halide, and final regioselective Hofmann elimination of the produced alkylated azetidinium ion to yield substituted α,β-unsaturated nitriles bearing an aminoethyl side-chain. The scope of this sequence was examined, and was found to depend both on the steric hindrance around the reactive center in the starting azetidinium salt, and on the nature of the reacting halide. Produced acrylonitriles were further used in DBU-catalyzed conjugate addition of amines, to yield 4-amino-2-aminomethyl-butyronitriles with fair diastereoselectivity, or, alternatively, to give C2 symmetrical cyclopropanes. 相似文献
6.
Dongshuang Wu Kohei Kusada Tomokazu Yamamoto Takaaki Toriyama Syo Matsumura Ibrahima Gueye Okkyun Seo Jaemyung Kim Satoshi Hiroi Osami Sakata Shogo Kawaguchi Yoshiki Kubota Hiroshi Kitagawa 《Chemical science》2020,11(47):12731
We report the synthesis of high-entropy-alloy (HEA) nanoparticles (NPs) consisting of five platinum group metals (Ru, Rh, Pd, Ir and Pt) through a facile one-pot polyol process. We investigated the electronic structure of HEA NPs using hard X-ray photoelectron spectroscopy, which is the first direct observation of the electronic structure of HEA NPs. Significantly, the HEA NPs possessed a broad valence band spectrum without any obvious peaks. This implies that the HEA NPs have random atomic configurations leading to a variety of local electronic structures. We examined the hydrogen evolution reaction (HER) and observed a remarkably high HER activity on HEA NPs. At an overpotential of 25 mV, the turnover frequencies of HEA NPs were 9.5 and 7.8 times higher than those of a commercial Pt catalyst in 0.05 M H2SO4 and 1.0 M KOH electrolytes, respectively. Moreover, the HEA NPs showed almost no loss during a cycling test and were much more stable than the commercial Pt catalyst. Our findings on HEA NPs may provide a new paradigm for the design of catalysts.RuRhPdIrPt high-entropy-alloy nanoparticles with a broad and featureless valence band spectrum show high hydrogen evolution reaction activity. 相似文献
7.
Fluorimetric Determination of Histamine in Fish Using Micellar Media and Fluorescamine as Labelling Reagent 总被引:1,自引:0,他引:1
Adamou R Coly A Douabalé SE Saleck ML Gaye-Seye MD Tine A 《Journal of fluorescence》2005,15(5):679-688
An analytical method based on the use of fluorescamine to produce a fluorescent derivative with histamine and combined with
micellar-enhanced fluorescence detection of the formed complex is developed for the sensitive and rapid determination of histamine
in fishes. The fluorescence properties of the obtained complex in water and micellar solutions of sodium dodecyl sulfate (SDS),
cetyltrimethylammonium chloride (CTAC) and brij-700 are reported. Physicochemical variables influencing the sensitivity of
the method (pH, micellar, fluorescamine and NaCl relative concentrations) have been optimized. The stability of the formed
complex, as shown by kinetic study, depends on the pH of the solution. Linear calibration curves allowing an effective histamine
determination were established with large linear dynamic range (LDR), and low limits of detection (LOD) between 0.5 and 33
ng mL−1, according to the solvent. Application to the analysis of fish samples (sardines) yielded satisfactory results. The method
seems to be suitable for environmental fish quality control.
Presented in part, at the 39th IUPAC Congress and the 86th Conference of the Canadian Society for Chemistry, August, 10–15,
2003, Ottawa (Canada). 相似文献
8.
In this paper, we characterize the d-symmetric d-orthogonal polynomials of Brenke type. We obtain two new families of polynomials and the moments of the corresponding d-dimensional vectors of linear functionals. Weights, providing integral representations for these moments, were also given. 相似文献
9.
By use of frequency-shifted feedback lasers, noise with a stationary amplitude and a periodically stationary phase is generated. The ensemble-averaged time correlation function is periodic, whereas the power spectrum is broadband, resulting in a waveform that does not obey the Wiener-Khintchine relations. An application to multiple-access communications is discussed. 相似文献
10.
Nawel Cheikh Didier Villemin Nathalie Bar Jean-François Lohier Nourredine Choukchou-Braham Bachir Mostefa-Kara Jana Sopkova 《Tetrahedron》2013,69(3):1234-1247
In the course of our studies on Cerpegin analogues synthesis, a serendipitous reactivity of enaminolactone nitrile has been observed. Instead of expecting iminocerpegins, we have gained new class of substituted 2-aminopyridines. The methodology has been applied on a wide range of primary amines, as aliphatic, aromatic, heteroaromatic and also, diamines, hydrazines and chiral amines. 相似文献