Deformational Properties of Irradiated Composite Materials Based on PET and PE

Considering the wide applicability of polymeric composite materials, heterogeneous blends of poly(ethylene terephtalate) (PET) and polyethylenes of high and low densities (HDPE and LDPE, respectively) were investigated. Rheological (the flow-behavior index), mechanical (the yield strength and the Charpy impact strength), and morphological (crystallinity and the melting temperature) properties were detected for individual blend components and different blend compositions. A radiation treatment (-rays) was applied to improve certain characteristics of the heterogeneous blends. The results of this investigation show that the radiation modification can be successfully used to improve some physical properties of the PET-based blends and to choose individual blend components, optimum irradiation conditions, and desirable blend compositions, which allows producing materials with a predictable set of mechanical properties.     

The accumulated dissipated energy of composites under cyclic-dynamic stress

This paper presents a method for the estimation of the vibratory fatigue strength of composite materials, which is based on the accumulated dissipated energy. The accumulated dissipated energy was measured with a special measuring technique that is able to catch quasi-continuously the mechanical properties of the tested samples. The samples were made of glass-fiber epoxy foams reinforced with pretreated woven fabrics. The curves of the accumulated dissipated energy were approximated by an equation that includes several parameters. These parameters were identified for experiments with different types of load and for samples with different contents of micropores. In the equation for samples that reach more than 10⁶ load cycles, the accumulated dissipated energy in one load stage tests turns out to be a linear function. With this function the fatigue limit of the samples can be predicted.     

Some physical and mechanical properties of recycled polyurethane foam blends

Blends of secondary rigid polyurethane foams (RPUFs) with soft polyurethane foams (SPUFs) were investigated. The effect of SPUF content and its chemical nature on some physical and mechanical properties of the blends was evaluated. Owing to the stronger intermolecular interaction and higher values of cohesion energy, the blends of RPUFs with polyester SPUFs showed higher mechanical properties than those with polyether SPUFs. The density, hardness, ultimate strength, and the tensile, shear, and flexural moduli increased, while the impact toughness, ultimate elongation, and damping characteristics decreased with increasing RPUF content in the blends. Translated from Mekhanika Kompozitnykh Materialov, Vol. 44, No. 5, pp. 737–746, September–October, 2008.     

Mode I,mode II,and mixed-mode I/II interlaminar fracture toughness of GFRP influenced by fiber surface treatment

The interlaminar fracture behavior of unidirectional glass fiber reinforced composites with fiber surface treatment has been investigated in modes I and II and for fixed mode I to mode II ratio of 1.33. The data obtained from these tests have been analyzed by using different analytical approaches. The present investigation is focused on the influence of the glass fiber surface treatment on the interlaminar fracture toughness of unidirectional laminates. Glass fibers with two different fiber surface treatments have been investigated. fiber surface treatment was carried out by using a polyethylene or silane coupling agent in combination with modifying agents. The glass fibers were embedded in the brittle epoxy matrix. Mode I, mode II, and mixed-mode I/II tests were performed in order to determine critical strain energy release rates. Double cantilever beam (DCB), end-notched flexure (ENF), and mixed-mode flexure (MMF) specimens were used. For both types of fiber surface treatment about the same values of mode I initiation fracture toughness G_IC ^init were obtained. It was observed that in mode I interlaminar crack growth in the DCB test for the composite sized by polyethylene, the crack propagation is accompanied by extensive fiber bridging. For both fiber surface treatments interlaminar fracture toughness increases considerably with increasing of crack length. For the fiber surface treatment with the silane coupling agent, the value of mode II initiation fracture toughness G_IIC ^init was about 2.5-times higher in comparison with that of a composite sized by polyethylene. For both types of fiber surface treatments the mixed-mode I/II test has shown a similar behavior to the mode I DCB test.     

The effect of interphase on residual thermal stresses. 1. Single fiber composite materials

Conclusions The residual thermal stresses in the constituents of a fiber-reinforced epoxy have been predicted using a concentric three-cylindrical (fiber-interphase-matrix) assemblage analysis. The interphase has been treated as a region with a variable Young's modulus — a direct consequence of the changes in the microstructure of the matrix near the fiber surface. The Navier equations of elasticity have been solved in series form solutions for each type of property variation.A parametric study is used to demonstrate the fact that changes in the interphase properties can drastically affect the residual stresses in the interphase.Published in Mekhanika Kompozitnykh Materialov, Vol. 30, No. 5, pp. 579–589, September–October, 1994.     

Investigations of interlaminar fracture toughness of laminated polymeric composites

The behavior of interlaminar fracture of fiber reinforced laminated polymeric composites has been investigated in modes I, II, and different mixed mode I/II ratios. The experimental investigations were carried out by using conventional beam specimens and the compound version of the CTS (compact tension shear) specimen. In this study, a compound version of the CTS specimen is used for the first time to determine the interlaminar fracture toughness of composites. In order to verify the results obtained by the CTS tests, conventional beam tests were also carried out. In the beam tests, specimens of double cantilever beam (DCB) and end notched flexure (ENF) were used to obtain the critical rates of the energy release for failure modes I and II. The CTS specimen is used to obtain different mixed mode ratios, from pure mode I to pure mode II, by varying the loading conditions. The highest mixed mode ratio obtained in the experiment was G _I /G _II =60. The data obtained from these tests were analyzed by the finite element method. The separated critical rates G _I and G _II of the energy release were calculated by using the modified virtual crack closure integral (MVCCI) method. The experimental investigations were performed on a unidirectional glass/epoxy composite. The results obtained by the beam and CTS tests were compared. It was found that the interlaminar fracture toughness G _IC ^init of mode I at crack initiation and the corresponding value G _II ^Cinit of mode II obtained by the conventional beam and the CTS tests were in rather good agreement. The experimental results of interlaminar fracture of mixed mode were used to obtain the parameters required for the failure criterion. The two different failure criteria were compared. The best correlation with the experimental data was obtained by using the failure criterion proposed by Wu in 1967 containing linear and quadratic terms of the rates of the energy release.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 3, pp. 307–322, May–June, 1998.