全文获取类型
收费全文 | 1145篇 |
免费 | 33篇 |
国内免费 | 6篇 |
专业分类
化学 | 808篇 |
晶体学 | 6篇 |
力学 | 28篇 |
数学 | 193篇 |
物理学 | 149篇 |
出版年
2022年 | 21篇 |
2021年 | 16篇 |
2020年 | 26篇 |
2019年 | 30篇 |
2018年 | 11篇 |
2017年 | 15篇 |
2016年 | 21篇 |
2015年 | 23篇 |
2014年 | 40篇 |
2013年 | 44篇 |
2012年 | 70篇 |
2011年 | 78篇 |
2010年 | 40篇 |
2009年 | 41篇 |
2008年 | 48篇 |
2007年 | 77篇 |
2006年 | 67篇 |
2005年 | 57篇 |
2004年 | 60篇 |
2003年 | 50篇 |
2002年 | 56篇 |
2001年 | 14篇 |
2000年 | 21篇 |
1999年 | 15篇 |
1998年 | 6篇 |
1997年 | 14篇 |
1996年 | 11篇 |
1995年 | 21篇 |
1994年 | 19篇 |
1993年 | 8篇 |
1992年 | 13篇 |
1991年 | 7篇 |
1990年 | 9篇 |
1988年 | 6篇 |
1987年 | 9篇 |
1986年 | 9篇 |
1985年 | 9篇 |
1984年 | 9篇 |
1983年 | 12篇 |
1982年 | 7篇 |
1981年 | 13篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1975年 | 8篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1969年 | 4篇 |
排序方式: 共有1184条查询结果,搜索用时 0 毫秒
1.
2.
3.
E.Ann Hallinan Clifford R. DornWilliam M. Moore Gina M. JeromePamela T. Manning Barnett S. Pitzele 《Tetrahedron letters》2003,44(39):7345-7347
Described is a method of introducing trifluoroalkyl groups at C-6 of lysine. This chemistry has the potential to introduce a variety of functionality at C-6 of lysine. 相似文献
4.
Vishal Sipani Ann Kirsch Alec B. Scranton 《Journal of polymer science. Part A, Polymer chemistry》2004,42(17):4409-4416
The effective propagation rate constant (kp; averaged over all the propagating active centers) was characterized for solvent‐free cationic photopolymerizations of phenyl glycidyl ether over the entire range of conversions, including the high conversion regime in which mass transfer limitations become important. The profile for the kp as a function of conversion was found to exhibit a constant plateau value at low to intermediate conversions, followed by a monotonic increase above a threshold value of conversion. To explain this trend, it is proposed that at high conversion the diffusional mobility of the photoinitiator counterion is reduced whereas the mobility of the cationic active center remains high because of reactive diffusion. Therefore, with increasing conversion, the average distance between the active centers and counterions may increase, resulting in an increase in the propagation rate constant. The profiles for the kp values were investigated as a function of the temperature, photoinitiator anion, and photoinitiator concentration. As the photoinitiator concentration was increased, the plateau value of the effective propagation rate constant decreased whereas the threshold conversion increased. All of the experimental trends are consistent with the proposed increase in ion separation at high conversions. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4409–4416, 2004 相似文献
5.
6.
James J. Li R. Alan Chrusciel Monica B. Norton David B. Reitz Timothy J. Hagen Sofya Tsymbalov E. Ann Hallinan 《Journal of heterocyclic chemistry》1994,31(6):1689-1696
Lithiation of 8-chlorodibenz[b,f][1,4]oxazepine-10-tert-butylcarbamate ( 1 ) is described. Electrophilic substitution of the resulting N-Boc dibenzoxazepine α- lithioamine 2 with ketones, aldehydes, nitriles, iso-cyanates and imines, followed by an in-situ cyclization, gave fused carbamates 5–26 , fused 2H-imidazol-2-ones 27–29 , fused hydantoins 30–32 , and fused ureas 33–35 , respectively, in 11–66% yield. 相似文献
7.
Leonard S Van Schepdael A Iványi T Lázár I Rosier J Vanstockem M Vermeersch H Hoogmartens J 《Electrophoresis》2005,26(3):627-632
A capillary electrophoretic (CE) method was developed for the separation of diastereoisomers of a new human immunodeficiency virus (HIV) protease inhibitor TMC114. In total 16 isomers of this drug have been synthesized (eight pairs of enantiomers). We succeeded in the separation of the eight diastereoisomers, but no enantiomers could be separated. Because of the high similarity and water-insolubility of these isomers, the separation is a real challenge. Different CE modes were tried out: capillary zone electrophoresis (CZE), nonaqueous capillary electrophoresis (NACE), micellar electrokinetic capillary chromatography (MEKC), and microemulsion electrokinetic capillary chromatography (MEEKC). Only MEEKC offered resolution of these compounds. 相似文献
8.
Ronald C. Crouch Ann O. Davis Timothy D. Spitzer Gary E. Martin Maged M. H. Sharaf Paul L. Schiff Charles H. Phoebe Albert N. Tackie 《Journal of heterocyclic chemistry》1995,32(3):1077-1080
Elucidation of minor natural product structures has been significantly augmented by inverse-detection; further improvement has been afforded by the development of micro inverse-detection probes. We report here the elucidation of the structure of a new alkaloid, quindolinone (5H, 10H-indolo[3,2-b]quinolin-11-one), from the West African plant Cryptolepis sanguinolenta. All nmr data for this minor, preparative hplc-isolated alkaloid, including 1H-15N one? bond heteronuclear shift correlation (HMQC) data, were recorded on an 800 μg sample of the alkaloid dissolved in 140 μl of 100% d6-DMSO using a 400 MHz spectrometer. 相似文献
9.
Mexiletine— and lysine hydrochloride—o-phthalaldehyde and mexiletine hydrochloride—, cysteine—, cysteamine—, homocysteine— and lysine hydrochloride—fluorescamine derivatives were subjected to Triton and β-cyclodextrin enhancement treatments. Of several classical fluorescence-enhancing reagents tested (Triton, β-cyclodextrin, sodium dodecyl sulphate, Brij), Triton provided the best results, followed by β-cyclodextrin. Increases in fluorescence emission by a factor of up to about 10 (mexiletine—fluorescamine—Triton X-100) were observed, with a generally negligible influence of the enhancing reagents on the excitation and emission maxima. Fluorescence enhancement by the addition of a suitable reagent solution to the final analyte solution may, in specific instances, enhance the detectability of native or chemically induced fluorophores. 相似文献
10.
Rudolph Willem Ann Delmotte Inge De Borger Monique Biesemans Marcel Gielen Franois Kayser Edward R. T. Tiekink 《Journal of organometallic chemistry》1994,480(1-2):255-259
The synthesis of (Z)-2-methyl-3-triphenylstannyl-3-pentene-2-ol and its characterization by an X-ray diffraction study and multinuclear NMR are reported. The tin atom exhibits a distorted tetrahedral SnC4 geometry with the four Sn---C bond distances experimentally equivalent. The slight distortion from the ideal tetrahedral geometry is because of the presence of a weak intramolecular HO → Sn interaction of 3.012(3) Å which produces a loose four-membered ring. The title compound was characterized in solution by 1H, 13C and 119Sn NMR, and the persistence of the weak intramolecular HO → Sn coordination in solution was revealed by 13C and 119Sn secondary isotope multiplet of partially labelled entities (SIMPLE-NMR) experiments. 相似文献