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1.
Daniel L. Feldheim Del R. Lawson Charles R. Martin 《Journal of Polymer Science.Polymer Physics》1993,31(8):953-957
We report a strong dependence of the thermal stability of Nafion® perfluorosulfonate ionomer on the nature of the counterion associated with the fixed sulfonate site. These results were obtained using thermal gravimetric analysis on a series of alkali metal and alkyl ammonium cation-exchanged Nafion films. We have found that the temperature of decomposition of Nafion is inversely dependent on the size of the exchanged cation; i.e., Nafion films show improved thermal stability as the size of the counter cation decreases. We attribute this inverse relationship of thermal stability with counterion size to an initial decomposition reaction which is strongly influenced by the strength of the sulfonate-coun-terion interaction. © 1993 John Wiley & Sons, Inc. 相似文献
2.
Summary We study the integration theory for general integral metrics when restricted to upper integrals q, finding improvements in the relation between the classes of the q-integrable and the ql-integrable functions. We give new results and notions which lead to the desirable characterizations of q-integrable functions as ql-integrable f with q(|f|) < ∞, and of ql-integrable functions via the integrability of their upper truncations, under natural conditions which are fulfilled in most
finitely additive integration theories. 相似文献
3.
V Ravindran Pankaj Agrawal Rahul Basu Satyaki Bhattacharya J Blümlein V Del Duca R Harlander D Kosower Prakash Mathews Anurag Tripathi 《Pramana》2006,67(5):983-992
This is the report of the subgroup QCD of Working Group-4 at WHEPP-9. We present the activities that had taken place in the
subgroup and report some of the partial results arrived at following the discussion at the working group meetings. 相似文献
4.
Bubbles released from a porous plug into a gas-stirred ladle present different bubbly dispersion patterns that can be studied by CFD means. Recent modeling (Alexiadis et al.) has, in fact, led to numerical results in accord with experimental data. However, due to the high number of equations involved, it is not easy to understand the physical reasons of the transitions between these patterns. In the present paper, attention was focused on the role of fragmentation and coalescence and the pattern-transition modeled by means of intersection points between these functions. 相似文献
5.
Flow injection methodology based on sample insertion between two different standard solutions used as carrier streams is described. This approach provides a simple system for continuous recalibration in process control; spectrophotometric and ion-selective electrode procedures are outlined. 相似文献
6.
L. Cianchi F. Del Giallo F. Pieralli M. Mancini S. Sciortino G. Spina 《Hyperfine Interactions》1991,66(1-4):387-391
Mössbauer parameters of151Eu in Eu1+x Ba2?x Cu3O7+δ have been studied as a function of temperature, forx=0.15 andx=0.25. The areas of the absorption spectra for the two samples are almost equal. This could mean that thef-Mössbauer factor for151Eu at the barium sites is much smaller than that for151Eu at the rare earth sites, i.e. we only observe the spectra of the latter sites. According to this, the fits of the spectra with a single quadrupolar pattern and with two quadrupolar patterns have given equivalent χ2 values. 相似文献
7.
M. A. Macrì C. Del Gratta L. Di Donato S. Di Luzio G. L. Romani S. Della Penna A. Pasquarelli 《Il Nuovo Cimento D》1994,16(5):425-432
Summary A preliminary study is here reported on a new potential marker for biomagnetic measurements. The marker consists of superparamagnetic
polymer microspheres which were detected in the presence of external steady magnetic fields by means of an r.f.-SQUID magnetometer.
The particles were prepared in samples differing in the concentration value and immersed in a homogeneous magnetic field of
variable intensity. A simple model was taken into account for the distribution of the microspheres in the samples, so that
the theoretical values were compared to the marker field values measured by the biomagnetic sensor. The overall sensitivity
of the experimental apparatus and the minimum concentration value of the marker were then estimated. 相似文献
8.
9.
B. Blank J. -J. Gaimard H. Geissel K. -H. Schmidt H. Stelzer K. Sümmerer D. Bazin R. Del Moral J. P. Dufour A. Fleury F. Hubert H. -G. Clerc M. Steiner 《Zeitschrift für Physik A Hadrons and Nuclei》1992,343(4):375-379
Total charge-changing cross sections have been measured for8Li on C and Pb targets, for9Li on C, Al, Cu, Sn and Pb targets, as well as for11Li on C, Sn and Pb targets at about 80 MeV/nucleon. These data are compared to measured total reaction cross sections and Glauber-type calculations using Hartree-Fock density distributions. These comparisons allow to draw conclusions on the proton density distribution of the neutronrich lithium isotopes. The results show that even for the most exotic nucleus11Li the proton distribution is only very weakly influenced by the long tail in the neutron density distribution already established in several experiments. 相似文献
10.
Summary A statistical study of precipitation over the Po Valley and the Alps during four winters, based on the application of a principal
component (p.c.) method, exhibited a good correlation between the first three rotated eigenvectors of the cross-product matrix
(between time series of data recorded at 70 stations) and three typical atmospheric circulation schemes over Northern Italy.
The study is here continued, by relating these results to meteorological fields evaluated over a region wider than the area
previously considered. Our attention mainly concentrated on the fields of time trend of geopotential height at 850 hPa over
Europe, between latitude 34.5 and 51 degrees North and longitudes 0 and 21 degrees East. This was suggested by some peculiar
relationships shown by the statistical distributions of geopotential height and wind direction and speed with respect to the
first three p.c.’s. These relationships made us think of the possibility to use those trends as predictors of precipitation
fields. Our analysis puts into evidence that three spatial patterns of geopotential, height time trend can be safely associated
to the first three p.c.’s and, as a consequence, to the three precipitation modes corresponding to the spatial distributions
of the eigenvectors, previously identified by us. They can therefore be considered meaningful precursors of precipitation
field patterns over Northern Italy and Alpine regions.
Riassunto Uno studio statistico della precipitazione sulla pianura padana e sulle Alpi durante quattro inverni, basato sull’applicazione del metodo delle componenti principali (c.p.), ha mostrato una buona correlazione fra i primi tre autovettori rotati della matrice dei prodotti incrociati (fra le serie temporali dei dati registrati in 70 stazioni) e tre tipici schemi di circolazione atmosferica sull’Italia del Nord. Lo studio viene qui prosequito, mettendo in relazione tali risultati con campi meteorologici valutati su una zona piú ampia di quella precedentemente considerata. La nostra attenzione si è prevalentemente concentrata sui campi di tendenza temporale dell’altezza di geopotenziale a 850 hPa sull’Europa, a latitudini comprese tra 34.5 e 51 gradi Nord e longitudini fra 0 e 21 gradi Est. Ciò è stato suggerito da alcune relazioni peculiari mostrate dalle distribuzioni statistiche di altezza di geopotenziale e di direzione ed intensità del vento rispetto alle prime tre c.p., che ci hanno fatto pensare alla possibilità di usare tali tendenze come predittori del campo di precipitazione. La nostra analisi ha messo in evidenza il fatto che tre distribuzioni spaziali di tendenza temporale del campo di altezza di geopotenziale possono essere con sicurezza associate alle prime tre c.p. e., quindi, ai tre modi di precipitazione corrispondenti alle distribuzioni spaziali degli autovettori precedentemente da noi identificati. Essi possono pertanto essere considerati significativi precursori del campo di precipitazione sull’Italia del Nord e sulle regioni alpine.
Резюме Статистическое исследование выпадения осадков над долиной реки По и Альпами в течение четырех зим, основанное на применении метода главных компонент, обнаруживает хорошую корреляцию между первыми тремя вращающимися собственными векторами матрицы векторного произведения (между временными последовательностями данных, зарегистрированных на 70 станциях) и тремя схемами типичной атмосферной циркуляции над Северной Италией. В этой работе продолжены исследования. Полученные результаты связывайотся с метеорологическими полями, вычисленными над областью, которая шире ранее рассмотренной области. Главное внимание мы обращаем на поля временного хода для геопотенциальной высоты при 850гПа над Европой, между 34.5щ и 51щ северной широты и между 0щ и 21щ восточной долготы. Это следует из специальных соотношений, полученных с помощью статистических распределений геопотенциальной высоты и направления и скорости ветра относительно первых трех главных компонент. Эти соотношения позволяют нам использовать исследованные тенденции, как предсказатели полей вьшадения осадков. Нам анализ подтверждает, что три пространственным распределения временного хода для геопотенциальной высоты могут быть связаны с первыми тремя главными компонентами и, как следствие, с тремя моделями выцадения осадков, которые соответствуют пространственным распределениям собственных векторов, ранее идентифицированных в работе [Ш]. Следовательно, они могут рассматриватяся как предвестники для распределений полей осадков над Северной Италией и над Альпами.相似文献