排序方式: 共有69条查询结果,搜索用时 13 毫秒
1.
A new ion selective electrode for salicylate based on N,N'-(aminoethyl)ethylenediamide bis(2-salicylideneimine) binuclear copper(Ⅱ) complex [Cu(Ⅱ)2-AEBS] as an ionophore was developed. The electrode has a linear range from 1.0 × 10^-1 to 5.0 ×10^-7 mol·L^- 1 with a near-Nemstian slope of ( - 55 ±1 ) mV/decade and a detection limit of 2.0 × 10-7 mol·L^-1 in phosphorate buffer solution of pH 5.0 at 25 ℃. It shows good selectivity for Sal^- and displays anti-Hofmeister selectivity sequence: Sal^-〉SCN^-〉 ClO4^- 〉I^-〉 NO2^- 〉Br^-〉 NO3^- 〉Cl^-〉 SO3^2- 〉 SO4^2- The proposed sensor based on binuclear copper(Ⅱ)complex has a fast response time of 5-10 s and can be used for at least 2 months without any major deviation. The response mechanism is discussed in view of the alternating current (AC) impedance technique and the UV-vis spectroscopy technique. The effect of the electrode membrane compositions and the experimental conditions were studied. The electrode has been successfully used for the determination of salicylate ion in drug pharmaceutical preparations. 相似文献
2.
Ni ZH Kou HZ Zheng L Zhao YH Zhang LF Wang RJ Cui AL Sato O 《Inorganic chemistry》2005,44(13):4728-4736
Two new cyano-bridged heterobinuclear complexes, [Mn(II)(phen)2Cl][Fe(III)(bpb)(CN)2] x 0.5CH3CH2OH x 1.5H2O (1) and [Mn(II)(phen)2Cl][Cr(III)(bpb)(CN)2] x 2H2O (2) [phen = 1,10-phenanthroline; bpb(2-) = 1,2-bis(pyridine-2-carboxamido)benzenate], and four novel azido-bridged Mn(II) dimeric complexes, [Mn2(phen)4(mu(1,1)-N3)2][M(III)(bpb)(CN)2]2 x H2O [M = Fe (3), Cr (4), Co (5)] and [Mn2(phen)4(mu(1,3)-N3)(N3)2]BPh4 x 0.5H2O (6), have been synthesized and characterized by single-crystal X-ray diffraction analysis and magnetic studies. Complexes 1 and 2 comprise [Mn(phen)2Cl]+ and [M(bpb)(CN)2]- units connected by one cyano ligand of [M(bpb)(CN)2]-. Complexes 3-5 are doubly end-on (EO) azido-bridged Mn(II) binuclear complexes with two [M(bpb)(CN)2]- molecules acting as charge-compensating anions. However, the Mn(II) ions in complex 6 are linked by a single end-to-end (EE) azido bridging ligand with one large free BPh4(-) group as the charge-balancing anion. The magnetic coupling between Mn(II) and Fe(III) or Cr(III) in complexes 1 and 2 was found to be antiferromagnetic with J(MnFe) = -2.68(3) cm(-1) and J(MnCr) = -4.55(1) cm(-1) on the basis of the Hamiltonian H = -JS(Mn)S(M) (M = Fe or Cr). The magnetic interactions between two Mn(II) ions in 3-5 are ferromagnetic in nature with the magnetic coupling constants of 1.15(3), 1.05(2), and 1.27(2) cm(-1) (H = -JS(Mn1)S(Mn2)), respectively. The single EE azido-bridged dimeric complex 6 manifests antiferromagnetic interaction with J = -2.29(4) cm(-1) (H = -JS(Mn1)S(Mn2)). Magneto-structural correlationship on the EO azido-bridged Mn(II) dimers has been investigated. 相似文献
3.
A dicyano-containing [Fe(bpb)(CN)2]- building block has been employed for the synthesis of cyano-bridged heterometallic Ni(II)-Fe(III) complexes. The presence of steric bpb(2-) ligand around the iron ion results in the formation of low-dimensional species: five are neutral NiFe2 trimers and three are one-dimensional (1D). The structure of the 1D complexes consists of alternating [NiL]2+ and [Fe(bpb)(CN)2]- generating a cyano-bridged cationic polymeric chain and the perchlorate as the counteranion. In all complexes, the coordination geometry of the nickel ions is approximately octahedral with the cyano nitrogen atoms at the trans positions. Magnetic studies of seven complexes show the presence of ferromagnetic interaction between the metal ions through the cyano bridges. Variable temperature magnetic susceptibility investigations of the trimeric complexes yield the following J(NiFe) values (based on the spin exchange Hamiltonian H = -2J(NiFe) S(Ni) (S(Fe(1)) + S(Fe(2))): J(NiFe) = 6.40(5), 7.8(1), 8.9(2), and 6.03(4) cm(-1), respectively. The study of the magneto-structural correlation reveals that the cyanide-bridging bond angle is related to the strength of magnetic exchange coupling: the larger the Ni-N[triple bond]C bond angle, the stronger the Ni- - -Fe magnetic interaction. One 1D complex exhibits long-range antiferromagnetic ordering with T(N) = 3.5 K. Below T(N) (1.82 K), a metamagnetic behavior was observed with the critical field of approximately 6 kOe. The present research shows that the [Fe(bpb)(CN)2]- building block is a good candidate for the construction of low-dimensional magnetic materials. 相似文献
4.
Four linear trinuclear transition metal complexes have been prepared and characterized. The complexes [MII(MeOH)4][FeIII(L)2]2·2MeOH (M = Fe (1) or Ni (2)), [CoII(EtOH)2(H2O)2][FeIII(L)2]2·2EtOH (3), and [MnII(phen)2][MnIII(L)2]2·4MeOH (4) (H2L = ((2-carboxyphenyl)azo)-benzaldoxime, phen = 1,10-phenanthroline) possesses a similar syn–anti carboxylate-bridged structure. The terminal Fe(III) or Mn(III) ions are low spin, and the central M(II) ions are high spin. Magnetic measurements show that antiferromagnetic interactions were present between the adjacent metal ions via the syn–anti carboxylate bridges. The antiferromagnetic coupling between low-spin Fe(III) and Ni(II) is unusual, which has been tentatively assigned to the structural distortion of Fe(III). 相似文献
5.
新型双核铜金属配合物为中性载体的硫氰酸根离子高选择性电极的研究 总被引:8,自引:0,他引:8
研制了基于N,N'-亚乙基(μ-5,5-亚甲基-二水杨醛根)(乙酰丙酮根)合二铜(II) [Cu2(II)-MDSBAE]金属配合物为中性载体的阴离子选择性电极. 试验表明, 以Cu2(II)-MDSBAE金属配合物为中性载体的电极对SCN-具有良好的电位响应特性, 且呈现反Hofmeister行为,其选择性序列为: SCN->Sal->I->ClO4->NO3->Br->NO2->Cl-≈SO32->SO42-. 在pH 5.0的磷酸盐缓冲体系中, 电极电位呈现近能斯特响应, 线性响应范围为1.0×10-6~1.0×10-1 mol/L, 斜率为-53. 6 mV/dec (25 ℃), 检测下限为8.1×10-7 mol/L. 用交流阻抗研究了电极的响应机理, 并用紫外可见光谱技术测定了电极载体与SCN-, Sal-, I-, ClO4-和NO3-离子间的配位数及缔合常数. 将该电极用于实验室废水和工业废水中硫氰酸根的检测, 其结果令人满意. 相似文献
6.
Ai-Li Cui Guo-Xing Feng Ya-Fan Zhao Hui-Zhong Kou Hong Li Guang-Hua Zhu Ho-Soon Hwang Hee-Chang Oh Young-Jin Kwon Doo-Chul Lee 《Electrochemistry communications》2009,11(2):409-412
Electrochemical oxidation of graphite anode in deionized water at galvanostatic mode is investigated. It is found that mellitic acid and graphite oxide colloid (>20 nm) are coexisted as main products, as identified by XRD and TEM, FTIR and XPS. They can be separated successfully through several procedures. A few amounts of graphene and graphene rolls are also appeared as co-products. 相似文献
7.
We use the modified Hermitian and skew-Hermitian splitting (MHSS) iteration method to solve a class of complex nonsymmetric singular linear systems. The semi-convergence properties of the MHSS method are studied by analyzing the spectrum of the iteration matrix. Moreover, after investigating the semi-convergence factor and estimating its upper bound for the MHSS iteration method, an optimal iteration parameter that minimizes the upper bound of the semi-convergence factor is obtained. Numerical experiments are used to illustrate the theoretical results and examine the effectiveness of the MHSS method served both as a preconditioner for GMRES method and as a solver. 相似文献
8.
In this paper, it is shown that every norm continuous linear local derivation from an arbitrary CSL algebra whose lattice is generated by finitely many independent nests into any ultraweakly closed subalgebra which contains the algebra is an inner derivation, and that every norm continuous linear local derivation from an arbitrary CSL algebra whose lattice is completely distributive into any ultraweakly closed subalgebra which contains the algebra is a derivation. 相似文献
9.
10.