全文获取类型
收费全文 | 327篇 |
免费 | 13篇 |
国内免费 | 3篇 |
专业分类
化学 | 179篇 |
力学 | 4篇 |
数学 | 67篇 |
物理学 | 93篇 |
出版年
2023年 | 2篇 |
2021年 | 2篇 |
2019年 | 6篇 |
2018年 | 2篇 |
2017年 | 6篇 |
2016年 | 9篇 |
2015年 | 12篇 |
2014年 | 8篇 |
2013年 | 12篇 |
2012年 | 15篇 |
2011年 | 23篇 |
2010年 | 19篇 |
2009年 | 8篇 |
2008年 | 21篇 |
2007年 | 8篇 |
2006年 | 27篇 |
2005年 | 11篇 |
2004年 | 12篇 |
2003年 | 11篇 |
2002年 | 11篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1991年 | 11篇 |
1990年 | 10篇 |
1989年 | 7篇 |
1988年 | 1篇 |
1987年 | 4篇 |
1984年 | 6篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 7篇 |
1976年 | 2篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 9篇 |
1972年 | 2篇 |
1970年 | 4篇 |
1966年 | 1篇 |
1941年 | 1篇 |
1920年 | 2篇 |
排序方式: 共有343条查询结果,搜索用时 15 毫秒
1.
A method using capillary gel electrophoresis with laser-induced fluorescence detection is described which permits complete sequence determination of antisense DNA analogues of unknown sequence. This method, originally created as a tool to confirm the sequence of antisense oligonucleotides being developed as therapeutic drugs, utilizes data collected under a range of experimental conditions described by the Ogston model as applied to gel electrophoresis. A linear relationship independent of experimental conditions between the relative electrophoretic migration time and the oligonucleotide base number was observed and is shown to be consistent with a simplified version of this model and can be used to facilitate the sequence determination. 相似文献
2.
3.
Soderstrom E McKenna JA Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(25):2980-2983
4.
Komamiya S Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gatto C Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(24):2881-2884
5.
Aharon Liebersohn David H. Kohn 《Journal of polymer science. Part A, Polymer chemistry》1974,12(10):2435-2447
Copolymers of styrene with α-cyanocinnamamide were prepared by free radical initiation in bulk and in DMF solution and also by thermal initiation in bulk. The copolymerization parameters were determined by the conventional scheme of copolymerization and by an improved scheme taking into account the penultimate unit. Different values of the copolymerization parameters were obtained at the above mentioned different polymerization conditions, indicating the existence of a solvent effect. The influence of the comonomer on some of the basic properties, like intrinsic viscosity, solubility, melting range, and glass transition temperature and on some mechanical and behavior properties of the copolymers was studied in comparison with homopolystyrene. 相似文献
6.
Na5AlF2(PO4)2: Synthesis, Crystal Structure and Ionic Conductivity Two different procedures (precipitation from aqueous solution and solid state reaction) for the synthesis of hitherto unknown Na5AlF2(PO4)2 were optimized. The crystal structure was determined using diffractometer data (P3 , a = b = 10.483(1), c = 6.607(1) Å, MoKα, 1080 independent reflections, Rw = 0.025). PO4-tetrahedra and AlO4F2-“octahedra” are connected via common vertices forming a twodimensionally extended heteropolyanion. Sodium is located in interconnected spacings of the [AlF2(PO4)2]-part of the structure. Ionic conductivity as expected because of these structural features was affirmed experimentally. 相似文献
7.
Harpeness R Peng Z Liu X Pol VG Koltypin Y Gedanken A 《Journal of colloid and interface science》2005,287(2):678-684
A rapid polyol process for the synthesis of ruthenium nanoparticles was developed using microwave irradiation. A colloidal solution of monodispersed anisotropic Ru metal nanoparticles (mean particle size 2-6 nm) with different aspect ratios was obtained first. Particles with different degrees of agglomeration have also been synthesized using monodisperse particles as seeds and PVP (poly-N-vinyl-2-pyrrolidone) as the stabilization reagent. The stabilization mechanisms of different protective reagents were studied by UV-vis spectra. The HRTEM images indicated that dendritic particles formed by controlling agglomeration consisted of single-crystal domains with a random crystalline orientation. 相似文献
8.
Semiconductor alpha-MoTe2 nanorods have been synthesized by annealing Te-seeded particles of an amorphous MoTe2 intermediate. This intermediate is prepared by a solution reaction between Mo(CO)6 and elemental Te in diphenylmethane. The as-synthesized products were characterized by structural, compositional, and morphological techniques of X-ray diffraction, selected area electron diffraction, selected area energy dispersive spectroscopy, energy dispersive X-ray analysis, X-ray photoelectron spectroscopy, transmission electron microscopy, and high-resolution transmission electron microscopy. The results of the annealing process are MoTe2 nanorods with diameters of 50-200 nm and lengths ranging from 0.1 to 3.0 microm. Here, the rodlike structure of MoTe2 is reported for the first time, and added to the list as one kind of new morphology of MoTe2 nanomaterials. A mechanism for the formation of the nanorods is proposed. The sandwich-layered structure of Te-Mo-Te and the similarity in the structure between hexagonal alpha-MoTe2 and hexagonal Te are responsible for the formation of nanorods of MoTe2. 相似文献
9.
In this article we give an existence theorem for localized travelling wave solutions on one-dimensional lattices with Hamiltonian $$H = \sum\limits_{n \in \mathbb{Z}} {\left( {\tfrac{1}{2}p_n^2 + V(q_{n + 1} - q_n )} \right)} ,$$ whereV(·) is the potential energy due to nearest-neighbour interactions. Until now, apart from rare integrable lattices like the Toda latticeV(φ)=ab ?1(e ?bφ+bφ?1), the only evidence for existence of such solutions has been numerical. Our result in particular recovers existence of solitary waves in the Toda lattice, establishes for the first time existence of solitary waves in the (nonintegrable) cubic and quartic latticesV(φ)= 1/2φ 2 + 1/3aφ 3,V(φ) = 1/2φ 2 + 1/4bφ 4, thereby confirming the numerical findings in [1] and shedding new light on the recurrence phenomena in these systems observed first by Fermi, Pasta and Ulam [2], and shows that contrary to widespread belief, the presence of exact solitary waves is not a peculiarity of integrable systems, but “generic” in this class of nonlinear lattices. The approach presented here is new and quite general, and should also be applicable to other forms of lattice equations: the travelling waves are sought as minimisers of a naturally associated variational problem (obtained via Hamilton's principle), and existence of minimisers is then established using modern methods in the calculus of variations (the concentration-compactness principle of P.-L. Lions [3]). 相似文献
10.