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The use of a laboratory-made iodide ion-selective electrode with tubular configuration and based on a crystalline membrane (AgI/Ag2S) as the detector for ion chromatographic determination of iodide in urine and serum is described. A CIS reversed-phase column was coated withN-cetylpyridinium chloride to prepare a low-exchange-capacity analytical column and with hexadecyltrimethylammonium bromide to prepare a concentrator pre-column. A 2.0 ml min–1 flow rate of deionized water and 0.1 mol 1–1 KNO3 solution was used for the pre-concentration and for the chromatographic separation, respectively. For optimum performance of the detector a background level of iodide was added into the column effluent. A linear relationship (r = 0.9997) between tubular electrode potential (as peak height) and iodide concentration in the range 5–400 g 1–1 and a detection limit of 1.47 g 1–1 were obtained. The method shows good reproducibility for both peak height (2.2% RSD) and retention time (1.3% RSD). Recoveries on its application to the samples were 93.0–100.9% for urine and 91.4–106.0% for serum. 相似文献
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Rodrigues Filipe Agra Agostinho Hvattum Lars Magnus Requejo Cristina 《Journal of Heuristics》2021,27(3):459-496
Journal of Heuristics - Proximity search is an iterative method to solve complex mathematical programming problems. At each iteration, the objective function of the problem at hand is replaced by... 相似文献
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Gomes João Pedro Agra Mourão Eduard David Simões dos Anjos Janaina Versiani de Alencar Filho Edilson Beserra 《Structural chemistry》2020,31(6):2501-2512
Structural Chemistry - In this paper, we present a quantitative structure–activity relationships modelling for two series of heterocyclic synthetic compounds with larvicidal activity against... 相似文献
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J. Agostinho Moreira A. Almeida M.R. Chaves J.M. Machado da Silva S.M.F. Vilela 《Solid State Communications》2011,151(5):368-371
This work reports an experimental investigation of the ferroelectric character of magnetic phases of the orthorhombic Eu1−xY xMnO3 system at low temperatures. The temperature dependence of the polarization curves clearly reveals the existence of a re-entrant improper ferroelectric phase for x=0.2, 0.3 and 0.5. A ferroelectric phase is also stable for x=0.4, and we have no experimental evidence for its vanishing down to 7 K. From these and early results obtained using other experimental techniques, the corresponding (x,T) phase diagram was traced, yielding significant differences with regard to the ones previously reported. 相似文献
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Lúcio AS Almeida JR Barbosa-Filho JM Pita JC Branco MV Diniz Mde F Agra Mde F da-Cunha EV da Silva MS Tavares JF 《Molecules (Basel, Switzerland)》2011,16(8):7125-7131
Phytochemical investigation of Anaxagorea dolichocarpa Sprague & Sandwith led to isolation of three azaphenanthrene alkaloids: eupolauramine, sampangine and imbiline 1. Their chemical structures were established on the basis of spectroscopic data from IR, HR-ESI-MS, NMR (including 2D experiments) and comparison with the literature. Sampangine and imbiline 1 are being described in the Anaxagorea genus for the first time. Eupolauramine and sampangine show concentration-dependent antitumoral activity in leukemic cells K562 with IC(50) of 18.97 and 10.95 μg/mL, respectively. 相似文献
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J. P. B. Silva K. C. Sekhar A. Almeida J. Agostinho Moreira M. Pereira M. J. M. Gomes 《Applied Physics A: Materials Science & Processing》2013,113(2):379-384
BaTiO3 thin films were deposited by pulsed laser deposition on Pt–Si at different laser pulse repetition frequencies. X-ray diffraction spectra show that preferred oriented films can be grown by adjusting the pulse repetition frequency. Enhanced dielectric and ferroelectric properties obtained in films deposited at 1 Hz is attributed to preferred orientation, low strain and homogeneous grain distribution. The films deposited at 1 Hz show an impressive remanent polarization of 21.4 μC/cm2 with a coercive field of 70.0 kV/cm. The shift in Curie temperature, which stems from changing the laser pulse repetition frequency, is associated with the strain state in the film. 相似文献
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Description of 2-integer continuous knapsack polyhedra 总被引:1,自引:0,他引:1
In this paper we discuss the polyhedral structure of several mixed integer sets involving two integer variables. We show that the number of the corresponding facet-defining inequalities is polynomial on the size of the input data and their coefficients can also be computed in polynomial time using a known algorithm [D. Hirschberg, C. Wong, A polynomial-time algorithm for the knapsack problem with two variables, Journal of the Association for Computing Machinery 23 (1) (1976) 147–154] for the two integer knapsack problem. These mixed integer sets may arise as substructures of more complex mixed integer sets that model the feasible solutions of real application problems. 相似文献
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ABSTRACT A systematic investigation on the influence of the diffusion parameters (time and temperature) and initial titanium film thickness on the spectral characteristics of the LiNbO3 Raman modes is reported. Raman spectra are measured in the range 50–1000 cm?1 ~2 µm below the surface of the crystals. Broadening of the Raman lines and, therefore, crystal lattice disorder induced by the titanium ions are found to depend on the fabrication parameters. The disorder associated with the titanium ions near the surface of LiNbO3 is encoded in the broadening of the A1(TO1) Raman line. A linear relation between the A1(TO1) mode broadening and the Ti concentration is presented. The diffusion theory is used to explain the experimental data. Raman spectroscopy combined with diffusion theory can be used to estimate the evolution of the titanium surface concentration. 相似文献