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排序方式: 共有864条查询结果,搜索用时 15 毫秒
1.
Photoisomerisation in Aminoazobenzene‐Substituted Ruthenium(II) Tris(bipyridine) Complexes: Influence of the Conjugation Pathway
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Dr. Anissa Amar Dr. Paul Savel Dr. Huriye Akdas‐Kilig Dr. Claudine Katan Prof. Hacène Meghezzi Prof. Abdou Boucekkine Dr. Jean‐Pierre Malval Dr. Jean‐Luc Fillaut 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):8262-8270
Transition‐metal complexes containing stimuli‐responsive systems are attractive for applications in optical devices, photonic memory, photosensing, as well as luminescence imaging. Amongst them, photochromic metal complexes offer the possibility of combining the specific properties of the metal centre and the optical response of the photochromic group. The synthesis, the electrochemical properties and the photophysical characterisation of a series of donor–acceptor azobenzene derivatives that possess bipyridine groups connected to a 4‐dialkylaminoazobenzene moiety through various linkers are presented. DFT and TD‐DFT calculations were performed to complement the experimental findings and contribute to their interpretation. The position and nature of the linker (ethynyl, triazolyl, none) were engineered and shown to induce different electronic coupling between donor and acceptor in ligands and complexes. This in turn led to strong modulations in terms of photoisomerisation of the ligands and complexes. 相似文献
2.
The template condensation of acetoacetic-2-pyridylamide with amino aliphatic alcohols such as 2-aminoethanol (HL1) and 3-amino propanol (HL2) in the presence of copper(II) ions gave octahedral complexes, which have been characterized by elemental analyses, u.v.-vis. and i.r. spectra, conductivity, d.t.a, magnetic and e.s.r. measurements. The molar conductance in DMF indicate that the complexes are non-ionic in character. The e.s.r. spectra of solid complexes (2) and (5) at room temperature indicate axial type symmetry (dx2-y2) with covalent bond character. 相似文献
3.
The presence of copper atoms as continuous networks at the grain boundaries of an aluminium-copper alloy has been considered not preventing the moving of dislocations during creep (or at least partially). The dislocations can bs absorbed by these boundaries and penetrate through them. That leads to changés of shape and structure of grains and also to the sliding of grains against each other. This was deduced from the accelerating increase in the sensitivity of the steady state creep rate to the applied stress of an aluminium 2·8 wt% copper alloy examined at wide range of temperatures (50–350 °C) and applied stresses (7–170 MPa). This rapid increase in the sensitivity parameter of the steady state creep rate occurs in Al-Cu alloys at quite higher ranges of applied stresses and may be attributed mainly to the contribution of the grain boundary movements to the creep strain. 相似文献
4.
In this paper we use real analysis techniques to establish a new real Paley-Wiener theorems for the Fourier-Bessel transform associated with the Weinstein operator. More precisely we characterize the C ∞-functions whose image under the Fourier-Bessel transform are functions with compact support through an L p growth condition, p ∈ [1, +∞] and we give another version of the real Paley-Wiener theorem for L 2-functions. 相似文献
5.
J. -Ph. Jay J. Ben Youssef H. Le Gall 《Journal of magnetism and magnetic materials》2002,240(1-3):287-290
The dynamic response of trilayer magnetoresistive permalloy/Cu/Co films was studied by high-frequency permeability spectra measurements. The resonance frequency is shown to depend on the interlayer copper thickness. This dependence is related to exchange coupling between permalloy and cobalt and the interaction field is estimated using the Landau–Lifschitz–Gilbert model. 相似文献
6.
Youssef Randjiou 《Journal of Theoretical Probability》2006,19(3):701-720
Let μ+(t) and μ−(t) be the locations of the maximum and minimum, respectively, of a standard Brownian motion in the interval [0,t]. We establish a joint integral test for the lower functions of μ+(t) and μ−(t), in the sense of Paul Lévy. In particular, it yields the law of the iterated logarithm for max(μ+(t),μ−(t)) as a straightforward consequence. Our result is in agreement with well-known theorems of Chung and Erdős [(1952) Trans. Amer. Math. Soc. 72, 179–186.], and Csáki, F?ldes and Révész [(1987) Prob. Theory Relat. Fields
76, 477–497].
相似文献
7.
Youssef Saab 《Journal of Heuristics》1997,3(3):207-224
A heuristic optimization methodology, Dynamic Contraction (DC), is introduced as an approach for solving a wide variety of hard combinatorial problems. Contraction is an operation that maps an instance of a problem to a smaller instance of the same problem. DC is an iterative improvement strategy that relies on contraction as a mechanism for escaping local minima. As a byproduct of contraction, efficiency is improved due to a reduction of problem size. Effectiveness of DC is shown through simple applications to two classical combinatorial problems: The graph bisection problem and the traveling salesman problem. 相似文献
8.
Youssef Z. Boutros Mina B. Abd-el-Malek Nagwa A. Badran Hossam S. Hassan 《Applied Mathematical Modelling》2007
The non-linear equations of motion describing the laminar, isothermal and incompressible flow in a rectangular domain bounded by two weakly permeable, moving porous walls, which enable the fluid to enter or exit during successive expansions or contractions, are considered. We apply Lie-group method for determining symmetry reductions of partial differential equations. Lie-group method starts out with a general infinitesimal group of transformations under which given partial differential equations are invariant, then, the determining equations are derived. The determining equations are a set of linear differential equations, the solution of which gives the infinitesimals of the dependent and independent variables. After the group has been determined, a solution to the given partial differential equation may be found from the invariant surface condition such that its solution leads to similarity variables that reduce the number of independent variables in the system. Effect of the permeation Reynolds number Re and the dimensionless wall dilation rate α on self-axial velocity have been studied both analytically and numerically and the results are plotted. 相似文献
9.
Wafaa M. Abdou Neven A. Ganoub Amin F. Fahmy Abeer A. Shaddy 《Monatshefte für Chemie / Chemical Monthly》2006,46(10):105-116
Two simple and efficient one-pot procedures for the synthesis of a series of α-branched N-heterocycle-substituted methane-1,1-bisphosphonates
are outlined. In the first method, the parent halosubstrates were reacted with cyanomethylphosphonate followed by reaction
with dialkyl phosphonates to give asymmetrical or symmetrical bisphosphonates (BPs). In the second approach, the same halocompounds were reacted with tetraethyl methyl-1,1-bisphosphonate to give the requisite
BPs. Partial and complete hydrolysis of the prepared BPs were also investigated. The products contain functional groups advantageous for further synthetic modification as structural
units for coupling with the drug. 相似文献
10.