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1.
Mohamed El Guendouzi Abderrahim Dinane Abdelfetah Mounir 《Journal of solution chemistry》2002,31(2):119-129
The mixed aqueous electrolyte system of ammonium and lithium chlorides has been studied by the hygrometric method at 25°C. The relative humidities of this system are measured at total molalities from 0.3 to 6 mol-kg– 1 for different ionic-strength fractions y of NH4Cl with y = 0.33, 0.50, and 0.67. The data obtained allow the deduction of new water activities and osmotic coefficients. The experimental results are compared with the predictions of the ECA (extended composed additivity) law proposed in our previous work. The Zdanovskii–Stokes–Robinson (ZSR), the Robinson–Stokes (RS), Reilly–Wood–Robinson (RWR), the Pitzer, and the Lietzke–Stoughton (LS II) models are also compared with our results. Predictions made using these models are, in general, consistent with our results. From these measurements, new Pitzer mixing ionic parameters are determined and used to predict the solute activity coefficients in the mixture for different ionic-strength fractions. 相似文献
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N. Daryabari T. Akbarzadeh M. Amini R. Miri H. Mirkhani A. Shafiee 《Journal of the Iranian Chemical Society》2007,4(1):30-36
The new analogues of nifedipine, in which 2-nitrophenyl group at position 4 is replaced by phenylisoxazolyl substituent, were synthesized. The symmetrical dialkyl 1,4-dihydro-2,6-dimethyl-4-(5-phenylisoxazol-3-yl)pyridine-3,5-dicarboxylates were prepared by classical Hantzsch condensation, and the asymmetrical analogues were synthesized using a procedure reported by Dagnino that involved the condensation of alkyl acetoacetate with alkyl 3-aminocrotonate and 5-phenylisoxazole-3-carboxaldehyde. The structure of all compounds was confirmed by IR, 1H NMR and Mass spectra. In vitro calcium channel antagonist activities were evaluated as calcium channel antagonists using the high K+ concentration of guinea-pig ileum longitudinal smooth muscle (GPILSM) assay. These compounds exhibited moderate calcium antagonist activity (IC50 = 10?7 to 10? 5 M range) relative to the reference drug nifedipine (IC50 = 1.10 ± 0.40 × 10?8 M). 相似文献
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Abdelfetah Mounir Mohamed El Guendouzi Abderrahim Dinane 《Journal of solution chemistry》2002,31(10):793-799
Ternary aqueous solutions of MgSO4 and K2SO4 have been studied by the hygrometric method at 25°C. The relative humidity of this system is measured at total molalities from 0.35 mol-kg–1 to about saturation for three ionic-strength fractions (y = 0.25, 0.50, and 0.80 of MgSO4. The data allow calculation of water activities and osmotic coefficients. From these measurements, the Pitzer ionic mixing parameters are determined and used to predict the solute activity coefficients in the mixture. The results are used to calculate the excess Gibbs energy at total molalities for ionic-strength fraction y. 相似文献
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Raoudha Abderrahim Belgacem Baccar et Mohamed Lamine Benkhoud 《Phosphorus, sulfur, and silicon and the related elements》2013,188(5):1033-1040
The reaction of hexamethylphosphotriamide or methylphosphonic bis(dimethylamide) compounds with amidines derived from N-Benzimidazoyl imidates 1 leads to (1,2a)benzimidazolo-1,3,5,2-tiazaphosphorine-2-oxides 4 in good yields. If the condensation is realized at room temperature, N-phosphonic amidines 3 can be isolated as intermediates. The isolated compounds 2 , 3 , and 4 are identified by spectroscopic methods: IR, 1 H, 13 C, 31 P, NMR, and M.S. 相似文献
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Cellulose - The electrical conductivity of cotton fabrics was enhanced using an in situ synthesis of graphene or polymerization of conductive polymer. The impact of conductive materials... 相似文献
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Begaa Samir Messaoudi Mohammed Ouanezar Abdelkader Hamidatou Lylia Malki Abderrahim 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(2):1107-1112
Journal of Radioanalytical and Nuclear Chemistry - The objectives of this research were to study the elemental concentrations of Mentha spicata L., using a sensitive nuclear analytical technique... 相似文献
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Reaction of ethyl chloroformate and acyl chlorides with iminoesters derived from 2- aminobenzimidazole, followed by Grignard reagent condensation leads to a variety of oxadiazinobenzimidazoles in good yield. 相似文献