溶胀后的弹性印章进行毛细微模塑

用溶胀后的聚二甲基硅氧烷弹性印章进行毛细微模塑,得到了聚苯乙烯丙酮溶液的微四方点阵图案．较少的PS溶液滴加量会造成孤立不相连的微点阵图形．同时还获得了由于在收缩过程中各部分溶剂挥发速度不一造成的特殊的微点阵图案．     

溴代丙酮酸乙酯的新合成法

溴代丙酮酸乙酯的新合成法黄锦霞，徐章煌，方国苏（湖北大学化学系武汉４３００６２）溴代丙酮酸乙酯是一种重要的化学物质，广泛用于医药、农药及天然产物的合成中［１］。它的合成已报道的有三条路线￣［２－４］，这些方法存在的不足之处是：（１）收率均不高（分别为...     

西印度蔗螟聚集信息素次要组份合成方法的改进

2-甲基-4-庚醇和2-甲基-4-辛醇是西印度蔗螟(Metamasiushemipterus)聚集信息素的次要组份，本文以天然产物(S)-亮氨酸为原料合成出了2-甲基-4-庚醇及2-甲基-4-辛醇的所有对映异构体，其关键步骤是由(2S)-4-甲基-1,2-戊二醇合成出(2S)和(2R)-4-甲基-1,2-环氧戊烷两种重要中间体，目标产物光学纯度可达95%以上。     

Study on the Phase Diagram of CsCl-CeCl3-HCl(11%)-H2O System and the Properties of the Compounds

The equilibrium solubility of CsCl-CeCl3-HCl(11%)-H2O qua-ternary system at 25℃ has been determined by the physicchemical analysis method ,and the phase diagram was plotted, Two new double salts 3CsCl.CeCl3.3H2O and CsCl.CeCl3.4H2O obtained from the complicated system were identified and characterized by XRD,TG-DTA ,DSC,UV and fluorescence spectroscopy, Studies on the fluorescence excitation and emission show that 3CsCl.CeCl3.3H2O and CsCl.CeCl3.4H2O have upconversion luminescence of infrared-visible range,and the upconversion emission intensity increases with the increase of ratio of CeCl3 in CsCl.     

手性亚砜法合成粉 虫性信息素

5-氯-2-戊酮(2)经四步反应制得(R)-(+)-4-甲基-3-戊烯基对甲苯基亚砜(6), 化合物6与乙醛进行不对称加成反应得手性醇(7), 7经兰尼镍还原性脱硫反应即合成出目标产物粉 虫性信息素(1), 其光学纯度可达45%。     

铌酸锂单晶光纤包层研究

通过镁离子内扩散铌酸锂单晶光纤，以改变晶纤表层的折射率，首次在国内实现了沿不同轴向生长、不同掺杂的铌酸锂单晶光纤的芯－包层波导结构。通过匹配扩散温度、扩散时间、ＭｇＯ膜厚等扩散参数及选择合适的晶纤直径，实现了晶纤具有阶跃和抛物折射率分布的包层，并对包层晶纤的模式特性进行了观察，得到低次模传输。     

立体选择性地合成非洲蔗螟性信息素E-(+ -)-Eldanolide

本文立体选择性地合成了非洲蔗螟性信息素E-(+ -)-Eldanolide.关键的关环步骤产率达到54.0% . 产物经气相色谱法测定, 顺,反异构体之比为8:92. 本合成方法具有路线较短, 产率较高, 反应条件温和等优点. 最终产物及中间体的结构经IR, ^1H NMR 和MS谱学数据证实.     

超高效液相串联质谱法检测牛肉中的马肉

利用超高效液相串联质谱法(UPLC-MS/MS)对牛肉中牛血清白蛋白(BSA)和马肉中马血清白蛋白(ESA)经胰蛋白酶消化后的目标肽进行鉴定,采用多反应监测(MRM)方法对结果进行验证,建立了一种检测牛肉中掺杂马肉的方法.对UPLC-MS/MS数据的深入研究表明,共检测到9个牛特异性多肽和17个马特异性多肽.其中DAFLGSFLYEYSR(m/z 784.3,Charge 2+)和ADFAEVSK(m/z 433.7,Charge 2+)的质谱响应最好,被选为牛肉和马肉定量的靶肽.所建方法在5.5～550.0和4.875～487.5 mg/L范围内线性关系较好(r~20.99),检测限、选择性、精密度、回收率和稳定性完全满足分析要求.     

Projectile fragment emission in the fragmentation of 56Fe on C,Al and CH2 targets at 471 A MeV

The emission angle and the transverse momentum distributions of projectile fragments produced in the fragmentation of 56Fe on CHs, C and A1 targets at 471 A MeV are measured. It is found that for the same target, the average value and width of the angular distribution decrease with an increase of the projectile fragment charge; for the same projectile fragment, the average value of the distribution increases and the width of the distribution decreases with increasing the target charge number. The transverse momentum distribution of a projectile fragment can be explained by a single Gaussian distribution and the averaged transverse momentum per nucleon decreases with the increase of the charge of projectile fragment. The cumulated squared transverse momentum distribution of a projectile fragment can be explained well by a single Rayleigh distribution. The temperature parameter of the emission source of the projectile fragment, calculated from the cumulated squared transverse momentum distribution, decreases with the increase of the size of the projectile fragment.