Formation of quaternary all-d-metal Heusler alloy by Co doping fcc type Ni2MnV and mechanical grinding induced B2-fcc transformation

The structure of the all-d-metal alloy Ni$_{50-x}$Co$_{x}$Mn$_{25}$V$_{25}$ ($x = 0$-50) is investigated by using theoretical and experimental methods. The first-principles calculations indicate that the most stable structure of the Ni$_{2}$MnV alloy is face-centered cubic (fcc) type structure with ferrimagnetic state and the equilibrium lattice constant is 3.60 Å, which is in agreement with the experimental result. It is remarkable that replacing partial Ni with Co can turn the alloy from the fcc structure to the B2-type Heusler structure as Co content $x > 37$ by using the melting spinning method, implying that the d-d hybridization between Co/Mn elements and low-valent elements V stabilizes the Heusler structure. The Curie temperature $T_{\rm C}$ of all-d-metal Heuser alloy Ni$_{50-x}$Co$_{x}$Mn$_{25}$V$_{25}$ ($x > 37$) increases almost linearly with the increase of Co due to that the interaction of Co-Mn is stronger than that of Ni-Mn. A magnetic transition from ferromagnetic state to weak magnetic state accompanying with grinding stress induced transformation from B2 to the dual-phase of B2 and fcc has been observed in these all-d-metal Heusler alloys. This phase transformation and magnetic change provide a guide to overcome the brittleness and make the all-d-metal Heusler alloy interesting in stress and magnetic driving structural transition.     

R3中四面体的Bonnesen型等周不等式

该文主要研究R3中四面体的Bonnesen型与逆Bonnesen型等周不等式.对于R3中给定的四面体,利用其表面积、体积、内切球半径及外接球半径之间的关系,构造出两个重要的几何不等式,得到了四面体的一些Bonnesen型等周不等式与等周不等式的新的简单证明.更进一步地,通过讨论四面体等周亏格的上界估计,获得了两个用内切...     

Unpinning the spiral waves by using parameter waves

The spiral waves anchored to heterogeneous areas are more difficult to control and eliminate than freely rotating ones in homogenous mediums. To eliminate pinned spiral waves, the resistant force should be provided to resist the pinning force. Other than advection field, we introduce parametric wave to play the role of providing resistant force. It is found that the parametric wave with large enough amplitude and proper frequency can unpin and eliminate the spiral wave successfully. The capability of parametric wave in providing resistant force is dependent on its amplitude and frequency sensitively. On the basis of parametric wave, the dependence of pinning force on the size and level of heterogeneity is further confirmed.     

高功率超级电容器用介孔炭电极材料

以纳米CaCO3为模板、蔗糖为前躯体制备超级电容器用介孔炭电极材料.材料的结构由氮吸附、TEM表征,借助恒流充放电、循环伏安和交流阻抗评价了其在6 mol.L-1KOH电解液中的电化学电容性能.结果表明,蔗糖基介孔炭的比表面积606 m2/g,富含10~30 nm的介孔.恒流放电法测得介孔炭在电流密度50 mA/g下的比电容为125 F/g,大电流倍率性能特别突出.电流密度增大到20 000 mA/g,比电容还保持有88F/g,远高于进口电容炭,该介孔炭是一种很有前景的高功率超级电容器炭电极材料.