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采用水淬的方法获得了Pd41Ni10Cu28P21大块非晶合金.结果表明,这一合金体系具有很强的玻璃形成能力,其约化的玻璃转变温度Trg为0.714.结构分析显示,Pd41Ni10Cu28P21非晶合金比以往所报道的Pd40Ni40P20非晶具有更接近于"冻结"液态的密堆积结构.非晶的晶化实验表明,晶化初期多种晶相同时结晶析出.低于710K退火非晶样品,亚稳相形成,继续提高退火温度亚稳相消失.此外,从热力学和动力学角度就Cu部分替代Ni对合金的玻璃形成能力的影响进行了探讨. 相似文献
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We investigate the uniaxial-pressure dependence of resistivity for URu2-x Fex Si2 samples with x=0 and 0.2,which host a hidden order (HO) and a large-moment antiferromagnetic (LMAFM) phase,respectively.For both samples,the elastoresistivity ζ shows a seemingly divergent behavior above the transition temperature T0 and a quick decrease below it.We find that the temperature dependence of ζ for both samples can be well described by assuming the uniaxial p... 相似文献
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Advanced high-pressure transport measurement system integrated with low temperature and magnetic field 下载免费PDF全文
We briefly introduce a new high-pressure transport measurement system integrated with low temperature and magnetic field that is being established as one of the user experimental stations of the Synergetic Extreme Condition User Facilities in the Huairou District of Beijing, China. To demonstrate the capabilities of the system for condensed matter research,the emergence of some pressure-induced phenomena and physics related to superconductivity found previously is also introduced, and then a perspective for such an advanced high-pressure system is presented. 相似文献
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Kinetics of the glass Transition of the Zr41Ti14Cu12.5Ni10Be22.5 Alloy Solidified in a Drop Tube 下载免费PDF全文
Droplets of Zr41Ti14Cu12.5Ni10Be22.5 glass-forming alloy with different sizes are solidified in a drop tube containerless process.The glass transition temperature Tg of Zr41Ti14Cu12.5Ni10Be22.5 glassy spheres solidified with different cooling rates is investigated by using a differential scanning calorimeter.It was found that all the amor phous spheres show an increase of Tg with the heating rate.The glassy spheres have a unique value for the glass transition activation energy Eg=435.50kJ/mol,which is independent of cooling rate q.The insensitivity of Tg to q is interpreted by an extension of the free volume model for flow. 相似文献
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Transition metal dichalcogenides, featuring layered structures, have aroused enormous interest as a platform for novel physical phenomena and a wide range of potential applications. Among them, special interest has been placed upon WTe_2 and MoTe_2, which exhibit non-trivial topology both in single layer and bulk as well as pressure induced or enhanced superconductivity. We study another distorted IT material NbTe_2 through systematic electrical transport measurements. Intrinsic superconductivity with onset transition temperature(T_c~(onset)) up to 0.72 K is detected where the upper critical field(H_c) shows unconventional quasi-linear behavior,indicating spin-orbit coupling induced p-wave paring. Furthermore, a general model is proposed to fit the angledependent magnetoresistance, which reveals the Fermi surface anisotropy of NbTe_2. Finally, non-saturating linear magnetoresistance up to 50 T is observed and attributed to the quantum limit transport. 相似文献
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Zr41Ti14Cu12.5Ni10Be22.5bulk metallic glass (BMG) is annealed at 573 K under 3 GPaand its structural relaxation is investigated by X-ray diffraction, ultrasonic study, compression as well as sliding wear measurements. It is found that after the ZrTiCuNiBe BMG sample was annealed under high pressure, the mechanical properties were improved. Moreover, the BMG with relaxed structure exhibits markedly different acoustic properties. These results are attributed to the fact that relaxation under high-pressure results in a microstructural transformation in the BMG. 相似文献
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超导体在压力的作用下会产生原子间距的缩小,进而导致晶格参数的改变,甚至能使其原子排列规律变化,引发结构相变.超导体的超导电性是一种演生现象,是由超导体中所包含的电荷、自旋、轨道、晶格等多种相互作用的自由度所决定的.因此,当超导体在外部压力作用下发生晶体结构的变化,通常都会引起超导电性的改变,尤其超导转变温度的变化.本文介绍近年发现的一类能够抵御大变形的超导体(robust super-conductivity against volume shrinkage, RSAVS)——这类超导体在压力作用下,即使发生很大的体积压缩,其超导转变温度仍保持不变.这种奇异的能抵御压缩变形的稳定超导电性最初是在对高熵合金的高压研究中观察到的,后续研究发现在广泛应用的商业化NbTi合金以及Nb, Ta等金属元素超导体中也具有这种可抵御大变形的超导电性.分析结果显示,这类超导体都具有体心立方晶体结构,并由过渡族金属元素构成.这种超导体的发现为统一理解“什么因素决定了超导体的超导转变温度?”这一关键问题提出了新的研究课题和挑战. 相似文献
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通过二次离子质谱仪(SIMS)研究了Mo在Zr57Nb5Cu15.4Ni12.6Al10非晶合金中的扩散,并计算出其扩散激活能Q和前置系数D0分别为1.95 eV和1.13×10-5 m2s-1.根据Stokes-Einstern关系式研究了玻璃转变温度以下593-673 K之间Zr57Nb5Cu15.4Ni12.6Al10非晶合金的黏滞特性,得到的黏滞系数从593 K的1.07×1010Poise降到673 K的1.42×108 Poise. 相似文献