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利用直流磁控溅射技术在玻璃衬底上沉积了TiO2薄膜,并对其进行了Co离子注入,最后在真空中500 ℃退火50 min,得到系列薄膜样品. 利用剥离-分散方法制备了薄膜的透射电镜样品,并用扫描电镜(SEM)、X射线能量散射谱(EDX)和高分辨透射电镜(HRTEM)对样品做了近似原位观察,研究了薄膜样品中不同Co离子注入深度的成分分布和显微结构. 结果表明,薄膜呈锐钛矿结构,Co元素主要分布在薄膜表层,Co离子的注入使TiO2薄膜的晶粒被部分破坏,并形成CoO,而5
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2薄膜')" href="#">Co注入TiO2薄膜
电镜原位观察
室温铁磁性 相似文献
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Preparation, structure and ferromagnetic properties of the nanocrystalline Ti1-xMnxO2 thin films grown by radio frequency magnetron co-sputtering 下载免费PDF全文
This paper reported that the Mn-doped TiO2 films were prepared by radio frequency (RF) magnetron cosputtering. X-ray diffraction measurements indicate that the samples are easy to form the futile structure, and the sizes of the crystal grains grow big and big as the Mn concentration increases. X-ray photoemlssion spectroscopy measurements and high resolution transmission electron microscope photographs confirm that the manganese ions have been effectively doped into the TiO2 crystal when the Mn concentration is lower than 21%. The magnetic property measurements show that the Ti1-xMnxO2 (x = 0.21) films are ferromagnetic at room temperature, and the saturation magnetization, coercivity, and saturation field are 16.0 emu/cm^3, 167.5 × 80 A/m and 3740 × 80 A/m at room temperature, respectively. The room-temperature ferromagnetism of the films can be attributed to the new futile Ti1-xMnxO2 structure formed by the substitution of Mn^4+ for Ti^4+ into the TiO2 crystal .lattice, and could be explained by O vacancy (Vo)-enhanced ferromagnetism model. 相似文献
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黄土隧道开挖中的变形与稳定是重要的工程问题,为探索黄土隧道台阶法施工中的围岩变形规律,以巴准铁路敖包沟隧道出口段的施工为例,采用数值模拟和现场实测对敖包沟隧道台阶法施工过程进行了分析,为隧道支护与加固提供依据。研究表明,拱顶下沉与水平收敛在隧道上台阶开挖后变形较大,地表沉降槽影响范围主要集中在距隧道中线20m范围内,且地表沉降主要由上台阶开挖引起,从拱顶到地表的地层沉降规律是沉降值从拱顶到地表呈由大到小,变化为先急后缓的曲线分布态势。 更多还原 相似文献
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