STUDIES ON ION IMPLANTATION AND ELECTRICAL PROPERTIES OF POLYACETYLENE FILMS

The effects of ion implantation on ployacetylene films PA have been studied with Ar~+, Fe~+, C1~+, I~+, Na~+ and K~+ ions in the energy range of 15—30 keV. The changes of PA films in the electrical conductivity, due to chemical doping and ion implantation in relation to their structure and depth profiles of impurities, were measured through infrared (ATR/FTIK), Rutherford backscattering spectrometry (RBS) and the four probe technique. In all cases, ion implantation of active ions exhibits the same effects as chemical doping. The formation of p-n junction is observed at the interface of implanted region and chemical doped PA substrate. The mechanism of interaction process between ion beam and polymer is also discussed.     

微量元素与中医辩证分型

通过对两间小学639名学生进行微量元素检测及体格检查，并进行中医辩证分型，发现广州市部份小学生体内微量元素缺乏较严重，占体检总人数的62．3％，同时也存在营养不良，贫血、佝偻病，急慢性上呼吸道炎等、按中医辩证分型有肝热、脾气虚弱、肝血不足、肾气虚等，本文试从微量元素缺乏与中医辩证中找出两者之间的联系，以便于指导治疗，提高小学生的健康水平，增强体质和智力。     

Highly Efficient One-Pot Synthesis of 2-Arylmethyl N-Substituted Anilines via Yb（OTf）3 Catalyzed Three-Component Reaction

An efficient method has been developed for one-pot three-component coupling reactions of various aldehydes, 1-cyclohexen-2-one, and primary or secondary amines in the presence of a catalytic amount of Yb（OTf）3 under mild conditions to afford the corresponding 2-arylmethyl N-substituted anilines in good yields. In addition, the catalyst was easily recovered and could be reused for at least four cycles without any loss of activity.     

热力强迫下斜压大气的多平衡态与副热带高压

本文用Lorenz的湿模式,在低谱简化下得到了描述大气运动的非线性耗散系统,讨论了在热力强迫与大气环流的非线性相互作用下,湿、斜压大气在参数空间的多平衡态与副热带高压冬、夏流型的转换及其东西振荡,并与相应的干模式进行比较。结果表明:副热带高压冬、夏流型的转换是一种不连续跳跃现象,是经过流场上的快速调整重建新的流型的过程。在干模式中反映不出副热带高压中心的东西摆动,而在湿模式中,由于引入了水汽的热力效应,体现了流场与加热场的非线性相互作用,促成了副热带高压中心的东西摆动。     

Alkaloids from Fritillaria Hupehensis

Phytochemical investigation of the bulbs of Fritillaria hupehensis resulted in the isolation and structural elucidation of a new highly conjugated alkaloid of veratramine type identified as 3β,23β-dihydroxy-7,12（14）-dien-5α- veratramin-6-one （1）, together with two known alkaloids, ebeinine （2） and zhebeinine （3）, which were isolated for the first time from F. hupehensis. The structures of alkaloids 1-3 were established by extensive 1D and 2D NMR spectral analyses.     

羧甲基羟丙基纤维素溶液流变性质的研究

用旋转粘度计研究了羧甲基羟丙基纤维素(CMHPC)复合醚水溶液在25～80℃温度范围内的热稳定性,以及水溶液和盐溶液的流变性质。借助阿氏(Arrheaius)方程得到的CMHPC粘流活化能介于离子型羧甲基纤维素醚(PAC)和非离子型纤维素醚(HEC)之间。研究发现,CMHPC体系中羧甲基含量较高时流动曲线类似PAC,符合Ostwad-Der Waele幂律模型,而羟丙基含量较高时,流动曲线类似HEC,偏离幂律模型。在CMHPC水溶液中加入小分子电解质时,羧甲基受屏蔽,流变行为主要受羟丙基的影响,曲线将发生偏离。本文还考察了CMHPC溶液的抗盐能力。     

GFAAS法基体改进剂对氯化物背景干扰清除及机理

本文探讨了石墨炉原子吸收光谱法(GFAAS)中的酒石酸、草酸和柠檬酸等七类基体改进剂在283.3nm波长氘灯测量方式对氯化物背景吸收干扰的清除效果,认为基体改进剂的作用是与干扰物形成了低沸点的挥发物,并讨论了其形成机理。     

A General, Highly Efficient Ullmann C-O Coupling Reaction under Microwave Irradiation and the Effects of Water

A general, rapid and highly efficient method for the synthesis of diaryl ethers under the assistance of microwave irradiation was described. A series of diaryl ethers were prepared by direct coupling of phenols and aryl halides in good to excellent yields in anhydrous DMF or NMP at 150 ℃ within 20 rain. The presence of water was found to have a significant impact on the Ullmann C-O coupling reaction between aryl halides and phenols under microwave irradiation.     

Ni添加对0.4Zr0.1V1.1Mn0.5Cr0.1合金的相结构和电化学性能的影响

本文通过XRD、SEM、EDS研究了Ti_0.4Zr_0.1V_1.1Mn_0.5Cr_0.1Ni_x(x=0，0.2，0.4，0.6，0.8)合金的相结构和电化学性能。该合金系由BCC结构的V基固溶体主相和六方结构的C14 Laves第二相组成，Ni能够促进第二相的生成，Ni含量的增加导致了各相中的化学组成和晶格参数的变化，并通过电化学方法研究了Ni含量对_0.4Zr_0.1V_1.1Mn_0.5Cr_0.1合金电极的最大放电容量、自放电性能、高倍率放电性能、循环稳定性能等的影响。     

《有机化学》是本好书

由蒋硕健、丁有骏、李明谦三位同志编写的《有机化学》一书,是在近年来为北京大学生物系生化等专业和中国医科大学医预科进行教学的基础上,吸取了近二十年来有机化学发展的新成果,逐步修改编写而成的.这部书与现已出版的同类书比较,有一个显明的特点,这就是它加强了有机化合物命名的内容.该书根据1980年有机化合物命名修订建议介绍了我国命名的原则.同时在书后简单介绍了有机化合物的英文命名,包括IUPAC的系统命名与美国化学文摘上使用的系统命名.这对学生查阅文摘、书刊、字典等有很大帮助.