Preparation and properties of ZnMoO4 anode materials with polymer network gel method

Polymer network gel method combines the advantages of solid-phase method and liquid phase method, triggering acrylamide (AM) radical polymerization in aqueous solution and N, N′- methylene bis acrylamide (MBAM) active double bond cross-linking reaction, forming polymer chains to form a three-dimensional network. The polymer network space formed by the gel is bound and evenly distributed to the ions in the solution, thereby reducing the contact and aggregation of molecules and achieving the purpose of uniform particle size and small particle size. The principle diagram of network gel is shown in Figure. Using cubic zinc acetate and ammonium molybdate tetrahydrate as raw materials, cubic ZnMoO₄ negative electrode materials were prepared with polymer network gel method. The polymer network gel method has various effects on the structure, morphology and electrochemical properties of materials. Besides, the calcination temperature and calcination time were also the key factors to the electrochemical properties of the materials. In this paper, the effects of the ratio of monomer and crosslinker, calcination temperature and calcination time on ZnMoO₄ materials were studied by single variable method, the preparation process was optimized, and its characterization and electrochemical tests were carried out. After 100 cycles, the optimized ZnMoO₄ electrode has a discharge capacity of 374.0 mAh· g^?1, 332.5, 263.5 and 177.1 mAh · g^?1 at current densities of 0.1, 0.5, 1.0 and 2.0 A g^?1, respectively. The electrochemical results show that the optimized ZnMoO₄ has high capacity, large rate capability and excellent cycle stability.     

A simultaneous space sampling method for DNA fraction collection using a comb structure in microfluidic devices

Fraction collection of selected components from a complex mixture plays a critical role in biomedical research, environmental analysis, and biotechnology. Here, we introduce a novel electrophoretic chip device based on a signal processing theorem that allows simultaneous space sampling for fractionation of ssDNA target fragments. Ten parallel extraction channels, which covered 1.5-mm-long sampling ranges, were used to facilitate the capturing of fast-moving fragments. Furthermore, the space sampling extraction made it possible to acquire pure collection, even from partly overlapping fragments that had been insufficiently separated after a short electrophoretic run. Fragments of 180, 181, and 182 bases were simultaneously collected, and then the recovered DNA was PCR amplified and assessed by CE analysis. The 181-base target was shown to be isolated in a 70-mm-long separation length within 10 min, in contrast to the >50 min required for the 300-mm-long separation channel in our previous study. This method provides effective combination of time and space, which is a breakthrough in the traditional concept of fraction collection on a chip.     

On-chip fraction collection for multiple selected ssDNA fragments using isolated extraction channels

High efficiency and high-purity fraction collection is highly sought in analysis of fragments-of-interest from selective polymerase chain reaction (PCR) products generated by High Coverage Gene Expression Profiling (HiCEP) methods. Here we demonstrate a new electrophoretic chip device enabling automatic high-efficient fractionation of multiple ssDNA target fragments during a run of separation. We used thoroughly isolated extraction channels for each selected target to reduce the risk of cross-contamination between targets due to cross-talk of extraction channels. Fragments of 35, 108 and 138 b, were successfully isolated, then the recovery was PCR-amplified and assessed by capillary electrophoresis (CE) analysis. Total impurity level of the targets due to unwanted fragments of 0.7%, 2% and 6% respectively, was estimated. Difficulties in collecting multiple target factions are due to band diffusion and DNA adsorption to the walls for the fragments in the separation channel, which is generated by transferring the DNA target fraction from the extraction section to the target reservoir. Therefore, we have carefully measured band broadening and analyzed its influence on the separation resolution due to the delay.     

Boron-Containing Lipids and Liposomes: New Conjugates of Cholesterol with Polyhedral Boron Hydrides

A series of boron-containing lipids were prepared by reactions of cyclic oxonium derivatives of polyhedron boranes and metallacarboranes (closo-dodecaborate anion, cobalt and iron bis(dicarbollides)) with amine and carboxylic acids which are derived from cholesterol. Stable liposomal formulations, on the basis of synthesized boron-containing lipids, hydrogenated soybean l -α-phosphatidylcholine and (HSPC) 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[methoxy(polyethylene glycol)-2000] (DSPE-PEG) as excipients, were prepared and then characterized by dynamic light scattering (DLS) that revealed the formation of particles to be smaller than 200 nm in diameter. The resulting liposomal formulations showed moderate to excellent loading and entrapment efficiency, thus justifying the design of the compounds to fit in the lipid bilayer and ensuring ease of in vivo use for future application. The liposomal formulations based on cobalt and iron bis(dicarbollide)-based lipids were found to be nontoxic against both human breast normal epithelial cells MCF-10A and human breast cancer cells MCF-7.     

Hydrogen Bonding Deduced α and β Polymorphs of Bis(tetrabutylammonium) Bis(cyclohexylammoinum) β-Octamolybdate, [β-Mo<Subscript>8</Subscript>O<Subscript>26</Subscript>]<Superscript>4−</Superscript>

Abstract  

The title compound, (C₆H₁₄N)₂(C₁₆H₃₆N)₂[β-Mo₈O₂₆] crystallizes in two polymorphs due to different hydrogen bonding self-assembly structures in the solid state. The two polymorphs are of same symmetry and similar cell parameters and inside them the octamolybdate anions are linked to form chains through pairs of N–H···O hydrogen bonds. Minor differences of the conformation of octomolybdate anions and the hydrogen bonding attach positions in the two crystals result in the two polymorphs.     

Simultaneous Fenton‐like Ion Delivery and Glutathione Depletion by MnO2‐Based Nanoagent to Enhance Chemodynamic Therapy

Chemodynamic therapy (CDT) utilizes iron‐initiated Fenton chemistry to destroy tumor cells by converting endogenous H₂O₂ into the highly toxic hydroxyl radical (^.OH). There is a paucity of Fenton‐like metal‐based CDT agents. Intracellular glutathione (GSH) with ^.OH scavenging ability greatly reduces CDT efficacy. A self‐reinforcing CDT nanoagent based on MnO₂ is reported that has both Fenton‐like Mn²⁺ delivery and GSH depletion properties. In the presence of HCO₃^?, which is abundant in the physiological medium, Mn²⁺ exerts Fenton‐like activity to generate ^.OH from H₂O₂. Upon uptake of MnO₂‐coated mesoporous silica nanoparticles (MS@MnO₂ NPs) by cancer cells, the MnO₂ shell undergoes a redox reaction with GSH to form glutathione disulfide and Mn²⁺, resulting in GSH depletion‐enhanced CDT. This, together with the GSH‐activated MRI contrast effect and dissociation of MnO₂, allows MS@MnO₂ NPs to achieve MRI‐monitored chemo–chemodynamic combination therapy.     

NUMERICAL STUDY ON DYNAMIC STALL FLOW CONTROL FOR WIND TURBINE AIRFOIL USING PLASMA ACTUATOR 1)

针对动态失速引起的风力机翼型气动性能恶化的问题,本文基于动网格和滑移网格技术, 开展了大涡模拟数值计算研究,探索了非定常脉冲等离子体的动态流动控制机理. 结果表明,等离子体气动激励能够有效控制翼型动态失速, 改善平均和瞬态气动力,减小力矩负峰值和迟滞环面积. 压力分布在等离子体施加范围内出现了负压"凸起",上翼面吸力峰值明显增大.脉冲频率和占空比这两个非定常控制参数对流动控制影响显著,无因次脉冲频率为1.5时等离子体控制效果较好,占空比为0.8时即可接近连续工作模式下的气动收益. 翼型深失速状态,等离子体促使流动分离位置明显向后缘移动, 抵抗了大尺度动态失速涡的发生,分离涡结构破碎耗散、重新附着, 涡流影响范围减小; 浅失速状态,等离子体激励具有较强的剪切层操纵能力, 诱导了翼型边界层提前转捩,促进了与主流的动量掺混. 等离子体气动激励诱导出前缘附近贴体翼面"涡簇",起到了虚拟气动外形的作用.不同尺度、频域的动态涡结构与等离子体气动激励的非线性、强耦合作用导致了气动力/力矩的谐波振荡.     

Study on the Synthesis of β-FeOOH by the Microemulsion Method

Monoclinic-FeOOH with: a = 0.9981 nm, b = 0.2948 nm, n = 1.0485 nm, β = 92.26° was synthesized by the hydrolysis of FeCl₃ · 6H₂O in micro emulsion including NP-4, octane, water. In this paper, the various morphology and size of the nano particles under different conditions are discussed, and it is found that the optimum conditions for synthesizing acicular β-FeOOH is that R = 6.0, [Fe³⁺] = 0.02 mol/L within the pH range 1.6–2.0. The text was submitted by the authors in English.     

Anderson型杂多酸作为催化剂在有机合成中的应用

Anderson型杂多酸（通式为[XM₆O₂₄]^n－）是一类具有特殊结构和性质的多金属-氧簇无机化合物,由于其分子结构易于化学修饰和可设计性以及其在材料、催化和医药等领域具有很高的应用价值,因此一直受到研究者们的广泛关注.近几年来,Anderson型杂多酸在催化有机氧化反应中的应用对于绿色催化过程的研究逐渐显露出非常重要的意义.本综述对Anderson型杂多酸在有机合成反应中的催化应用进行了相关的调研,根据Anderson型多金属氧酸盐的结构分类对这些工作进行了归纳概述与总结.这将为Anderson型杂多酸的催化应用以及为绿色催化的研究提供新的思路.     

Dynamical modulating the directional excitation of surface plasmons sources

We demonstrate two methods to dynamically modulate the directional excitation of surface plasmons (SPs) in subwavelength slits structure by embedding nonlinear media or introducing oblique incidence. Finite-difference time-domain method simulation shows that the electromagnetic field intensity, patterned by the interference of two SPs waves along the exit interface, can be arbitrarily tailored by adjusting the phase difference between the two slits. The modulation of SPs has the potential application for all-optical SPs switch.