测定亚硝酸根的表面活性剂增敏催化动力学光度法

基于在稀硫酸介质中溴化十六烷基三甲基铵对ＮＯ２－催化溴酸钾氧化曙红褪色反应的作用，建立了测定ＮＯ－２的表面活性剂增敏催化动力学光度法。加入十六烷基三甲基溴化铵（ＣＴＭＡＢ）后体系最大吸收波长由４８０ｎｍ红移至５４０ｎｍ，ΔＡ增大约２０倍。ΔＡ与ＮＯ－２含量在００１～０２ｍｇ／Ｌ范围内存在线性关系，检出限为０００４ｍｇ／Ｌ。方法已用于水样中ＮＯ－２测定，结果满意     

Quantum dots modified with the Al(III)-pefloxacin complex as a novel bioprobe for the sensitive turn-on and dual-fluorescence detection of dsDNA

Microchimica Acta - We describe a novel fluorescent bioprobe for the sensitive and selective detection of double-stranded DNA (dsDNA). It consists of quantum dots (Q-dots) whose fluorescence is...     

Ag@AgBr光催化剂的制备及其可见光催化降解亚甲基蓝反应性能

采用沉积-沉淀及光还原法制备了Ag@AgBr等离子体光催化剂,利用X射线衍射、扫描电镜和紫外-可见漫反射光谱对其进行了表征,并考察了该等离子体光催化剂在可见光(λ420nm)下的催化性能,探讨了催化剂用量、pH值、亚甲基蓝初始浓度、H2O2添加量、循环使用及捕获剂对Ag@AgBr催化性能的影响.结果表明,当亚甲基蓝的初始浓度为10mg/L,催化剂用量为1g/L,pH=9.8时,光照12min后,亚甲基蓝的降解率高达96%,且样品经5次循环使用后活性基本保持不变;而少量H2O2的添加对光催化活性影响不大,过量的H2O2会降低光催化活性;乙二胺四乙酸捕获空穴后比异丙醇捕获·OH后的光催化活性降得更低.同时,对Ag@AgBr等离子体光催化剂可见光降解亚甲基蓝的催化机理进行了分析.     

The study on microstructure and electrochemical properties of Al–Mg–Sn–Ga–Pb alloy anode material for Al/AgO battery

The microstructure of Al–Mg–Sn–Ga–Pb quinary aluminum alloy anode material and the influences of its electrochemical properties and self-corrosion rate in 4 mol/l NaOH +10 g/l Na₂SnO₃ medium were studied. The microstructure and morphology were characterized by metallographic microscope, transmission electron microscope, and scanning electron microscopy. The electrochemical properties were tested by electrochemical workstation, and the self-corrosion rate of Al alloy anode was studied by methods of recovery H₂ gas by discharge water. The results show that homogenization has not much impact on the electrochemical properties and the corrosion rate of the cast aluminum alloy anode material; besides, return annealing treatment of the cold-rolled Al–Mg–Sn–Ga–Pb quinary aluminum alloy anode material can reduce the rate of self-corrosion and make Al anodic potential shift negative steadily and improve the properties of the material.

     

High spatial resolution distributed strain sensor based on linear chirped fiber Bragg grating and fiber loop ringdown spectroscopy

A simple sensor system for high spatial resolution distributed strain field measurement is proposed and demonstrated experimentally. The fiber loop ringdown technique combined with a linear chirped fiber Bragg grating is used to realize the high spatial resolution. A proof-of-concept distributed strain sensor with 2?mm spatial resolution is realized. The sensor network is also explored and researched experimentally. The proposed technique suggests a broad range of applications for real-time distributed physical parameter sensing, such as strain or temperature.     

多级孔WO3/ZrO2固体酸催化剂的制备与表征

采用复合模板表面活性剂辅助水热法一步合成了WO3/ZrO2多级孔固体酸催化剂,并应用X射线衍射、低温N2吸附-脱附、拉曼光谱及NH3程序升温脱附对催化剂进行了表征.结果表明,WO3的引入使得WO3/ZrO2催化剂的比表面积增大,表面的酸中心明显增加.在乙酸和正丁醇的酯化反应中,WO3/ZrO2多级孔固体酸催化剂表现出较...     

高能核－核作用中不同带电强子快度分布

在反应体质心系中，依据热化模型并考虑碰撞参量的涨落及核阻止性，对工作在ＢＮＬ／ＡＧＳ上Ｅ－８０２合作组给出的中心和周边Ｓｉ与Ａｕ、Ｃｕ和Ａｌ相互作用的强子快度分布进行了分析和讨论．     

聚合松香中锌含量的火焰原子吸收法直接测试研究

利用９５％乙醇作溶剂，采用火焰原子吸收法直接测定聚合松香中的锌含量，因内未见类似报道，此方法非常适合在林化企业中推广使用。     

高能强子－核作用中快度分布与横能的关联

假定强子－核作用中的产生粒子相对于反应体质心系各向同性衰变，给出了强子－核作用中横能快度分布，计算结果能够解释最新的ＨＥＬＩＯＳ合作组的实验结果．     

Generation of millimeter-wave sub-carrier optical pulse by using cascaded all-pass cavities

A novel scheme is proposed to transform an ultra-short optical pulse to a millimeter-wave frequencymodulated pulse by using the cascaded all-pass cavities （APCs）. The envelope waveform of the generated pulse train is calculated, showing effective improvement by APC cascading. The extinction ratio is analyzed with different input pulses, different cavity reflectivities, and different cascading numbers. It is shown that the cascading does not introduce much effect on the extinction ratio. Two designs by using Gires-Tournois cavity and waveguide ring resonators are proposed to realize the cascaded APC.