高取代度淀粉醋酸酯的制备

改善淀粉热塑性的方法主要是用塑化剂对其进行处理和用化学方法制备淀粉衍生物,使羟基被长链取代,减弱淀粉分子间的氢键,大分子可在较低温度下运动,从而达到降低熔融温度的目的。近年来,对高取代度淀粉醋酸酯已有报道^[1-5],Sagar等^[2]认为,粉酯的取代度越高,侧链越长,热塑性和亲水性的改变就越明显,而且酯基可起到内增塑作用,可塑性的提高反映在材料的流变学,热学及力学性能的改变上,Maheras等^[3]用高取代度的淀粉醋酸酯和纤维素醋酸酯共混,制成了纤维和塑料制品,由于高取代度淀粉醋酸酯熔点较高,Brochers等^[4]提出通过加入分子量为100－1000的增塑剂,如甘油三醋酯等,可使熔融温度降到150℃左右,Tanaka等^[6]将淀粉和乙烯类化合物在酯化催化剂的作用下反应,得到的淀粉酯性能较为理想,分子量高,具有相当好的机械性能和耐水性,国外专利报道了以甲磺酸（MSA）为催化剂制备淀粉醋酸酯的方法^[7},但对其结构和性能尚未作系统的研究,本文以冰醋酸和醋酸酐为混合酸,MSA为催化剂,制得了具有较高取代度的高直链淀粉醋酸酯,并系统研究了反应温度,反应时间,反应物比例等不同反应条件对取代度的影响,通过红外分析,特性粘度测试,溶解性等分析手段,表征了高直链淀粉醋酸酯的结构与性能。     

基于双极性铼配合物的低浓度淬灭电致发光器件

合成了一种含双极性9,9-双(9-乙基咔唑-3-基)-4,5-二氮芴(ECAF)配体的新型三羰基铼配合物Re(CO)3(ECAF)Cl,通过核磁共振氢谱及高分辨质谱对其结构进行了确定。以含有4,5-二氮-9,9-螺二芴(SB)配体的铼配合物Re(CO)3(SB)Cl作为参比物,对比研究了其热稳定性及光电性能。结果表明,与参比物的分解温度(366℃)相比,配合物Re(CO)3(ECAF)Cl有极好的热稳定性(热分解温度419℃)。由于富电子咔唑基团导致的能隙增大,相比参比物的发光波长(572 nm),Re(CO)3(ECAF)Cl的发光波长蓝移至565 nm。Re(CO)3(ECAF)Cl的发光量子效率(39%)稍高于参比物(37%)。以旋涂法制成电致发光器件后,基于Re(CO)3(ECAF)Cl器件的最佳掺杂浓度(质量分数)高达30%,是基于参比物器件的2.4倍,而且开启电压低至2.9 V,明显比参比物器件的4.0 V低,说明ECAF配体能有效抑制发光浓度淬灭,且明显改善了铼配合物的载流子传输性能。基于Re(CO)3(ECAF)Cl器件的最大电流效率及最大外量子效率分别为8.2 cd·A^-1和3.0%,低于参比物器件的9.7 cd·A^-1和3.9%。     

Elastic interactions between multi-valued foldons and anti-foldons for the (2+1)-dimensional variable coefficient Broer–Kaup system in water waves

With the help of the improved tanh-function method, some exact variable separation solutions for a (2+1)-dimensional variable coefficient Broer–Kaup system in water waves are found. The detailed investigation indicates that these seemly independent variable separation solutions actually depend on each other. Based on the exact variable separation solution, completely and noncompletely elastic interactions between multi-valued foldons and anti-foldons are studied analytically and graphically.     

考虑量子效应的Zakharov方程组的孤波解

借助Maple程序，利用扩展的双曲函数法和双函数法求解了考虑量子效应的Zakharov方程组，得到了多种孤波解，其中包括亮孤波解、W型孤波解、M型孤波解和奇性孤波解. 关键词： 量子效应 Zakharov方程组 扩展的双曲函数法 孤波解     

Reconstruction of stability for Gaussian spatial solitons in quintic–septimal nonlinear materials under $${{\varvec{\mathcal {P}}}}{\varvec{\mathcal {T}}}$$ P T -symmetric potentials

Nonlinear Dynamics - Gaussian spatial soliton solutions of both the constant-coefficient and variable-coefficient (2 + 1)-dimensional nonlinear Schrödinger equations in...     

Quassinoids from the Roots of Eurycoma longifolia and Their Anti-Proliferation Activities

A phytochemical investigation on the roots of medicinal plant Eurycoma longifolia resulted in the isolation of 10 new highly oxygenated C₂₀ quassinoids longifolactones G‒P (1–10), along with four known ones (11–14). Their chemical structures and absolute configurations were unambiguously elucidated on the basis of comprehensive spectroscopic analysis and X-ray crystallographic data. Notably, compound 1 is a rare pentacyclic C₂₀ quassinoid featuring a densely functionalized 2,5-dioxatricyclo[5.2.2.0^4,8]undecane core. Compound 4 represents the first example of quassinoids containing a 14,15-epoxy functionality, and 7 features an unusual α-oriented hydroxyl group at C-14. All isolated compounds were evaluated for their anti-proliferation activities on human leukemia cells. Among the isolates, compounds 5, 12, 13, and 14 potently inhibited the in vitro proliferation of K562 and HL-60 cells with IC₅₀ values ranging from 2.90 to 8.20 μM.     

Dynamics of nonlocal and localized spatiotemporal solitons for a partially nonlocal nonlinear Schrödinger equation

Modern methods of nonlinear dynamics including time histories, phase portraits, power spectra, and Poincaré sections are used to characterize the stability and bifurcation regions of a cantilevered pipe conveying fluid with symmetric constraints at the point of contact. In this study, efforts are made to demonstrate the importance of characterizing the system at the arbitrarily positioned symmetric constraints rather than at the tip of the cantilevered pipe. Using the full nonlinear equations of motion and the Galerkin discretization, a nonlinear analysis is performed. After validating the model with previous results using the bifurcation diagrams and achieving full agreement, the bifurcation diagram at the point of contact is further investigated to select key flow velocities of interest. In addition to demonstrating the progression of the selected regions using primarily phase portraits, a detailed comparison is made between the tip and the point of contact at the key flow velocities. In doing so, period doubling, pitchfork bifurcations, grazing bifurcations, sticking, and chaos that occur at the point of contact are found to not always occur at the tip for the same flow speed. Thus, it is shown that in the case of cantilevered pipes with constraints, more accurate characterization of the system is obtained in a specified range of flow velocities by characterizing the system at the point of contact rather than at the tip.     

New Exact Solutions of （1 ＋ 1）-Dimensional Coupled Integrable Dispersionless System

This paper applies the exp-function method, which was originally proposed to find new exact travelling wave solutions of nonlinear evolution equations, to the Riccati equation, and some exact solutions of this equation are obtained. Based on the Riccati equation and its exact solutions, we find new and more generalvariable separation solutions with two arbitrary functions of (1+1)-dimensional coupled integrable dispersionless system. As some special examples, some new solutions can degenerate into variable separation solutions reported in open literatures. By choosing suitably two independent variables p(x) and q(t) inour solutions, the annihilation phenomena of the flat-basin soliton, arch-basin soliton, and flat-top soliton are discussed.     

Spatiotemporal Rogue Waves for the Variable-Coefficient (3+1)-Dimensional Nonlinear Schrödinger Equation

With the help of the similarity transformation connected the variable-coefficient (3+1)-dimensional nonlinear Schrödinger equation with the standard nonlinear Schrödinger equation, we firstly obtain first-order and second-order rogue wave solutions. Then, we investigate the controllable behaviors of these rogue waves in the hyperbolic dispersion decreasing profile. Our results indicate that the integral relation between the accumulated time T and the real time t is the basis to realize the control and manipulation of propagation behaviors of rogue waves, such as sustainment and restraint. We can modulate the value T₀ to achieve the sustained and restrained spatiotemporal rogue waves. Moreover, the controllability for position of sustainment and restraint for spatiotemporal rogue waves can also be realized by setting different values of X₀.