大功率激光制备a-C和a-C∶H类金刚石膜的光学性能研究

采用大功率高重复频率准分子激光溅射热解石墨靶制备了类金刚石碳膜, 研究了实验条件对类金刚石膜光学性能的影响, 发现氢可以提高膜中sp3键的含量和膜的光学透过率. 在实验参数范围内, 膜的光学性能随着氢压的增加而提高. 根据类金刚石膜的反应沉积机理对上述结果进行了分析、解释.     

低压闪蒸液滴形态和温度变化的研究

将液滴在常压下突然置于低压环境中,液滴由最初的平衡状态变成过热状态,发生闪蒸.本文实验研究了低压闪蒸液滴内部形态和温度的变化,系统描述了液滴闪蒸过程中的各种形态变化,总结了稳态闪蒸和稳态结冰过程中环境压力和初始温度对温度变化的影响.实验结果表明液滴闪蒸分六种形态.稳态闪蒸中环境压力越低,液滴的最终温度也越低;液滴的初始温度越高,降到最低温度的时间越长.稳态结冰过程中,液滴初始温度增加,液滴结冰温度和结冰回升最高温度也随之增加;液滴的结冰温度和回升最高温度随环境压力的增高而减小.     

金属配合物(pq)_2Ir(N-phMA)发光材料的合成及光谱性质

设计出一种酰胺类金属铱有机配合物磷光电致发光材料,该材料是以2-苯基喹啉(pq)为主配体,N-苯基甲基丙烯酰胺(N-phMA)为辅助配体的金属配合物(pq)2Ir(N-phMA)。该化合物的结构由核磁,红外表征确定,它在586nm处的强荧光发射,表明它是一种可用于OLED的黄光发光材料。     

光学元件群延迟的直接测量

提出了一种测量群延迟的新方法,利用白光干涉仪产生的光谱干涉,通过时间频率联合分析直接得出群延迟,减小了传统相位差分方法产生的误差,并通过测量结果减去系统背景,进一步提高了光学元件色散测量的准确度. 该方法适合于具有复杂色散光学元件群延迟和色散的准确测量,也适合于慢光器件群速度延迟的测量. 关键词： 色散测量 白光干涉 时间频率分析 超快激光     

Oscillatory disturbance in force calibration of optical tweezers

In the calibration of the optical trap stiffness, it is found that there appears an attenuating oscillation as an oscillatory disturbance added to the trapped bead movement, when the scanner is driven by a triangular wave input.An equivalent oscillator model is put forward to explain the mechanism of the oscillatory disturbance. Both the measurements and calculations show that the attenuating oscillation comes from the oscillation of the scanner and the triangular wave drive causes this additional oscillation of the scanner. Furthermore, the analysis indicates that the oscillatory disturbance will become stronger, when the stiffness of the trap increases or the natural frequency of the scanner decreases. We adopt another driving way, i.e. a sinusoidal wave input is used instead of the triangular wave input. Our experiment has verified that in this case the oscillatory disturbance is eliminated completely.     

Mechanical Properties of Breast Cancer Cell Membrane Studied with Optical Tweezers

Membrane tethers are extracted from breast cancer cells using a force generated by an optical trap. It is experimentally obtained that the radius of tether is about 0.1μm and the static tether force is about 8.5 pN. Calculations based on the experimental measurements give a bending modulus for the tether of 1.35 x 10^-19 N.m and a surface membrane tension of 6.76 x 10^-6 N/m in the breast cancer cell. The treatment with cytochalasin D results in the decreasing bending modulus and decreasing apparent surface tension. When the membrane protein caveolin is over-expressed, similar cases occur in bending modulus and apparent surface tension. In addition, the viscous resistance coefficient of the membrane is calculated to be 1.15pN.s/μm according to the dynamic tether forces obtained under different pulling velocities.     

利用光子统计概率测量单分子光子源的信号背景比

理论上研究了基于Hanbury Brown Twiss 探测方式，利用单光子和双光子统计概率P RS(1),PRS(2),直接测量单分子光子源的信号背景比.在研究过程中同时考 虑到单分子布居于暂稳态和探测器量子效率对测量结果的影响.在满足PRS(1)2 PRS(2)-3PRS(2)的条件时，研究给出了一种有效测量信号背景比的方 法SBR=P2RS(1)/2PRS(2).另外，分析讨论了Mandel参数Q 与信号背景比之间的关系. 关键词： 单分子光子源 信号背景比 光子统计 暂稳态 Mandel参数     

The fine structure levels and spin-singlet contributions to zero-field-splitting parameters of Cr2+ ion in CdGa2S4

A theoretical investigation is reported of the fine structure levels and the spin-singlet contributions to zero-field-splitting (ZFS) parameters for Cr²⁺ ion in CdGa₂S₄ crystals. Firstly, the complete energy matrix including all spin states for a 3d ⁴ ion in tetrahedral D _2d symmetry is constructed according the double-group chain in the strong-field scheme. Then, by diagonalizing the complete energy of electron–electron interactions, the crystal field and the spin–orbit coupling for the Cr²⁺ (3d ⁴) ion in CdGa₂S₄ crystal, the fine structure levels and the spin-singlet contributions to ZFS parameters a, D and F are calculated. The results show that the spin-singlet contribution to D is negligible, but the contributions to a and F are very important. So, to obtain more accurate ZFS parameters for 3d ⁴ ions in the tetrahedral crystals, all spin states should be considered.     

Phase Diagram of Random Field Spin-S Ising Model with a Transverse Field

Random field spin-S Ising model with a transverse field has been studied by making use of the pair approximation with the discretized path-integral representation, and an analytical expression of second-order phase transition is derived for all the symmetric probability distributions of (longitudinal) random fields. The phase diagrams at T = 0 are obtained, and the conditions for existence of tricritical points are examined for an arbitrary number of nearest-neighbor spins.