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1.
Alkynes cycloaddition reactions are powerful tools for constructing cyclic molecules with optimal atom efficiency, but these reactions cannot proceed at ambient temperature without transition-metal catalysts. In this work, a heterobimetallic complex featuring an Nb–Fe triple bond, Nb(iPrNPMe2)3Fe–PMe3, has been evaluated as the potential catalyst for acetylene cycloaddition, using density functional theory. The calculated results show that the singlet-state (i.e. ground-state) Nb(iPrNPMe2)3Fe–PMe3 can be applied to benzene synthesis, but is not suitable for cyclobutadiene. Benzene can be obtained easily at room temperature and is the unique product on the singlet potential surface. The irradiation of infrared-red light can drive the excitation of singlet Nb(iPrNPMe2)3Fe–PMe3 to its triplet state. Both benzene and cyclobutadiene can be formed on the triplet reaction potential surface due to their low energy barriers. Therefore, Nb(iPrNPMe2)3Fe–PMe3 is a potential high reactivity heterobimetallic catalyst for the cyclotrimerization of alkynes. In the reaction process, the catalytic active site of Nb(iPrNPMe2)3Fe–PMe3 moves from niobium to iron. 相似文献
2.
Polymethyl methacrylate (PMMA) is one of the most commonly used optical materials. However, the application of it in the area of optical communication is strongly limited by the intrinsic absorption loss of carbon-hydrogen stretching vibration. In this paper, we present a method to solve the problem by adopting the hollow-core fibers with cobweb cladding structure. The fibers use a single dielectric material and may solve the problem of structural support. Thus the feasibility of the “OmniGuide” fibers is improved, while a series of advantages of the “OmniGuide” hollow-core fiber are retained. It is promising that a fiber with low transmission loss, high bandwidth, large-core, and low costs can be designed and fabricated using PMMA. At the same time, a very broad range of the wavelengths (from visible to near infrared region, for instance, wavelengths at 0.65-1.12 μm, and even 1.30 μm, 1.54 μm and their neighbors) may be adopted for signal wavelength. 相似文献
3.
C.-G. Duan L.-H. Song L.-J. Huo G.-L. Li 《The European Physical Journal C - Particles and Fields》2003,29(4):557-561
The energy loss effect in nuclear matter, which is a nuclear effect apart from the nuclear effect on the parton distribution as in deep-inelastic scattering process, can be measured best by the nuclear dependence of the high energy nuclear Drell-Yan process. By means of the nuclear parton distribution studied only with lepton deep-inelastic scattering experimental data, the measured Drell-Yan production cross sections for 800 GeV proton incident on a variety of nuclear targets are analyzed within the Glauber framework which takes into account the energy loss of the beam proton. It is shown that the theoretical results with considering the energy loss effect are in good agreement with the FNAL E866 data.Arrival of the final proofs: 24 June 2003 相似文献
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Shui Cao ZHENG Huo Nan LIN Di He HU 《数学学报(英文版)》2005,21(5):1137-1148
In this paper, we investigate the Hausdorff measure for level sets of N-parameter Rd-valued stable processes, and develop a means of seeking the exact Hausdorff measure function for level sets of N-parameter Rd-valued stable processes. We show that the exact Hausdorff measure function of level sets of N-parameter Rd-valued symmetric stable processes of index α is Ф(r) = r^N-d/α (log log l/r)d/α when Nα 〉 d. In addition, we obtain a sharp lower bound for the Hausdorff measure of level sets of general (N, d, α) strictly stable processes. 相似文献
6.
利用BUU模型模拟核-核碰撞36Ar+108Ag(35Mev/u)、14N+108Ag(35MeV/u)中的平衡前中子发射.模拟结果与唯象的运动源拟合给出的中等速度源成份相吻合.这说明中等速度源成份产生于核-核碰撞的早期,对应平衡前发射.并从级联碰撞的角度定量地研究了平衡前发射的持续时间 相似文献
7.
Zhao‐Peng Deng Shan Gao Li‐Hua Huo Hui Zhao 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(5):m225-m227
In the title complex, [Mn(SO4)(C3H7NO)(H2O)2]n, each MnII ion has a distorted octahedral geometry formed by three O atoms of three different sulfate groups, one O atom of a dimethylformamide ligand and two water molecules. The sulfate groups act as tridentate bridging ligands connecting the MnII ions into a two‐dimensional layer structure which can be regraded as a 4.82 network. 相似文献
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建立以凝胶渗透色谱法(GPC)和固相萃取法(SPE)及气相色谱法(GC)联用技术测定大豆中10种二硝基苯胺类除草剂(氟乐灵、乙氟灵、环丙氟、氯乙氟灵、仲丁灵、异乐灵、二甲戊乐灵、二硝胺、氨基丙氟灵和磺乐灵)多残留检测方法.目标农药经正己烷饱和的乙腈提取,凝胶渗透色谱除去大豆中大部分油脂及色素,再经Florisil柱净化和富集,依次用6 mL二氯甲烷和6 mL二氯甲烷+丙酮(99+1)洗脱.目标农药采用电子捕获检测(GC/ECD),外标法定量,并经质谱(MS)确证.两个添加水平重复6次,回收率分别为74%~105%和59%~105%;相对标准偏差<20%;检出限为1.8~7.6 μg/kg;定量限为6~38 μg/kg. 相似文献
10.
研究了新显色剂5-(对羧基苯偶氮)-8-羟基喹啉(p-CPHQ)与U(Ⅵ)的显色反应条件,在阳离子表面活性剂CTMAB存在下,pH 4.0~6.0缓冲介质中,形成稳定的红色络合物,最大吸收波长为470nm,ε=4.39×10~4,含U(Ⅵ)量在0~55μg/25ml范围内符合比耳定律,结合TBP萃淋树脂分离富集,并以CyDTA、KF联合掩蔽,方法适用于岩石矿物中痕量铀的测定。 相似文献