全文获取类型
收费全文 | 69篇 |
免费 | 7篇 |
国内免费 | 10篇 |
专业分类
化学 | 53篇 |
晶体学 | 1篇 |
力学 | 3篇 |
综合类 | 2篇 |
数学 | 8篇 |
物理学 | 19篇 |
出版年
2023年 | 4篇 |
2022年 | 1篇 |
2021年 | 4篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 9篇 |
2013年 | 11篇 |
2012年 | 4篇 |
2011年 | 4篇 |
2010年 | 4篇 |
2009年 | 5篇 |
2008年 | 4篇 |
2007年 | 2篇 |
2006年 | 1篇 |
2005年 | 4篇 |
2003年 | 1篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
排序方式: 共有86条查询结果,搜索用时 15 毫秒
1.
Let {X n , n ≥ 1} be a sequence of negatively associated random variables. The aim of this paper is to establish some limit theorems of negatively associated sequence, which include the L p -convergence theorem and Marcinkiewicz–Zygmund strong law of large numbers. Furthermore, we consider the strong law of sums of order statistics, which are sampled from negatively associated random variables. 相似文献
2.
Jin Kai Li Baowei Wang Kaixing Luo Huijuan Gong Zhijun Wu Wenfei 《Research on Chemical Intermediates》2018,44(11):6933-6943
Research on Chemical Intermediates - A rare-earth concentrate obtained from Bayan Obo tailings was used as catalyst for low-temperature selective catalytic reduction (SCR) of NOx. X-ray powder... 相似文献
3.
The first total synthesis of a natural prenylflavanone, (±)-kenusanone B (1) has been achieved by condensation of acetophenone 4 and benzaldehyde 6 followed by cyclization and deprotection. Chloromethyl methyl ether was used as a facile protecting reagent of free hydroxy groups for the synthesis of polyhydroxylated flavanones. 相似文献
4.
DONG Wenfei CHEN Xiaoyu PENG Juan LIU Wanyi JIN Xiaoyong NI Gang LIU Zheng 《高等学校化学研究》2020,36(4):648-661
Ammonia is a commodity chemical with high added value. Electrochemical reduction of nitrogen has great promise for the sustainable synthesis of ammonia in recent years. Because of its rich resources and unique electronic structure and characteristics, 2D transition metal compounds have been used as electrocatalysts for electrochemical reduction of nitrogen for clean and sustainable production of ammonia. This review outlines the latest development in the use of 2D transition metal compounds as high-efficiency electrocatalysts for nitrogen reduction reaction(NRR). First, we introduce the N2 reduction mechanism, and briefly summarize the performance indicators of the catalyst. Then, we focused on the functionalization of unique 2D materials to design high-performance 2D electrocatalysts in respect of simulation calculation and experimental development. Finally, the current challenges and future opportunities for NRR electrocatalysts are introduced. 相似文献
5.
6.
Yong Tang Junjian Xiang Yaoqiang Chen Wenfei He Ning Deng Hongyu Yang 《Analytica chimica acta》2010,657(2):210-214
In the current study, we developed a nanosphere bio-barcode technology to detect trace gonyautoxin 2/3 (GTX 2/3). GTX 2/3-glucose oxidase (GOX) conjugates were first prepared as the coating antigen in a periodate reaction. Subsequently, gold nanoparticles (NP) dual-labeled with anti-GTX 2/3 monoclonal antibodies (Mab) and DNA oligonucleotides were synthesized via a one-step preparation method. Combining PCR with indirect competitive ELISA (icELISA), a novel immunosorbent bio-barcode assay was established utilizing the Mab-NP-dsDNA complex to convert enzymatic signals to DNA signals. Importantly, the limit of detection of the method was lower than 0.74 μg mL−1. Thus, the immunosorbent bio-barcode assay is a rapid and high-throughput screening tool to detect GTX 2/3 in aquatic products. 相似文献
7.
Ruihua Lv Bing Na Wenfei Xu Pingsheng Yu Rong Chen 《Journal of Macromolecular Science: Physics》2013,52(3):449-461
Plane strain compression of isotactic polypropylene iPP)/clay nanocomposite in a channel die at 140 and 160°C, respectively, has been adopted to prepare oriented samples with well-controlled structure for comparative studies. Molecular orientation in the amorphous phase, independent of clay loadings, decreases with increasing preparation temperature, whereas crystallographic orientation is nearly the same for all oriented samples. Severer voiding and void coalescence during stretching, mostly induced by the crystals and inter-chain sliding in the amorphous phase, respectively, is suggested to be responsible for higher volume dilatation and lower failure strain in the oriented samples prepared at higher temperature (e.g., 160°C). Fracture toughness is well correlated with the molecular orientation and crystal-dependent voiding in the oriented samples with respect to preparation temperatures. Furthermore, debonding of clay in the iPP matrix, especially in the oriented samples prepared at 140°C, is another contributor to the enhanced toughness. 相似文献
8.
Liang Jingshuang Yang Yulin Gao Jian Zhou Lei Gao Ming Zhang Zhongyuan Yang Wenfei Javid Muhammad Jung Youngguan Dong Xinglong Cao Guozhong 《Journal of Solid State Electrochemistry》2019,23(3):735-748
Journal of Solid State Electrochemistry - Polymorphic Si-Cu nanocomposites of Si@Cu3Si nanowires, Si@Cu3Si nanorods, and Si@Cu3Si(Cu) nanocapsules are synthesized via the high-energy arc-discharge... 相似文献
9.
Zinc-fingers, which widely exist in eukaryotic cell and play crucial roles in life processes, depend on the binding of zinc ion for their proper folding. To computationally study the zinc-coupled folding of the zinc-fingers, charge transfer and metal induced protonation/deprotonation effects have to be considered. Here, by attempting to implicitly account for such effects in classical molecular dynamics and performing intensive simulations with explicit solvent for the peptides with and without zinc binding, we investigate the folding of the Cys2His2-type zinc-finger motif and the coupling between the peptide folding and zinc binding. We find that zinc ion not only stabilizes the native structure but also participates in the whole folding process. It binds to the peptide at an early stage of folding and directs or modulates the folding and stabilizations of the component beta-hairpin and alpha-helix. Such a crucial role of zinc binding is mediated by the packing of the conserved hydrophobic residues. We also find that the packing of the hydrophobic residues and the coordination of the native ligands are coupled. Meanwhile, the processes of zinc binding, mis-ligation, ligand exchange, and zinc induced secondary structure conversion as well as the water behavior due to the involvement of zinc ion are characterized. Our results are in good agreement with related experimental observations and provide significant insight into the general mechanisms of the metal cofactor dependent protein folding and other metal-induced conformational changes of biological importance. 相似文献
10.
Qidi Ren Lu Wang Wenfei Qian Baiqiu Chen Qi Shuai Yunfeng Yan 《Macromolecular bioscience》2023,23(7):2300085
RNA interference (RNAi) is a promising approach for disease treatments. But the development of safe and effective delivery carriers remains a major challenge. Organic–inorganic hybrid nanoparticles (NPs), with the integration of functions from distinct materials, show great potential in small interfering RNA (siRNA) delivery. Herein, pH responsive amorphous calcium carbonate NPs (ACC NPs) are prepared using flash nanoprecipitation and hybrid NPs are constructed by coating ACC NPs with polyethyleneimine (PEI) for efficient siRNA delivery. PEI/ACC NPs show robust pH responsiveness and stability as well as effective siRNA loading and protection. Furthermore, siRNA-loaded PEI/ACC NPs demonstrate enhanced cellular uptake and efficient endosomal escape, mediating improved siRNA delivery compared to pure PEI. These findings suggest that PEI/ACC NPs may have great potential in siRNA delivery for RNAi-based therapy. 相似文献