排序方式: 共有35条查询结果,搜索用时 31 毫秒
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Vedat Yılmaz Şenol Kartal 《International journal of environmental analytical chemistry》2015,95(2):106-120
A new Cu(II)-imprinted polymer has been prepared for selective solid-phase extraction of Cu(II) prior to its determination by flame atomic absorption spectrometry. Two functional monomers, 4-(methacryloylamino)benzamide and 4-vinylpyridine, formed a complex with Cu(II) ion through coordination interactions. The self-assembled Cu(II)-monomer complex was copolymerised via bulk polymerisation method in the presence of ethyleneglycoldimethacrylate cross-linker. In order to remove Cu(II) ions, the resulting polymer was washed with 1.0 M HNO3 and then with water until obtaining a neutral pH. The ion imprinted polymer was characterised by Fourier transform infrared. The experimental conditions were optimised for solid-phase extraction of Cu(II) using a column of ion-imprinted polymer (IIP). Quantitative retention was achieved between pH 5.0 and 7.0, whereas the maximum recovery for the non-imprinted polymer (NIP) was about 74% at pH 7.0. The IIP showed higher selectivity to Cu(II) in comparison to the NIP. The IIP also exhibited excellent selectivity for Cu(II) in the presence of other metal ions. The relative standard deviation and limit of detection (3s) of the method were 1.6% and 1.8 µg L?1, respectively. The method was verified by analysis of two certified reference materials (CWW-TM-D and SRM 3280) and then applied to the determination of Cu(II) in seawater and lake water samples and haemodialysis concentrates. 相似文献
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Nezaket ParlakMesut Gür Vedat Ar?Hasan Küçük Tahsin Engin 《Experimental Thermal and Fluid Science》2011,35(1):60-67
In the study, a second law analysis for a steady-laminar flow of water in adiabatic microtubes has been conducted. Smooth microtubes with the diameters between 50 and 150 μm made of fused silica were used in the experiments. Considerable temperature rises due to viscous dissipation and relatively high pressure losses of flow were observed in experiments. To identify irreversibility of flow, rate of entropy generation from the experiments have been determined in the laminar flow range of Re = 20-2200. The second law of thermodynamics was applied to predict the entropy generation. The results of model taken from the literature, proposed to predict the temperature rise caused by viscous heating, correspond well with the experimental data. The second law analysis results showed that the flow characteristics in the smooth microtubes distinguish substantially from the conventional theory for flow in the larger tubes with respect to viscous heating/dissipation (temperature rise of flow) total entropy generation rate and lost work. 相似文献
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Cihan Topcu Gamze Lacin Vedat Yilmaz Fatih Coldur Bulent Caglar Osman Cubuk 《Analytical letters》2018,51(12):1890-1910
A novel copper(II)-selective electrode based on graphite oxide/imprinted polymer composite was developed for the electrochemical monitoring of copper(II) (Cu2+) ions. The electrode exhibited highly selective potentiometric response to Cu2+ with respect to common alkaline, alkaline earth and heavy metal cations. The composite composition studies indicated that the most suitable composite composition performing the most promising potentiometric properties was 20.0% ionophore (Cu2+-ion imprinted polymer), 10.0% paraffin oil, 5.0% multiwalled carbon nanotubes, and 65.0% graphite oxide. The fabricated electrode exhibited a linear response to Cu2+ over the concentration range of 1.0?×?10??6–1.0?×?10??1?M (correlation coefficient of 0.9998) with a sensitivity of 26.1?±?0.9?mV decade??1. The detection limit of the fabricated electrode was determined to be 4.0?×?10??7?M. The electrode worked well in the pH range of 4.0–8.0. The electrode had stable, reversible and fast potentiometric response (3?s). In addition, the electrode had a lifetime of more than 1 year. The analytical applications of the proposed electrode were performed using as an indicator electrode for the potentiometric titration of Cu2+ with ethylene diamine tetraacetic acid solution and for the determination of Cu2+ of spiked river, dam, and tap water samples. The obtained results for potentiometric titration and water samples were satisfactory. 相似文献
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Shaher Momani Vedat Suat Erturk 《Numerical Methods for Partial Differential Equations》2008,24(2):663-669
In this paper, we present a numerical scheme for the solution of viscous Cahn–Hilliard equation. The scheme is based on Adomian's decomposition approach and the solutions are calculated in the form of a convergent series with easily computable components. Some numerical examples are presented. © 2007 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2008 相似文献
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A hydride generation (HG) procedure has been described for determination of Pb by ICP-MS using potassium hexacyanomanganate(III), K3Mn(CN)6, as an additive to facilitate the generation of plumbane (PbH4). Potassium hexacyanomanganate(III) was prepared in acidic medium as it was unstable in water. The stability of hexacyanomanganate(III) was examined in dilute solutions of HCl, HNO3 and H2SO4. The solutions prepared in 1% v/v H2SO4 were found to be stable for over a period of 24 h. The least suitable medium was 1% v/v HNO3. For generation of plumbane, acidic hexacyanomanganate(III) and sample solutions were mixed on-line along a 5-cm long tygon tubing (1.14 mm i.d.) and then reacted with 2% m/v sodium borohydride (NaBH4). A concentration of 0.5% m/v K3Mn(CN)6 facilitated the generation of PbH4 remarkably. In comparison to H2SO4, HCl provided broader working range for which optimum concentration was 1% v/v. No significant interferences were noted from transition metals and hydride forming elements, up to 0.5 μg mL−1 levels, except Cu which depressed the signals severely. The depressive effects in the presence of 0.1 μg mL−1 Cu were alleviated by increasing the concentration of K3Mn(CN)6 to 2% m/v. Under these conditions, the sensitivity was enhanced by a factor of at least 42 to 48. The detection limit (3 s) was 0.008 μg L−1 for 208Pb isotope. Average signal-to-noise ratio (S/N) ranged between 18 and 20 for 1.0 μg mL−1 Pb solution. The accuracy of the method was verified by analysis of several certified reference materials, including Nearshore seawater (CASS-4), Bone ash (SRM 1400), and Mussel tissue (SRM 2976). The procedure was also successfully applied to the determination of Pb in coastal seawater samples by ICP-MS. 相似文献
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Vibration of a variable cross-section beam 总被引:4,自引:0,他引:4
Vibration of an isotropic beam which has a variable cross-section is investigated. Governing equation is reduced to an ordinary differential equation in spatial coordinate for a family of cross-section geometries with exponentially varying width. Analytical solutions of the vibration of the beam are obtained for three different types of boundary conditions associated with simply supported, clamped and free ends. Natural frequencies and mode shapes are determined for each set of boundary conditions. Results show that the non-uniformity in the cross-section influences the natural frequencies and the mode shapes. Amplitude of vibrations is increased for widening beams while it is decreased for narrowing beams. 相似文献
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Goksu Oruc Emine Kesici Gulcin M. Muslu 《Numerical Methods for Partial Differential Equations》2019,35(3):993-1007
We study numerically the semi‐classical limit for three‐coupled long wave–short wave interaction equations. The Fourier–Galerkin semi‐discretization is proved to be spectrally convergent in an appropriate energy space. We propose a split‐step Fourier method in the semi‐classical regime with the discussion of the meshing strategy, which is necessary to obtain correct numerical solution. Plane wave solution with weak and strong initial phases, solitary wave solution and Gaussian solution are considered to investigate the semi‐classical limit. 相似文献
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The change in flow characteristics downstream of a circular cylinder (inner cylinder) surrounded by an outer permeable cylinder was investigated in shallow water using particle image velocimetry technique. The diameter of the inner cylinder and the water height were kept constant during the experiments as d?=?50?mm and h w ?=?25?mm, respectively. The depth-averaged free-stream velocity was also kept constant as U?=?170?mm/s which corresponded to a Reynolds number of Red?=?8,500 based on the inner cylinder diameter. In order to examine the effect of diameter and porosity of the outer cylinder on flow characteristics of the inner cylinder, five different outer cylinder diameters (D?=?60, 70, 80, 90 and 100?mm) and four different porosities (???=?0.4, 0.5, 0.6 and 0.7) were used. It was shown that both porosity and outer cylinder diameter had a substantial effect on the flow characteristics downstream of the circular cylinder. Turbulent statistics clearly demonstrated that in comparison with the bare cylinder (natural case), turbulent kinetic energy and Reynolds stresses decreased remarkably when an outer cylinder was placed around the inner cylinder. Thereby, the interaction of shear layers of the inner cylinder has been successfully prevented by the presence of outer cylinder. It was suggested by referring to the results that the outer cylinder having 1.6????D/d????2.0 and 0.4????D/d????0.6 should be preferred to have a better flow control in the near wake since the peak magnitude of turbulent kinetic energy was considerably low in comparison with the natural case and it was nearly constant for these mentioned porosities ??, and outer cylinder to inner cylinder diameter ratios D/d. 相似文献