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1.
Subhi A. Al-Jibori Afra S. S. Al-Zaubai Modher Y. Mohammed Talal A. K. Al-Allaf 《Transition Metal Chemistry》2007,32(3):281-286
Palladium(II) and platinum(II) complexes containing the mixed ligands tertiary diphosphines Ph2P(CH2)
n
PPh2, (n = 1–4) and benz-1,3-imidazoline-2-thione, benz-1,3-oxazoline-2-thione or benz-1,3-thiazoline-2-thione have been prepared
and characterized by elemental analysis, magnetic susceptibility, molar conductance and i.r. spectral data. 31P–{1H}-n.m.r. data have been applied to characterize the produced linkage isomers. 相似文献
2.
Subhi A. Al-Jibori Ziyad M. Kalay Talal A. K. Al-Allaf 《Transition Metal Chemistry》1994,19(3):293-295
Summary The mixed phosphine-phosphine oxides Ph2P(CH2)n-P(O)Ph2 (n = 1 or 2) react with K2PtCl4 to give cis-{PtCl2-
1-Ph2P(CH2)
n
P(O)Ph2]2}. Treatment of the latter (n = 2) with transition metal chlorides MCl2·nH2O, or with Me2SnCl2, SnCl4·5H2O, Th(NO3)4·xH2O or UO2(NO3)2· 6H2O, gives novel heterobimetallic complexes identified as cis-{PtCl2[-Ph2P(CH2)2P(O)Ph2]2MX2}·nH2O. Attempts to prepare similar heterobimetallic complexes using the starting complexes {PtX2[
1-Ph2PCH2P(O)-Ph2]2} (X = C1), cis- or CN, trans-] were unsuccessful. Possible reasons for this are discussed. 相似文献
3.
Differential pulse polarographic determination of some organotin(IV) compounds in dimethyl sulfoxide
The differential pulse polarographic behavior of two series of organotin(IV) compounds having the general formula RxSnCl4 − x (R = Me, Ph; x = 1, 2, 3, 4) has been investigated in DMSO. The peaks obtained are recommended for the trace determination of these compounds. Linear calibration curves are obtained over the concentration range 10−4 –10−6 M. 相似文献
4.
Unraveling σ and π Effects on Magnetic Anisotropy in cis‐NiA4B2 Complexes: Magnetization,HF‐HFEPR Studies,First‐Principles Calculations,and Orbital Modeling
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Dr. Gaëlle Charron Dr. Elena Malkin Dr. Guillaume Rogez Dr. Luke J. Batchelor Dr. Sandra Mazerat Dr. Régis Guillot Dr. Nathalie Guihéry Dr. Anne‐Laure Barra Dr. Talal Mallah Dr. Hélène Bolvin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(47):16850-16862
By using complementary experimental techniques and first‐principles theoretical calculations, magnetic anisotropy in a series of five hexacoordinated nickel(II) complexes possessing a symmetry close to C2v, has been investigated. Four complexes have the general formula [Ni(bpy)X2]n+ (bpy=2,2′‐bipyridine; X2=bpy ( 1 ), (NCS?)2 ( 2 ), C2O42? ( 3 ), NO3? ( 4 )). In the fifth complex, [Ni(HIM2‐py)2(NO3)]+ ( 5 ; HIM2‐py=2‐(2‐pyridyl)‐4,4,5,5‐tetramethyl‐4,5‐dihydro‐1H‐imidazolyl‐1‐hydroxy), which was reported previously, the two bpy bidentate ligands were replaced by HIM2‐py. Analysis of the high‐field, high‐frequency electronic paramagnetic resonance (HF‐HFEPR) spectra and magnetization data leads to the determination of the spin Hamiltonian parameters. The D parameter, corresponding to the axial magnetic anisotropy, was negative (Ising type) for the five compounds and ranged from ?1 to ?10 cm?1. First‐principles SO‐CASPT2 calculations have been performed to estimate these parameters and rationalize the experimental values. From calculations, the easy axis of magnetization is in two different directions for complexes 2 and 3 , on one hand, and 4 and 5 , on the other hand. A new method is proposed to calculate the g tensor for systems with S=1. The spin Hamiltonian parameters (D (axial), E (rhombic), and gi) are rationalized in terms of ordering of the 3 d orbitals. According to this orbital model, it can be shown that 1) the large magnetic anisotropy of 4 and 5 arises from splitting of the eg‐like orbitals and is due to the difference in the σ‐donor strength of NO3? and bpy or HIM2‐py, whereas the difference in anisotropy between the two compounds is due to splitting of the t2g‐like orbitals; and 2) the anisotropy of complexes 1 – 3 arises from the small splitting of the t2g‐like orbitals. The direction of the anisotropy axis can be rationalized by the proposed orbital model. 相似文献
5.
Dr. Julie Jung M. Ashraful Islam Dr. Vincent L. Pecoraro Dr. Talal Mallah Dr. Claude Berthon Dr. Hélène Bolvin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(66):15112-15122
Two series of lanthanide complexes have been chosen to analyze trends in the magnetic properties and crystal field parameters (CFPs) along the two series: The highly symmetric LnZn16(picHA)16 series (Ln=Tb, Dy, Ho, Er, Yb; picHA=picolinohydroxamic acid) and the [Ln(dpa)3](C3H5N2)3 ⋅ 3H2O series (Ln=Ce–Yb; dpa=2,6-dipicolinic acid) with approximate three-fold symmetry. The first series presents a compressed coordination sphere of eight oxygen atoms whereas in the second series, the coordination sphere consists of an elongated coordination sphere formed of six oxygen atoms. The CFPs have been deduced from ab initio calculations using two methods: The AILFT (ab initio ligand field theory) method, in which the parameters are determined at the orbital level, and the ITO (irreducible tensor operator) decomposition, in which the problems are treated at the many-electron level. It has been found that the CFPs are transferable from one derivative to another, within a given series, as a first approximation. The sign of the second-order parameter differs in the two series, reflecting the different environments. It has been found that the use of the strength parameter S allows for an easy comparison between complexes. Furthermore, in both series, the parameters have been found to decrease in magnitude along the series, and this decrease is attributed to covalent effects. 相似文献
6.
I. Spǎnulescu I. Dima Mohamed Ismail Abd El-Ati N. Bǎlţǎţeanu Talal Khalass 《辐射效应与固体损伤》2013,168(3-4):299-303
The influence of 8 MeV electrons on the crystalline structure of HgTe and Hg1-xCdxTe thin films was studied. HgTe and Hg1-xCdxTe layers were obtained by thermal evaporation and condensation in vacuum on optically flat silica glass substrates heated at different temperatures. One finds that the results of irradiation of HgTe and Hg1-xCdxTe thin films with 8 MeV electrons depend on the preparation conditions of the samples, and therefore on the level of perfection of the crystalline structure and the quantity of nonstoichiometric atoms. 相似文献
7.
The coordination behaviour of the diorganotin (IV) compounds R2SnCl2 (where R = Me, Ph) with 4H-pyrido [1,2-a] pyrimidin-4-one derivatives (L) has been described. The complexes R2SnCl2 · L obtained have been characterized physicochemically and spectroscopically. The pyrimidin-4-one ligands were found to coordinate with R2SnCl2 species in a monodentate fashion, mainly via the oxygen atom of the 4-one group or possibly via the nitrogen atom of the (SINGLE BOND)C(DOUBLE BOND)N linkage (the less sterically hindered nitrogen of the pyrimidine derivative) to give pentacoordinate tin complexes. Of the complexes selected to be screened against five tumour cell lines, some exhibited significant in vitro activity. 相似文献
8.
Influences of nanoparticles and chain length on thermodynamic and electrical behavior of fluorine liquid crystals 下载免费PDF全文
Ines Ben Amor Lotfi Saadaoui Abdulaziz N. Alharbi Talal M. Althagafi and Taoufik Soltani 《中国物理 B》2022,31(10):104202-104202
Hydrogen-bonded polar nematic liquid crystal series with the general formula nOBAF (n = 7—12) is studied. The mesomorphic characterization is demonstrated through differential scanning calorimetry (DSC) and polarized optical microscopy (POM). The complexes with short alkyl chains (n=7, 8) present a wide nematic range and monotropic smectic F mesophase, whereas the longer alkyl chain (n=10—12) analogues show high melting and low clearing mesomorphic liquid crystals. The thermal range of the mesophase and the birefringence increase with chain length decreasing. Furthermore, the effect of the nanoparticles (LiNbO3) on the thermal and the electrical behavior of 8OBAF are investigated. The presence of LiNbO3 nanoparticles increases the conductivity and reduces the resistivity of the complex. 相似文献
9.
The crystal structure of an inorganic linear polymer consisting of Mn(II) and an N-centered tripodal ligand N,N-bis(2-(6-methyl)pyridylmethyl)glycinate is presented (1, C(16)H(20)N(3)O(3)F(6)P(1)Mn(1), a = 9.993(2) A, b = 13.285(3) A, c = 16.040(3) A, orthorhombic, Pnam, Z = 4). The polymeric structure is ensured by carboxylato ligands connecting two Mn(II) in a rather rare syn-anti geometry. The magnetic properties of this infinite chain have been investigated, together with the magnetic properties of a dimeric Mn(II) compound (3) from a closely related ligand [N,N-bis[(1-methylimidazol-2-yl)-methyl)glycinate] involving an unusual bis(monatomic-carboxylato) bridge. The inorganic polymer 1 shows a pseudo-2D magnetic structure, with a major interaction pathway along the chain (J/k = -0.172 +/- 0.005 K) and an interchain minor one (zJ'/k = -0.006 +/- 0.004 K). These properties are reminiscent of those from a closely related previously reported inorganic Mn(II) polymer (2 obtained from manganese(II) and N,N-(2-pyridylmethyl)((1-methylimidazol-2-yl)methyl)glycinate). The dimer 3 shows a small antiferromagnetic coupling of J/k = -0.693 +/- 0.016 K. To address the influence of the carboxylato bridging mode on the magnetic properties, these complexes are compared to a series of compounds involving carboxylato bridges of several geometries between Mn(II) ions. Carboxylato bridges induce usually antiferromagnetic coupling, with the magnitude of the interaction (/J/) increasing with the number of bridges. The J value is dependent on the bridging mode. The syn-syn bridge is an efficient pathway, even by comparison with the monatomic [(mu-eta(1)-carboxylato)] bridge. 相似文献
10.
Mukherjee PS Konar S Zangrando E Mallah T Ribas J Chaudhuri NR 《Inorganic chemistry》2003,42(8):2695-2703
Two novel inorganic-organic hybrid 3D extended networks of Ni(II) and Mn(II) having molecular formulas [(maleate)(2)Ni(3)(bpe)(4)(H(2)O)(4)](NO(3))(2).H(2)O (1) and [(adipate)Mn(bpe)] (2) (bpe = 1, 2-bis(4-pyridyl)ethane), respectively, have been synthesized and characterized by single-crystal X-ray diffraction studies and low-temperature (300-2 K) magnetic measurements. Compound 1 crystallizes in the monoclinic system, space group C2/c (No. 15), with chemical formula C(56)H(62)N(10)Ni(3)O(19), a = 30.955(4) A, b = 12.705(3) A, c = 17.058(5) A, beta = 117.26(2) degrees, and Z = 4. Compound 2 crystallizes in the triclinic system, space group Ponemacr; (No. 2), with chemical formula C(18)H(20)MnN(2)O(4), a = 8.492(2) A, b = 9.444(2) A, c = 11.533(3) A, alpha = 97.19(1) degrees, beta = 94.64(1) degrees, gamma = 105.02(1) degrees, and Z = 2. The structure determination reveals for both a 3D network. Compound 1 contains two crystallographically independent Ni(II) ions in different octahedral environments. Ni(1) lies on an inversion center, and its coordination environment comprises two chelating maleate anions and two bpe nitrogen donors, while the Ni(2) ion is surrounded by meridionally disposed three bpe N atoms, two water molecules, and one oxygen donor from the dicarboxylate anion. Of the three crystallographic independent bpe ligand, one presents an anti and the others a gauche conformation. The corresponding N-to-N distances are 9.344, 6.543, and 6.187 A. Variable-temperature magnetic susceptibility measurement of the complex reveals the existence of a dominant ferromagnetic interaction within the molecule. Compound 2 is composed of Mn(2) dimer units linked by adipate anions to form corrugated 2D sheets which, on interconnection through bpe (anti conformation, N-to-N distance of 9.391 A), produces an interpenetrated 3D alpha-polonium-related type net. Complex 2 reveals to be antiferromagnetic fitting data using a dimeric Mn(II) model that considers negligible magnetic transmission through the carbon skeleton of adipate and the bpe pathway. 相似文献