CrIII-Phthalocyaninate: Darstellung,Eigenschaften und Kristallstruktur von l-Bis(triphenylphosphin)iminium-trans-di(nitrito(O))phthalocyaninato(2–)-chromat(III)

Cr^III Phthalocyaninates: Synthesis, Properties, and Crystal Structure of l-Bis(triphenylphosphine)iminium trans-Di(nitrito(O))phthalocyaninato(2–)chromate(III) [Cr(H₂O)₂Pc^2?]I_x reacts with excess (PNP)NO₂ in dimethylformamide to yield less soluble greenblack l-bis(triphenylphosphine)iminium trans-di(nitrito(O))phthalocyaninato(2–)chromate(III), ^l(PNP)^trans[Cr(ONO)₂Pc^2?], which crystallizes in the triclinic space group P1 (No. 2) with Z = 2. The Cr atom is in the center of the Pc^2? ligand and the two nitrite ions are monodentate O-coordinated in a mutually trans arrangement to the Cr atom. The Cr? O and Cr? N_iso bond distances are 1.9898(14) und 1.981(2) Å, respectively. The geometric data of the coordinated nitrite ion are: d(N? O) = 1.307(2) Å; d(N? O) = 1.205(2) Å; ?(O? N? O) = 113.7(2)°; ?(Cr? O? N) = 116.85(12)°. The non-bonding O atoms are trans to the Cr atom. The Pc^2? ligand is slightly saddled. Three weak spin-allowed trip-quartet(TQ) transitions (in 10³ cm^?1): TQ1 (8.20) < TQ2 (11.3) < TQ3 (20.33) and the characteristic π-π* transitions of the Pc^2? ligand: B (14.68) < Q₁ (27.1) < Q₂ (29.0) < N (35.4) are observed in the UV-VIS-NIR spectrum. Prominent luminescence spectra are obtained by excitation within the TQ1 region, in which the spin-forbidden trip-sextet transition at 7376 cm^?1 dominates at low temperatures (T < 50 K). The vibrational spectra are discussed. In coincidence of the excitation lines with TQ3, v_s(Cr? O) at 378 cm^?1 is selectively resonance Raman (RR) enhanced. v_as(Cr? O) is observed in the FIR spectrum at 391 cm^?1. The following internal vibrations (in cm^?1) of the nitrito ligand are in the MIR spectrum: v_as(N? O)/1447 > v_as(N? O)/1018/1029 > δ(O? N? O)/828 and in the RR-spectrum: v_s(N? O)/1410 > v_s(N? O)/952, the last followed by three overtones.     

3J(PCNH) in phosphorus substituted thioformamides as a configurational probe

Coupling between P and (N)? H has been observed in the ¹H{¹⁴N}NMR spectra of a series of phosphorus substituted thioformamides, R¹₂/P(X)C(S)NHR². For R² = H one of the two couplings constants ³J(PCNH) is much larger than the other. The larger constant is assumed to be ³J(PCNH) (trans) and the magnitude of ³J(PCNH) for several compounds with R² = Me or Ph is used to assign the configuration about the C(S)? N bond.     

The incoherent Raman spectrum of O2 molecular constants from all experimental data

A new incoherent vibration-rotational Raman spectrum of ¹⁶O₂ recorded by means of an interferometer is presented. The measured wavenumbers are analyzed together with a coherent Raman spectrum, six different microwave spectra from the vibrational ground state, and one microwave spectrum from the first vibrationally excited state in one fit. Due to the non-linear energy expression for oxygen, such an analysis requires the use of an iteration to find the minimum for the so-called merit function. A method has been developed to secure a stable iteration. The energy expression originally contains 21 constants. A systematic search leads to a reduction of this to 19 constants to make the fit possible. This results in two solutions, which are, however, only two different ways of indicating the one final energy function. The systematic use of iterations reduces the influence of the computational uncertainty on the final molecular constants to be orders of magnitude lower than the uncertainty due to the experimental errors.     

The multi‐stage centred‐scheme approach applied to a drift‐flux two‐phase flow model

For two‐phase flow models, upwind schemes are most often difficult do derive, and expensive to use. Centred schemes, on the other hand, are simple, but more dissipative. The recently proposed multi‐stage (MUSTA ) method is aimed at coming close to the accuracy of upwind schemes while retaining the simplicity of centred schemes. So far, the MUSTA approach has been shown to work well for the Euler equations of inviscid, compressible single‐phase flow. In this work, we explore the MUSTA scheme for a more complex system of equations: the drift‐flux model, which describes one‐dimensional two‐phase flow where the motions of the phases are strongly coupled. As the number of stages is increased, the results of the MUSTA scheme approach those of the Roe method. The good results of the MUSTA scheme are dependent on the use of a large‐enough local grid. Hence, the main benefit of the MUSTA scheme is its simplicity, rather than CPU ‐time savings. Copyright © 2006 John Wiley & Sons, Ltd.     

Determination of the B0 constant of C6H6

The ν₁₁ infrared band of gaseous benzene C₆H₆ is recorded at a resolution of 0.010 cm^?1. The analysis yields a number of constants, primarily B₀ = 0.1897543 ± 0.0000061 cm^?1 (standard error). This number is in perfect agreement with a value determined from a recent analysis of the ν₁ Raman band.     

Electron detachment and relaxation of OH-(aq)

Femtosecond transient absorption spectroscopy is used to study the primary reaction dynamics of photoinduced electron detachment of the hydroxide ion in water, OH- (aq). The electron is detached by excitation of OH- (aq) to the charge-transfer-to-solvent (CTTS) state at 200 nm. The subsequent relaxation processes are probed in the spectral range from 193 to 800 nm with femtosecond time resolution. We determine both the time-dependent quantum yields of OH- (aq), OH(aq), and e-(aq), and we observe a transient spectral signature which is assigned to relaxation of hot (OH-)* ions formed via solvent-assisted conversion of the excited CTTS state to OH-. The primary quantum yield of OH(aq) is 65 +/- 5%, while recombination with e-(aq) reduces the yield to 34% after 5 ps and 12% after 200 ps. The yield of hot (OH-)* ions is 35 +/- 5%. Rotational anisotropy measurements of OH- (aq) and OH(aq) indicate a reorientation time for OH- (aq) of 1.9 ps, while no rotational anisotropy is resolved for the OH(aq) radical within our time resolution of 0.3 ps. This is consistent with the notion that OH(aq) radicals formed after electron detachment are only weakly bound to the hydrogen bond network of water. The assignment of the experimental data is supported by a series of electronic structure calculations of simple complexes of OH- (H(2)O)(n).