An iterative method of evaluation of elastic-plastic deflections of hyperstatic framed structures

Summary The concept of substitutive concentrated elastic-plastic rotations, replacing actual elasticplastic zones is used, together with an iterative method of determination of the bending moment distribution to simplify the evaluation of elastic-plastic deflections of hyperstatic beams and frames.

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Eine iterative Methode der Auswertung von elastisch-plastischen Verschiebungen für statisch unbestimmte Rahmen

Übersicht Die Idee von fiktiven Ersatzrotationen, welche die tatsächlichen elastisch-plastischen Zonen modelliert, wird mit einer iterativen Methode kombiniert, um eine relativ einfache Bestimmung von Biegemomentenfeldern in statisch unbestimmten Balken und Rahmen zu ermöglichen. Die resultierenden Verschiebungen, ergeben sich mit ausreichender Genauigkeit.

     

Eu-doped glass materials for red luminescence

Red luminescence (at wavelength about 622 nm) from Eu³⁺ ions embedded in PbO–Bi₂O₃–Ga₂O₃–BaO glass hosts is reported for room and liquid helium temperatures. The substantial influence of energy transfer processes between the host and Eu³⁺ ions is shown experimentally through the dependences of photoluminescence on light polarization and excitation wavelength. Only polarized, excited pulsed XeII laser light (λ=714 nm) gives substantial luminescence with efficiency up to 14.3%. The role of phonon-relaxation subsystem in the observed luminescence is discussed.     

Light Induces lnositol Trisphosphate Elevation in Blepharisma japonicum

Abstract— Photoinduced formation of inositol 1,4,5-trisphosphate (Ins[1,4,5]P₃) was examined using a specific radioimmu-noassay to investigate the molecular mechanisms of light signal transduction mediating photophobic responses in the ciliate Blepharisma japonicum. Application of light stimuli of moderate intensity to dark-adapted cells induced a rapid and significant increase in the basal level of Ins (1,4,5)P₃, with a peak at about 20 s. Thereafter, the level of Ins (1,4,5)P₃ declined to the resting value within the subsequent 100 s. Light stimuli of higher intensity raised the cell Ins (1,4,5)P₃ content to still higher levels within about 20 s, but the decaying time course was considerably prolonged. In ciliates incubated under dark conditions with agents interfering with the inositol signalling pathway, like neomycin and Li⁺ the basal levels of Ins (1,4,5)P₃ were lower than in control cells. A photoinduced rise of Ins (1,4,5)P₃, content in ciliates treated with neomycin or Li⁺ was significantly inhibited in a dose-dependent manner. Depolarizing ionic stimuli in dark-adapted ciliates induced no significant alterations of the resting Ins (1,4,5)P₃ level, indicating a lack of a contribution of this kind of stimulation to the inositol turnover. These studies are the first in vivo demonstration of a possible role for inositol trisphosphate as a second messenger in the light signal transduction process in the ciliate B. japonicum.     

Method of substitutive plastic rotation applied to elastic-plastic structures with axial forces

Summary The paper extends the notion of substitutive plastic rotation which simplifies the determination of the elastic-plastic deflections of beams and frames to structures with non-negligible axial forces. The formulae derived have been illustrated with a simple example of a cantilever beam and then applied to the geometrically nonlinear elastic-plastic problem of an imperfection in a pipeline shell.

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Die Methode der Ersatzrotationen für elastisch-plastische Strukturen mit Axialkräften

Übersicht Die Arbeit erweitert die Methode der fiktiven Ersatzrotationen, die die Bestimmung der elastisch-plastischen Verschiebungen in Balken- und Rahmenstrukturen vereinfacht, auf den Fall mit größeren axialen Kräften. Die ausgeführten Formeln werden am einfachen Beispiel des Kragbalkens illustriert und dann für die geometrisch nichtlineare Analyse einer Beule in einer dünnwandigen Rohrleitung verwendet.

     

Mixtures of anisotropic and spherical colloids: Phase behavior, confinement, percolation phenomena and kinetics

Purely entropic systems such as suspensions of hard rods, platelets and spheres show rich phase behavior. Rods and platelets have successfully been used as models to predict the equilibrium properties of liquid crystals for several decades. Over the past years hard particle models have also been studied in the context of non-equilibrium statistical mechanics, in particular regarding the glass transition, jamming, sedimentation and crystallization. Recently suspensions of hard anisotropic particles also moved into the focus of materials scientists who work on conducting soft matter composites. An insulating polymer resin that is mixed with conductive filler particles becomes conductive when the filler percolates. In this context the mathematical topic of connectivity percolation finds an application in modern nano-technology. In this article, we briefly review recent work on the phase behavior, confinement effects, percolation transition and phase transition kinetics in hard particle models. In the first part, we discuss the effects that particle anisotropy and depletion have on the percolation transition. In the second part, we present results on the kinetics of the liquid-to-crystal transition in suspensions of spheres and of ellipsoids.     

On the influence of a patterned substrate on crystallization in suspensions of hard spheres

We present a computer simulation study on crystal nucleation and growth in supersaturated suspensions of mono-disperse hard spheres induced by a triangular lattice substrate. The main result is that compressed substrates are wet by the crystalline phase (the crystalline phase directly appears without any induction time), while for stretched substrates we observe heterogeneous nucleation. The shapes of the nucleated crystallites fluctuate strongly. In the case of homogeneous nucleation amorphous precursors have been observed [T. Schilling et al., Phys. Rev. Lett. 105(2), 025701 (2010)]. For heterogeneous nucleation we do not find such precursors. The fluid is directly transformed into highly ordered crystallites.     

PbO–Bi2O3–Ga2O3–BaO glasses doped by Er as novel materials for IR emission

Infra-red luminescence (at wavelengths about 1600 and 2500 nm) from Er³⁺ ions embedded in PbO–Bi₂O₃–Ga₂O₃–BaO glass hosts is reported for room and helium liquid temperatures. The substantial influence of energy transfer processes between the host and Er³⁺ ions is shown experimentally through the dependences of photoluminescence on light polarization and excitation wavelength. Only the application of the polarized pumping YAG–Nd laser beam (λ=1060 nm) stimulates substantial luminescence with quantum efficiency up to 24%. The role of phonon-relaxation subsystem in the observed luminescence is discussed.     

Model analysis of supermode generation in active 5-core optical fibre

In the paper, the phase-locked emitters in multi-core optical fibres for high power fibre lasers are presented. The influence of the normalized frequency and diameters of the cores on the shape of the pattern in the Fraunhofer diffraction region has been analysed. The simulation of coupling coefficient between cores influences on phase-locking and in the consequence on the far-field pattern of the fibre laser, based on the analyzed multi-core optical fibre, were performed. In the analyzed fibre laser, while exchanging power of the generated radiation between two adjacent cores on the fibre length (L = 5 m) within the range of 4–10%, the radiation becomes phased. Having satisfied this condition, in the far-field low-divergence, high-power laser beam (supermode) is attained. 5-core double clad optical fibre doped with neodymium ions was fabricated. Luminescence spectra of the manufactured fibre were measured.     

Double clad aluminosilicate optical fibre doped with $\mbox{\sffamily\bfseries Nd}^{\hbox{\sffamily\bfseries\fontsize{12}{12}\selectfont 3+}}$ ions

Double clad aluminosilicate optical fibre doped with neodymium ions was obtained. Aluminosilicate glasses with low silica (25 mol%) content possess very good optical, thermal and mechanical properties. Simultaneously they are characterized by high solubility of rare earth elements. A set of physical measurements including: DTA, DSC, DL analysis, absorption spectroscopy and thermo-physical properties (thermal stability parameters, refractive index, thermal expansion coefficient, microhardness, density and molar volume) were determined. Double-crucible drawing technique was applied to obtain neodymium doped double clad optical fibre with . Luminescence spectra of aluminosilicate glass and fibre doped with Nd^{3 +} ions are presented.     

Oxygen species adsorbed on CeX zeolites identified by ESR spectroscopy

Two kinds of paramagnetidc O^?₂ ions have been identified by contacting molecular oxygen with CeX zeolite heat treated at 200°C in vacuo. The first O^?₂ species corresponds to the usual O^?₂ ions adsorbed on cerium oxide with the following parameters: g₁ = g_? ≈ 2.035 ± 0.002, g₂ = g₃ = g_⊥ = 2.0095 ± 0.0005 and a hyperfine pattern of six and eleven lines centred about g₃ and split by about 78 Oe, the other two components being not resolved. The second paramagnetic species of much higher intensity (larger by 2 or 3 orders of magnitude) presents rather ESR parameters and hyperfine structure. One has: g₁ = 2.0242, g₂ = 2.0208 and g₃ = 2.0112 ± 0.0003; c₁ = 24 ± 3, c₂ = 66 ± and c₃ = 12 ± 3 Oe. The six and eleven hyperfine line pattern which has been observed shows that the unpaired spin is qually distributed between two oxygen nuclei. The g tensor values are interpreted in terms of almost complete averaging of g₁ and g₂ components due to rotational motion at ?196°C about axis (3 (χ_ξ). The species is attributed to O^?₂ ion formed according to the equilibrium:

. The Ce ions are located in cationic sites SII within the zeolite supercages and are only weakly bonded to the oxygen leading to rotational motion and to case of desorption, the species reversibly disappearing by outgassing at room temperature.