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Mukherjee P Shade CM Yingling AM Lamont DN Waldeck DH Petoud S 《The journal of physical chemistry. A》2011,115(16):4031-4041
This work explores the sensitization of luminescent lanthanide Tb(3+) and Eu(3+) cations by the electronic structure of zinc sulfide (ZnS) semiconductor nanoparticles. Excitation spectra collected while monitoring the lanthanide emission bands reveal that the ZnS nanoparticles act as an antenna for the sensitization of Tb(3+) and Eu(3+). The mechanism of lanthanide ion luminescence sensitization is rationalized in terms of an energy and charge transfer between trap sites and is based on a semiempirical model, proposed by Dorenbos and co-workers (Dorenbos, P. J. Phys.: Condens. Matter 2003, 15, 8417-8434; J. Lumin. 2004, 108, 301-305; J. Lumin. 2005, 111, 89-104. Dorenbos, P.; van der Kolk, E. Appl. Phys. Lett. 2006, 89, 061122-1-061122-3; Opt. Mater. 2008, 30, 1052-1057. Dorenbos, P. J. Alloys Compd. 2009, 488, 568-573; references 1-6.) to describe the energy level scheme. This model implies that the mechanisms of luminescence sensitization of Tb(3+) and Eu(3+) in ZnS nanoparticles are different; namely, Tb(3+) acts as a hole trap, whereas Eu(3+) acts as an electron trap. Further testing of this model is made by extending the studies from ZnS nanoparticles to other II-VI semiconductor materials; namely, CdSe, CdS, and ZnSe. 相似文献
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An J Shade CM Chengelis-Czegan DA Petoud S Rosi NL 《Journal of the American Chemical Society》2011,133(5):1220-1223
Luminescent metal-organic frameworks (MOFs), Ln(3+)@bio-MOF-1, were synthesized via postsynthetic cation exchange of bio-MOF-1 with Tb(3+), Sm(3+), Eu(3+), or Yb(3+), and their photophysical properties were studied. We demonstrate that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting lanthanide cations in aqueous solution. 相似文献
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Back Cover: Polynuclear SmIII Polyamidoamine‐Based Dendrimer: A Single Probe for Combined Visible and Near‐Infrared Live‐Cell Imaging (Angew. Chem. Int. Ed. 11/2014)
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Bryce V. Johnson Daniel P. Sturtzel Joyce E. Shade 《Journal of organometallic chemistry》1978,154(1):89-111
Primary amines react with a variety of cationic and neutral iron isocyanide complexes to yield structural and rotational diaminocarbene isomers characterized by variable temperature 1H and 13C NMR spectra. Structural isomers result from the conversion of amines to isocyanide ligands via the base-catalyzed nucleophilic attack of initially formed diaminocarbenes on isocyanides substituents, the effect on isomer populations is often marked. Factors influencing structural and rotational isomeric preferences are discussed. 相似文献
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Experimental Techniques - 相似文献
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等离子体温度和密度的诊断是聚变研究不可缺少的重要方面。本文概要叙述KT-5B托卡马克实验中与等离子体温度和密度有关的几项诊断,说明其特点,对已获得的结果作了初步分析。 相似文献
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Chengelis DA Yingling AM Badger PD Shade CM Petoud S 《Journal of the American Chemical Society》2005,127(48):16752-16753
The electronic structure of CdSe semiconductor nanocrystals has been used to sensitize Tb3+ in solution by incorporation of Tb3+ cations into the nanocrystals during synthesis. Doping of luminescent Tb3+ metal ions in semiconductor nanocrystals utilizes the positive attributes of both species' photophysical properties, resulting in a final product with long luminescence lifetimes, sharp emission bands, high absorptivities, and strong resistance to decomposition. This strategy also helps protect the lanthanide cations from nonradiative deactivation from C-H, N-H, and O-H oscillators of solvent molecules or traditional organic lanthanide ligands, leading to long Tb3+ luminescence lifetimes. This new type of nanomaterial synergistically combines the photophysical properties of nanocrystals and Tb3+. 相似文献