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1.
The collision-generated hybridization which has been found responsible for the on-site mixing of the atomic-likef-state and the band-liked states in mixed valence solids has been studied for the cerium solid. A practical expression which depends on the lattice
constant and temperature has been obtained for the collision-generated hybridization. Numerical calculations show that the
valence varies continuously with lattice constant and that temperature makes the transition smoother. The collision-generated
hybridization is found to be of significant strength in the intermediate valence regime; but over a wide range of the valence
near 3.5 it varies rather slowly without preferring a particular valence. Factors which can assist the collision-generated
hybridization in stabilizing the mixed valence phase at a particular lattice constant are discussed. 相似文献
2.
The structures of loxylostosidine A and B, two new sulfoxide - containing monoterpene alkaloid glucosides, are described. 相似文献
3.
A. H. Joarder 《International Journal of Mathematical Education in Science & Technology》2013,44(4):538-543
The mean and variance of some continuous distributions, in particular the exponentially decreasing probability distribution and the normal distribution, are considered. Since they involve integration by parts, many students do not feel comfortable. In this note, a technique is demonstrated for deriving mean and variance through differential calculus. The general nature of the technique has potential for wider applications. 相似文献
4.
Ratan Kotipalli Bart Vermang Viktor Fjällström Marika Edoff Romain Delamare Denis Flandre 《固体物理学:研究快报》2015,9(3):157-160
The benefits of gallium (Ga) grading on Cu(In,Ga)Se2 (CIGS) solar cell performance are demonstrated by comparing with ungraded CIGS cells. Using drive‐level capacitance profiling (DLCP) and admittance spectroscopy (AS) analyses, we show the influence of Ga grading on the spatial variation of deep defects, free‐carrier densities in the CIGS absorber, and their impact on the cell's open‐circuit voltage Voc. The parameter most constraining the cell's Voc is found to be the deep‐defect density close to the space charge region (SCR). In ungraded devices, high deep‐defect concentrations (4.2 × 1016cm–3) were observed near the SCR, offering a source for Shockley–Read–Hall recombination, reducing the cell's Voc. In graded devices, the deep‐defect densities near the SCR decreased by one order of magnitude (2.5 × 1015 cm–3) for back surface graded devices, and almost two orders of magnitude (8.6 × 1014 cm–3) for double surface graded devices, enhancing the cell's Voc. In compositionally graded devices, the free‐carrier density in the absorber's bulk decreased in tandem with the ratio of gallium to gallium plus indium ratio GGI = Ga/(Ga + In), increasing the activation energy, hindering the ionization of the defect states at room temperature and enhancing their role as recombination centers within the energy band. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
5.
6.
We present calculations of the mean square concentration fluctuations, Sα(0), for binary mixtures of model polar fluids. The assumed pair interactions are taken to be of the forms of a hard core plus either dipole-dipole, quadrupole-quadrupole or dipole- quadrupole terms. The calculations are carried out within a mean field approximation. We have considered in some detail the interplay between size differences and the difference in the strength and range of the potentials in deciding how Sα(0) deviates from the ideal behaviour. 相似文献
7.
A two dimensional simulation study was performed to investigate the photoacoustic signal properties of non-aggregated and aggregated erythrocytes. Spatial distributions of non-aggregated blood samples were generated by employing a Monte Carlo method and aggregated blood samples were simulated using a hexagonal packing scheme. For the non-aggregating case photoacoustic signals demonstrated a monotonic rise with hematocrit. For the aggregating case it was found that spectral (<20 MHz) intensity increased (11 dB at 15.6 MHz) when the aggregate size increased. This study strongly suggests that the assessment of erythrocyte aggregation level in human blood might be possible by using a photoacoustic spectroscopic method. 相似文献
8.
The neutron diffraction data analysis of deuterated liquid 2-propanol at room temperature to define its molecular conformation
is presented. 2-Propanol being a large molecule with twelve atomic sites, the conformation analysis is tricky and an improved
method of data analysis is given. The intermolecular structural correlations, i.e., hydrogen-bonded liquid structure, can
be modelled accurately to extract the nature of the average hydrogen-bonded molecular association in liquid state at room
temperature. Like other alcohols these are mostly hexamer ring chain (HRC) clusters. The cluster analysis of recent X-ray
data available in the literature also support the same liquid structure. 相似文献
9.
We have described here the physical basis for lasing without population inversion (LWOPI). This type of amplification is obtained
basically by two mechanisms: (i) one is based on atomic interference and (ii) the other is based on Fano-type interference.
We have shown here, in H2 molecules, amplification without population inversion is feasible by considering both the mechanisms. 相似文献
10.
Like liquid alkali metalsd-shell liquid metals show scaling behaviour in structure and interaction potentials. A realistic interaction potential model,
properly parametrized can reasonably describe the universality in the isothermal compressibility and vacancy formation energy
of 3d-liquid metals in electron ion plasma model. 相似文献