全文获取类型
收费全文 | 24058篇 |
免费 | 3839篇 |
国内免费 | 4242篇 |
专业分类
化学 | 19557篇 |
晶体学 | 342篇 |
力学 | 1345篇 |
综合类 | 341篇 |
数学 | 2984篇 |
物理学 | 7570篇 |
出版年
2024年 | 35篇 |
2023年 | 329篇 |
2022年 | 647篇 |
2021年 | 689篇 |
2020年 | 865篇 |
2019年 | 940篇 |
2018年 | 818篇 |
2017年 | 780篇 |
2016年 | 1109篇 |
2015年 | 1186篇 |
2014年 | 1453篇 |
2013年 | 1827篇 |
2012年 | 2139篇 |
2011年 | 2243篇 |
2010年 | 1674篇 |
2009年 | 1653篇 |
2008年 | 1883篇 |
2007年 | 1578篇 |
2006年 | 1435篇 |
2005年 | 1327篇 |
2004年 | 1155篇 |
2003年 | 913篇 |
2002年 | 998篇 |
2001年 | 844篇 |
2000年 | 655篇 |
1999年 | 503篇 |
1998年 | 390篇 |
1997年 | 319篇 |
1996年 | 304篇 |
1995年 | 260篇 |
1994年 | 219篇 |
1993年 | 176篇 |
1992年 | 160篇 |
1991年 | 138篇 |
1990年 | 121篇 |
1989年 | 76篇 |
1988年 | 78篇 |
1987年 | 58篇 |
1986年 | 39篇 |
1985年 | 40篇 |
1984年 | 16篇 |
1983年 | 15篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 4篇 |
1977年 | 3篇 |
1971年 | 2篇 |
1959年 | 2篇 |
1957年 | 4篇 |
1936年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Guo-Xing Li Xiao-Wei Qu Lu-Wei Hao Qing Li Su Chen 《Journal of polymer science. Part A, Polymer chemistry》2022,60(11):1710-1717
From the implementation point of view, the printable magnetic Janus colloidal photonic crystals (CPCs) microspheres are highly desirable. Herein, we developed a dispensing-printing strategy for magnetic Janus CPCs display via a microfluidics-automatic printing system. Monodisperse core/shell colloidal particles and magnetic Fe3O4 nanoparticles precursor serve as inks. Based on the equilibrium of three-phase interfacial tensions, Janus structure is successfully formed, followed by UV irradiation and self-assembly of colloid particle to generate magnetic Janus CPCs microspheres. Notably, this method shows distinct superiority with highly uniform Janus CPCs structure, where the TMPTA/Fe3O4 hemisphere is in the bottom side while CPCs hemisphere is in the top side. Thus, by using Janus CPCs microspheres with two different structural colors as pixel points, a pattern with red flower and green leaf is achieved. Moreover, 1D linear Janus CPCs pattern encapsulated by hydrogel is also fabricated. Both the color and the shape can be changed under the traction of magnets, showing great potentials in flexible smart displays. We believe this work not only offers a new feasible pathway to construct magnetic Janus CPCs patterns by a dispensing-printable fashion, but also provides new opportunities for flexible and smart displays. 相似文献
2.
Hua Saixiang Zhu Huichao Wang Xiao Wu Mingyuan Wu Qingyun Liu Jiuyi Yang Jianjun Zhang Jianan 《Cellulose (London, England)》2022,29(13):7465-7475
Cellulose - Ultraviolet (UV) protective cotton fabric is a convenient and reliable way to protect human body from sunlight. Herein, a polymerizable UV-absorber,... 相似文献
3.
Li Quanxin Li Zheng He Cheng Sun Huilin Tan Shengheng Zhang Hua 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(5):2105-2115
Journal of Radioanalytical and Nuclear Chemistry - The simplified 8-oxide system (SiO2-B2O3-Na2O-Al2O3-CaO-TiO2-MoO3-La2O3) has been prepared under two types of cooling methods, and analyzed with... 相似文献
4.
5.
Pengjin Qin Li-An Wang Prof. Joseph M. O'Connor Prof. Kim K. Baldridge Yifan Li Burak Tufekci Jiyue Chen Prof. Arnold L. Rheingold 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(41):18114-18121
Triene 6π electrocyclization, wherein a conjugated triene undergoes a concerted stereospecific cycloisomerization to a cyclohexadiene, is a reaction of great historical and practical significance. In order to circumvent limitations imposed by the normally harsh reaction conditions, chemists have long sought to develop catalytic variants based upon the activating power of metal–alkene coordination. Herein, we demonstrate the first successful implementation of such a strategy by utilizing [(C5H5)Ru(NCMe)3]PF6 as a precatalyst for the disrotatory 6π electrocyclization of highly substituted trienes that are resistant to thermal cyclization. Mechanistic and computational studies implicate hexahapto transition-metal coordination as responsible for lowering the energetic barrier to ring closure. This work establishes a foundation for the development of new catalysts for stereoselective electrocyclizations. 相似文献
6.
7.
Wenpin Wang Qing Yao Jianhui Song Binbin Yao Hui Wang Zhibo Li 《Journal of Polymer Science.Polymer Physics》2019,57(11):662-669
The PeakForce Quantitative Nanomechanical Mapping based on atomic force microscope (AFM) is employed to first visualize and then quantify the elastic properties of a model nitrile rubber/poly(vinyl chloride) (NBR/PVC) blend at the nanoscale. This method allows us to consistently observe the changes in mechanical properties of each phase in polymer blends. Beyond measuring and discriminating elastic modulus and adhesion forces of each phase, we tune the AFM tips and the peak force parameters in order to reliably image samples. In view of viscoelastic difference in each phase, a three‐phase coexistence of an unmixed NBR phase, the mixed phase, and PVC microcrystallites is directly visualized in NBR/PVC blends. The nanomechanical investigation is also capable of recognizing the crosslinked rubber phase in cured rubber. The contribution of the mixed phase was quantified and it was found that the mechanical properties of blends are mainly determined by the homogeneity and stiffness of the mixed phase. This study furthers our understanding the structure–mechanical property relationship of thermoplastic elastomers, which is important for their potential design and applications. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 662–669 相似文献
8.
Qin Yin Shou-Guo Wang Xiao-Wei Liang De-Wei Gao Jun Zheng Shu-Li You 《Chemical science》2015,6(7):4179-4183
An organocatalytic asymmetric chlorinative dearomatization of naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee). The reaction features mild reaction conditions, good tolerance of diverse functional groups and simple reaction operation. 相似文献
9.
讨论一类非齐次非线性椭圆边界值问题.利用极大值原理证明了该问题解的梯度估计.作为它的应用得到了解的效率比估计. 相似文献
10.
Dr. Qing Xu Dr. Shanshan Tao Dr. Qiuhong Jiang Prof. Donglin Jiang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(11):4587-4593
A strategy based on covalent organic frameworks for ultrafast ion transport involves designing an ionic interface to mediate ion motion. Electrolyte chains were integrated onto the walls of one-dimensional channels to construct ionic frameworks via pore surface engineering, so that the ionic interface can be systematically tuned at the desired composition and density. This strategy enables a quantitative correlation between interface and ion transport and unveils a full picture of managing ionic interface to achieve high-rate ion transport. Moreover, the effect of interfaces was scaled on ion transport; ion mobility is increased in an exponential mode with the ionic interface. This strategy not only sets a benchmark system but also offers a general guidance for designing ionic interface that is key to systems for energy conversion and storage. 相似文献