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排序方式: 共有706条查询结果,搜索用时 966 毫秒
1.
Yoshio Suzuki Noriyuki Tanji Chikako Ikeda Aki Honda Kenji Ookubo Daniel Citterio Suzuki Koji 《Analytical sciences》2004,20(3):475-482
Novel labeling reagents, called MS probes, which possess a positively charged quaternary amine moiety and can transform a neutral analyte into a charged compound by simply mixing with the analyte and allowing the mixture to stand from several minutes to 30 min at room temperature or while heating to 50 degrees C, were designed and synthesized for the highly sensitive detection of carbonyl, alcohol, carboxylic acid and primary amine samples by electrospray ionization mass spectrometry (ESI-MS). The positively charged products can be detected with high sensitivity in an ESI-MS system, which is the most popular liquid MS instrument. All of the labeled products showed a remarkably large increase in the molecular-ion peak abundance detection sensitivity of over 500-fold at picomolar concentration levels compared to that of unlabeled analytes in an ESI-MS system. These MS probes, used together with liquid MS detection, are widely applicable as a convenient method for the highly sensitive detection of less than picomolar levels of analytes, and therefore greatly enhance the power of ESI-MS analysis. 相似文献
2.
Noriyuki Mizoguchi 《Journal of mathematical chemistry》1991,7(1):325-340
Generalized graphs represent Hückel-type and Möbius-type polycyclic conjugated systems. We show that the number of generalized graphs with different spectra for a given parent graph is not larger than 2
N(R) and is equal to 2
N(R) if no two rings are equivalent,N(R) being the number of rings (fundamental circuits) in the parent graph. We demonstrate that the rule for the stability of generalized graphs, proved in a previuos paper, and the information on the relative magnitudes of the effects of individual circuits enable one to predict the stabilities of generalized graphs without performing numerical calculations. 相似文献
3.
Michihiro Shirakawa 《Tetrahedron》2006,62(9):2016-2024
New porphyrin-based gelators bearing eight hydrogen-bond-forming amide groups at their periphery were synthesized. They acted as versatile gelators for aromatic solvents. SEM and TEM observations and X-ray crystallographic analysis established that they tend to aggregate into a two-dimensional sheet-like structure utilizing the intermolecular hydrogen-bonding interaction. In this structure the porphyrin-porphyrin π-π stacking interaction is not involved because of the energetically-predominant hydrogen-bonding interactions, keeping the space distance of 12.9 Å. Very interestingly, when C60 was added, the morphology was transformed to a one-dimensional fibrous structure, which can enjoy a porphyrin-C60-porphyrin interaction. This multicapsular structure having porphyrin-based compartments for hosting C60 was further characterized by XRD, EPR of a Cu(II) analogue, and the theoretical calculation. Thus, this paper presents a new concept, ‘molecular recognition in gel’, which is effective for the weak host-guest interaction. 相似文献
4.
5.
Junji Kido Yasuyuki Imamura Noriyuki Kuramoto Katsutoshi Nagai 《Journal of colloid and interface science》1992,150(2)
Interactions between poly(N-substituted acrylamide)s and surfactants, such as sodium dodecyl sulfate (SDoS) and sodium decyl sulfate (SDeS), in aqueous solutions were investigated using a solvatochromic probe. The polymers used were poly(N,N-dimethylacrylamide) (PDMA), poly(N-isopropylacrylamide) (PIPA), poly(N-acryloylpyrrolidine) (PAPR), and poly(vinylpyrrolidone) (PVPy) for comparison. They were labeled with pyridinium dicyanomethylide chromophore as a solvatochromic probe, and the changes in the microenvironment polarity of the polymer upon association with surfactant micelles were investigated by monitoring the λmax in the absorption spectra of the probe molecule. It was found that the Gibbs free energy of micelle stabilization by polymer complexation for SDoS is 7.6, 4.1, and 2.2 kJ mol−1, and for SDeS 5.1, 2.9, and 0.8 kJ mol−1 with PIPA, PAPR, and PDMA, respectively. These results indicate that the complexation between polymer and surfactant is influenced not only by the alkyl-chain length of the surfactant, but also by the polymer side groups. 相似文献
6.
Noriyuki Asakura Toshiaki Kamachi Ichiro Okura 《Research on Chemical Intermediates》2006,32(3-4):341-355
The behavior of redox molecules in solution that was not detected by electrochemical techniques was measured by a highly-sensitive electrochemical quartz crystal microbalance (EQCM) technique that has been improved in this study to obtain a high sensitivity of EQCM measurement in solution. The improved EQCM technique allowed to monitor the motion of a redox molecule, that is an access of the molecule to an electrode surface and repulsion from the surface during redox. An EQCM technique currently in use has measured adsorption of redox molecules on an electrode surface or polymerization on the surface caused by a chemical reaction following redox, which exhibits an enough large mass change response to detect with an EQCM measurement. However, access and repulsion of redox molecule, which is a slight motion of the molecule near on electrode surface, has not been detected and investigated by an EQCM technique, because the mass change response seems to be very small. In this study, the redox behavior of methyl viologen on a bare gold surface, pyridinethiol surface and methylpyridinethiol surface was investigated. Although the three electrodes give the same cyclic voltammogram of methyl viologen, the three are different in QCM response recorded at the same time as the voltammetry. Access/repulsion of methyl viologen within an electrical double layer was monitored by the highly-sensitive EQCM technique. 相似文献
7.
Takeo Ito Hideki Shirakawa Sakuji Ikeda 《Journal of polymer science. Part A, Polymer chemistry》1974,12(1):11-20
A direct method of simultaneously polymerizing and forming acetylene monomer to produce uniformly thin films of polyacetylene was investigated in terms of catalyst system, catalyst concentration, and polymerization temperature. The best catalyst was a Ti(OC4H9)4–Al(C2H5)3 system (Al/Ti = 3–4) and the critical concentration was 3 mmole/l. of Ti(OC4H9)4. Below the critical concentration, only a solid or a powder was obtained. The configuration of the polymers obtained depends strongly upon the polymerization temperature. Thus an all-cis polymer was obtained at temperatures lower than ?78°C, whereas an all-trans polymer resulted at temperatures higher than 150°C. Observations either in an electron microscope by direct transmission or in a scanning electron microscope showed that the film is composed of an accumulation of fibrils about 200–300 Å in width and of indefinite length. 相似文献
8.
Yoshiki Chujo Kenji Kohno Noriyuki Usami Yuya Yamashita 《Journal of polymer science. Part A, Polymer chemistry》1989,27(6):1883-1890
Amphiphilic block copolymers, i.e., poly(methyl methacrylate)-b-poly(2-dimethylethylammoniumethyl methacrylate), were synthesized by the reaction between two prepolymers. Carboxyl-terminated poly(methyl methacrylate) and hydroxyl-terminated poly(2-dimethylaminoethyl methacrylate) were prepared by radical polymerization of the corresponding monomers in the presence of thioglycolic acid and 2-mercaptoethanol as a chain transfer agent, respectively. Two condensation methods, i.e., DCC and the acid chloride method, were used for the reactions of these prepolymers. The subsequent quarternization produced the amphiphilic block copolymers. Surface property of poly(methyl methacrylate) films containing this amphiphilic block copolymer was examined by measuring contact angles for water. The addition of only 0.5 wt% of the block copolymer was sufficient to make poly(methyl methacrylate) surfaces hydrophilic. The block copolymer formed a polymeric micelle in acetone–water mixed solvent. 相似文献
9.
2-Alkyl-1-alkylthioisoquinolinium salts were readily prepared from 2-alkyl-1(2H)-isoquinolones via 2-alkyl1(2H)-thioisoquinolones in two steps. Under mild conditions, the reaction of 2-alkyl-1-alkylthioisoquinolinium salts with active methylene compounds in the presence of sodium hydride afforded 2-alkyl-1-(substituted methylene)iso-quinolines in good yields. Pyrrolo[2,1-a]isoquinolines were synthesized by the cyclization of 2-benzyl-1-(substituted methylene)isoquinolines using acetic anhydride. 相似文献
10.
[structure: see text] The structure of gelsemoxonine, isolated from Gelsemium elegans Benth., was revised to be a novel oxindole alkaloid having an azetidine unit. A new alkaloid, 14,15-dihydroxygelsenicine, which was presumed to be a biosynthetic precursor of gelsemoxonine, was also isolated. 相似文献