排序方式: 共有57条查询结果,搜索用时 15 毫秒
1.
Stanciu C Hino SS Stender M Richards AF Olmstead MM Power PP 《Inorganic chemistry》2005,44(8):2774-2780
The synthesis and characterization of the first divalent germanium, tin, and lead monoamide derivatives of the parent amide group -NH(2) are presented. They have the general formula (ArMNH(2))(2) (M = Ge, Ar = Ar'(C(6)H(3)-2,6-Pr(i)(2)) or Ar* (C(6)H(3)-2,6(C(6)H(2)-2,4,6-Pr(i)(3))); M = Sn, Ar = Ar*; M = Pb, Ar = Ar*). For germanium and tin, they were obtained by reacting the corresponding terphenyl halides of the group 14 elements with liquid ammonia in diethyl ether. The lead amide derivative (Ar*PbNH(2))(2) was synthesized by reaction of LiNH(2) with Ar*PbBr in diethyl ether. The compounds were characterized by IR and multinuclear NMR spectroscopies and by X-ray crystallography in the case of the (Ar'GeNH(2))(2) or (Ar*SnNH(2))(2) derivatives. They possess dimeric structures with two -NH(2) groups bridging the germanium and tin centers. For lead, the reaction with ammonia led to isolation of a stable ammine complex of formula Ar*PbBr(NH(3)) which was characterized by IR and NMR spectroscopies and by X-ray crystallography. It is the first structural characterization of a divalent lead ammine complex. 相似文献
2.
R. Hristu S. G. Stanciu F.-J. Kao G. A. Stanciu 《Applied physics. B, Lasers and optics》2012,107(1):97-101
We report on the two-photon excited photoluminescence of photonic quantum ring laser structures using Ti:Sapphire femtosecond
pulsed laser. Using two-photon excited photoluminescence microscopy, we were able to image the laser structures when optically
excited and compare the results with previously obtained images on electrically pumped photonic quantum ring lasers. We also
propose a method to evaluate the Rayleigh band on the circumference of these structures. 相似文献
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The title compound is the first stable structural analogue for the monobridged isomer of a heavier group 14 alkene analogue. 相似文献
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Xu F Zhang H Ilavsky J Stanciu L Ho D Justice MJ Petrache HI Xie J 《Langmuir : the ACS journal of surfaces and colloids》2010,26(24):19199-19208
The dispersion of Nafion ionomer particles and Pt/C catalyst aggregates in liquid media was studied using both ultra-small-angle X-ray scattering (USAXS) and cryogenic TEM. A systematic approach was taken to study first the dispersion of each component (i.e., ionomer particles and Pt/C aggregates), then the combination of the components, and last the catalyst ink. Multiple-level curve fitting was used to extract the particle size, size distribution, and geometry of the Pt/C aggregates and the Nafion particles in liquid media from the scattering data. The results suggest that the particle size, size distribution, and geometry are not uniform throughout the systems but rather vary significantly. It was found that the interaction of each component (i.e., the Nafion ionomer particles and the Pt/C aggregates) occurs in the dispersion. Cryogenic TEM was used to observe the size and geometry of the particles in liquid directly and to validate the scattering results. The TEM results showed excellent agreement. 相似文献
6.
Victor Bulacovschi Aurelian Stanciu Iulian Rusu Adrian C
ilean Florina Ungureanu 《Polymer Degradation and Stability》1998,60(2-3):487-491
Three new chemically crosslinked polyurethanes were synthesized. Their behaviour in organic solvents and in dynamic heating conditions was studied. Predictions regarding the thermal stability have been made by using the isoconversion kinetic method. 相似文献
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Marieta Nichifor Magdalena Cristina Stanciu Bogdan C. Simionescu 《Journal of Macromolecular Science: Physics》2013,52(5):983-993
The intermolecular hydrophobic association in diluted aqueous solutions of some cationic amphiphilic polysaccharides was investigated using fluorescence techniques. Dextran and dextran carrying N-alkyl-N,N-dimethyl-N(2-hydroxypropylene) ammonium chloride groups as side chains were single labeled with pyrene or naphthalene. The intensity of the pyrene excimer peak and the ratio I3/I1 determined from the fluorescence emission spectra of pyrene-labeled amphiphilic polymer increased with increasing polymer concentration and were higher than in the solution containing pyrene-labeled dextran. Emission spectra of diluted solution (0.008–0.2 g/dl) containing mixtures of pyrene and naphthalene single-labeled amphiphilic polymers proved the occurrence of a nonradiative energy transfer between labels at very a low polymer concentration (<10?2 g/dl). The energy transfer was not observed in mixtures of single-labeled unmodified dextran. All these results suggest that the intermolecular hydrophobic association of alkyl substituents takes place at a very low concentration of amphiphilic polymers. 相似文献
8.
Reactions of R4Sb2 (R = Me, Et) with (Me3SiCH2)3M (M = Ga, In) and Crystal Structures of [(Me3SiCH2)2InSbMe2]3 and [(Me3SiCH2)2GaOSbEt2]2 The reaction of (Me3SiCH2)3In with Me2SbSbMe2 gives [(Me3SiCH2)2InSbMe2]3 ( 1 ) and Me3SiCH2SbMe2. [(Me3SiCH2)2GaOSbEt2]2 ( 2 ) is formed by the reaction of (Me3SiCH2)3Ga with Et2SbSbEt2 and oxygen. The syntheses and the crystal structures of 1 and 2 are reported. 相似文献
9.
Victoria Stanciu 《Annali dell'Universita di Ferrara》2003,49(1):11-18
Families of quasiconformal homeomorphisms of bounded mean oscillation (BMO-qc) are studied from the point of view of compacity (normality + closedness). Using Tukia's convergence theorems and David's
existence and factorization theorem, a normality criterion for families ofBMO-qc homeomorphisms and a compacity criterion for families transforming a given compact subsetM
1 in a compact subsetM
2 are established.
Sunto Le famiglie di applicazioni quasiconforme di media oscillazione limitata (BMO-qc) vengono studiate dal punto di vista della compacità (normalità + chiusura). Utilisando i teoremi di convergenza di Tukia ed il teorema di esistenza e fattorisazione di David, si stabiliscono un criterio di normalità per famiglie di omeomorfismiBMO-qc ed un criterio di compacità per famiglie che transformano un certo sottoinsieme compattoM 1 in uno sottoinsiemeM 2.相似文献
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