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1.
Mikkelsen Ø Skogvold SM Schrøder KH Gjerde MI Aarhaug TA 《Analytical and bioanalytical chemistry》2003,377(2):322-326
Evaluation of different solid electrode systems for detection of zinc, lead, cobalt, and nickel in process water from metallurgical nickel industry with use of differential pulse stripping voltammetry has been performed. Zinc was detected by differential pulse anodic stripping voltammetry (DPASV) on a dental amalgam electrode as intermetallic Ni–Zn compound after dilution in ammonium buffer solution. The intermetallic compound was observed at –375 mV, and a linear response was found in the range 0.2–1.2 mg L–1 (r2=0.98) for 60 s deposition time. Simultaneous detection of nickel and cobalt in the low g L–1 range was successfully performed by use of adsorptive cathodic stripping voltammetry (AdCSV) of dimethylglyoxime complexes on a silver–bismuth alloy electrode, and a good correlation was found with corresponding AAS results (r2=0.999 for nickel and 0.965 for cobalt). Analyses of lead in the g L–1 range in nickel-plating solution were performed with good sensitivity and stability by DPASV, using a working electrode of silver together with a glassy carbon counter electrode in samples diluted 1:3 with distilled water and acidified with H2SO4 to pH 2. A new commercial automatic at-line system was tested, and the results were found to be in agreement with an older mercury drop system. The stability of the solid electrode systems was found to be from one to several days without any maintenance needed. 相似文献
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3.
Mikkelsen LM Hernáiz MJ Martín-Pastor M Skrydstrup T Jiménez-Barbero J 《Journal of the American Chemical Society》2002,124(50):14940-14951
The conformational properties of the C-glycosyl analogue of the core trisaccharide alpha-D-Man-(1 --> 3)-[alpha-D-Man-(1 --> 6)]-D-Man in solution have been carefully analyzed by a combination of NMR spectroscopy and time-averaged restrained molecular dynamics. It has been found that both the alpha-1,3- and the alpha-1,6-glycosidic linkages show a major conformational averaging. Unusual Phi ca. 60 degrees orientations for both Phi torsion angles are found. Moreover, a major conformational distinction between the natural compound and the glycomimetic affects to the behavior of the omega(16) torsion angle around the alpha-1 --> 6-linkage. Despite this increased flexibility, the C-glycosyl analogue is recognized by three mannose binding lectins, as shown by NMR (line broadening, TR-NOE, and STD) and surface plasmon resonance (SPR) methods. Moreover, a process of conformational selection takes place, so that these lectins probably bind the glycomimetic similarly to the way they recognize the natural analogue. Depending upon the architecture and extension of the binding site of the lectin, loss or gain of binding affinity with respect to the natural analogue is found. 相似文献
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Alexandru Vlasceanu Dr. Søren L. Broman Anne S. Hansen Anders B. Skov Prof. Dr. Martina Cacciarini Prof. Dr. Anders Kadziola Prof. Dr. Henrik G. Kjaergaard Prof. Dr. Kurt V. Mikkelsen Prof. Dr. Mogens Brøndsted Nielsen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(31):10796-10800
The conversion and efficient storage of solar energy is recognized to hold significant potential with regard to future energy solutions. Molecular solar thermal batteries based on photochromic systems exemplify one possible technology able to harness and apply this potential. Herein is described the synthesis of a macrocycle based on a dimer of the dihydroazulene/vinylheptafulvene (DHA/VHF) photo/thermal couple. By taking advantage of conformational strain, this DHA–DHA macrocycle presents an improved ability to absorb and store incident light energy in chemical bonds (VHF–VHF). A stepwise energy release over two sequential ring‐closing reactions (VHF→DHA) combines the advantages of an initially fast discharge, hypothetically addressing immediate energy consumption needs, followed by a slow process for consistent, long‐term use. This exemplifies another step forward in the molecular engineering and design of functional organic materials towards solar thermal energy storage and release. 相似文献
6.
Stratton B. C. Knight R. Mikkelsen D. R. Blutke A. Vavruska J. 《Plasma Chemistry and Plasma Processing》1999,19(2):191-216
The technical feasibility of using an induction-coupled plasma (ICP) torch to synthesize ozone at atmospheric pressure is explored. Ozone concentrations up to ~250 ppm were achieved using a thermal plasma reactor system based on an ICP torch operating at 2.5 MHz and ~11 kVA with an argon/oxygen mixture as the plasma-forming gas. The corresponding production rate and yield were ~20 g ozone/hr and ~2g ozone/kWh, respectively. A gaseous oxygen quench formed ozone by rapid mixing of molecular oxygen with atomic oxygen produced by the torch. The ozone concentration in the reaction chamber was measured by Fourier Transform infrared (FTIR) spectroscopy over a wide range of experimental conditions and configurations. The geometry of the quench gas flow, the quench flow velocity, and the quench flow rate played important roles in determining the ozone concentration. The ozone concentration was sensitive to the torch RF power, but was insensitive to the torch gas flow rates. These observations are interpreted within the framework of a simple model of ozone synthesis. 相似文献
7.
Strain gauges are used together with the corresponding gauge factor to relate the relative electrical resistance change of the strain gauge with the strain of the underlying material. The gauge factor is found from a calibration on a stiff material - steel. Nevertheless, the gauge factor depends on the stiffness of the calibration material and ideally the calibration should be done on a similar material as tested. In practice, the gauge factor found by the strain gauge manufacturer is often used. The paper documents that even for moderately stiff materials such as glass-fibre composites a significant error is found on the strain measurements obtained by the strain gauges. This is documented both experimentally and numerically. A stiffness, also test sample and strain gauge geometry dependent correction coefficient of the gauge factor is proposed. A correction coefficient covers material stiffnesses ranging from 1 GPa to 200 GPa. 相似文献
8.
Daniel G. Barbee Clark D. Mikkelsen 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1973,24(1):73-82
Numerical solutions for the stream function, vorticity, velocity, and pressure fields are presented for the case of a steady, laminar, isothermal, Newtonian flow developing from an initial slug flow in a circular cylinder of infinite length at zero Reynolds number. 相似文献
9.
I. V. Naumov I. V. Litvinov R. F. Mikkelsen V. L. Okulov 《Thermophysics and Aeromechanics》2015,22(6):657-665
LDA and PIV techniques were used to study the decay of an axisymmetrical turbulent wake originated downstream an immobile disk in a water flume for Reynolds numbers Re = 1.5?2.4?105. Data were compared with experiments performed with a set of thermo-anemometers behind a disk in a wind tunnel at lower Reynolds numbers (Re = 1.3?2.6?104). Observations for a new range of Reynolds number confirmed that the velocity distribution in the disk wake keeps self-similarity. The decay of a wake by the power law ?2/3 in the presented experiments remains until the maximum deficit of velocity becomes comparable with the turbulent pulsation level in the free-stream (less than 2 %). 相似文献
10.
The turbulence in the interior of a wind farm is simulated using large eddy simulation and the actuator line technique implemented in the Navier–Stokes equations. The simulations are carried out for an infinitely long row of turbines simulated by applying cyclic boundary conditions at the inlet and outlet. The simulations investigate the turbulence inherent to the wind turbines as no ambient turbulence or shear is added to this idealised case. The simulated data give insight into the performance of the wind turbines operating in the wake of others as well as details on key turbulent quantities. One of the key features of wakes behind wind turbines is the dynamic wake meandering, which is shown to be related to the wind turbine spacing and the vortex shedding from the turbine as a bluff body. The flow is analysed and reconstructed by applying proper orthogonal decomposition. 相似文献