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1.
Monia Renzi Antonietta Specchiulli Davide Baroni Tommaso Scirocco Lucrezia Cilenti Silvia Focardi 《International journal of environmental analytical chemistry》2013,93(6):676-697
Samples of surface sediments and tissues (liver and muscle) of commercially available European silver eels (Anguilla anguilla L.) collected from Varano lagoon (Italy) were analysed to determine trace element contents. Univariate and multivariate analyses were performed to highlight both the differences between sampling sites and the influence of channel discharges. Atomic ratios indices for sediment data and biological enrichment factors (BEF) for eel tissues were calculated in order to evaluate the enrichment factor due to human activities. The highest levels of As (11.9?µg?g?1) and Zn (14.1?µg?g?1) were observed in the south-eastern zone of the lagoon, which is influenced by urban and agricultural discharges. The low levels of Hg observed in this study (0.04?µg?g?1) led us to exclude both natural and human local sources of this element. Trace element concentrations of all elements were lower in muscle than in liver tissue. Significant enrichment of Cu and Zn was found in livers. 相似文献
2.
Francesco A Bottino Anna Rosa Cinquegrani Giovanna Di Pasquale Leonardi Lucrezia Antonino Pollicino 《European Polymer Journal》2003,39(11):2203-2208
A series of new poly(arylene ether sulfone)s has been obtained by solution condensation polymerisation starting from 1,5- and 2,6-bis-(4-fluorosulfonyl)naphthalene with various aromatic dihydroxy compounds. The polymers, obtained in quantitative yields, possessed inherent viscosities in the range 0.28-0.68 dl g−1, had good thermal stability (10% weight loss temperatures were above 405 and 420 °C respectively in nitrogen and air) and high glass transition temperatures (in the range 217-258 °C). They have been characterised by elemental and infrared analyses, GPC and wide-angle X-ray diffraction. The properties of these poly(arylene ether sulfone)s have been compared with those of the corresponding poly(arylene ether ketone)s. 相似文献
3.
The paper shows that the variation of the relative sensitivity between different dropouts testers can defend solely on the different quality of the material at the time of the test. It is shown how this phenomenon can be determined by the dropouts frequency distribution, independently on their calibration status. 相似文献
4.
Anna Verdino Gaetano DUrso Carmen Tammone Bernardina Scafuri Lucrezia Catapano Anna Marabotti 《Molecules (Basel, Switzerland)》2021,26(19)
Classic galactosemia is an inborn error of metabolism associated with mutations that impair the activity and the stability of galactose-1-phosphate uridylyltransferase (GALT), catalyzing the third step in galactose metabolism. To date, no treatments (including dietary galactose deprivation) are able to prevent or alleviate the long-term complications affecting galactosemic patients. Evidence that arginine is able to improve the activity of the human enzyme expressed in a prokaryotic model of classic galactosemia has induced researchers to suppose that this amino acid could act as a pharmacochaperone, but no effects were detected in four galactosemic patients treated with this amino acid. Given that no molecular characterizations of the possible effects of arginine on GALT have been performed, and given that the samples of patients treated with arginine are extremely limited for drawing definitive conclusions at the clinical level, we performed computational simulations in order to predict the interactions (if any) between this amino acid and the enzyme. Our results do not support the possibility that arginine could function as a pharmacochaperone for GALT, but information obtained by this study could be useful for identifying, in the future, possible pharmacochaperones for this enzyme. 相似文献
5.
García Ruano JL Torrente E Alonso I Rodriguez M Martín-Castro AM Degl'Innocenti A Frateschi L Capperucci A 《The Journal of organic chemistry》2012,77(4):1974-1982
Phenylselenyl benzylcarbanion stabilized by an (S)-2-p-tolylsulfinyl group evolves in a highly stereoselective way in the reactions with (S)-N-(p-tolylsulfinyl)imines at -98 °C affording diastereomerically pure 1,2-selenoamino derivatives in good yields. The syn or anti relationship of the obtained compounds depends on the alkyl or aryl character of the imine. They are easily transformed into enantiomerically pure (1R,2S)-1-aryl[or (1S,2S)-1-alkyl]-2-(phenylseleno)-2-phenylethylamines by reaction with t-BuLi and subsequent methanolysis of the generated sulfinamide derivatives with TFA. 相似文献
6.
We give a topological bound on the number of minimal models of a class of three-dimensional log smooth pairs of log general type. 相似文献
7.
In this paper the solid phase synthesis of various substituted purines is described starting from 4,6-dichloro-5-nitropyrimidine. The 4,6-dichloro-5-nitropyrimidine was coupled to Rink amide resin followed by displacement of the second chloride by an amino compound. Reduction of the nitro compound proved to be problematic but was achieved using lithium aluminum hydride/aluminum trichloride. The diamines (13) were then elaborated to purines by three different routes. 相似文献
8.
In this paper, a masonry system composed of a façade wall connected with two sidewalls and subjected to out-of-plane loading is investigated within the framework of three-dimensional limit analysis. Two different modeling approaches, namely macro and micro-block models, are adopted. A rigid-perfectly plastic model with dry contact interfaces governed by Coulomb failure criterion is assumed for masonry walls with regular units and staggering (non-standard limit analysis). Three classes of failure modes are investigated, involving rocking, sliding, twisting failure and combinations of them. The macro-block model is based on the assumption that the failure involves a number of cracks which separate the structure into a few macro-blocks and all the possible relative motions among micro-blocks are concentrated along the cracks. Two limiting conditions for the ultimate load factor are kinematically computed by use of minimization routines. The micro-block model is based on a concave contact formulation in which contact points are located at the corners of interfaces, allowing failure modes involving opening and sliding to be simulated. An iterative solution procedure is used to solve the non-associative friction problem, with second order cone programming (SOCP) used to allow the conic yield function to be solved directly. Both models are validated against experimental outcomes from the literature. A parametric analysis is carried out in order to highlight the influence of each geometrical and mechanical parameter on the prevalence of a mechanism over the other. The presence of an unrestrained horizontal floor system with different orientations is also analyzed. 相似文献
9.
Lucrezia Palummo Andrea Bearzotti 《Applied Physics A: Materials Science & Processing》2009,97(4):835-839
Linseed oil is a material widely used in various applications as a protecting layer for surfaces in industry, in scientific
research, for medical use, and finally for artistic purpose. This natural origins substance has a particular application as
a protective and smoothing layer on phenolic-melaminic laminate electrodes on Resistive Plate Chamber (RPC) detectors used
in various particle physic experiments. In such electronic applications where linseed oil could be exposed to water vapours,
an electrical characterization should result useful for having an overall control of the process involving the oil. In this
paper, we studied the electrical behaviour towards relative humidity variations of linseed oil films deposited on interdigitated
metal electrodes. Moreover, I/V characterisation both in air and vacuum, current vs. temperature and relative humidity was
performed. 相似文献
10.
Paolo Cascini 《Milan Journal of Mathematics》2013,81(2):291-315
We give an overview of the study of rational curves on a complex manifold. Starting from Mori’s celebrated theorem on the extremal rays of the cone of curves, we describe some of its applications, and some of the tools used to produce rational curves in Algebraic Geometry and in Kähler Geometry. 相似文献