全文获取类型
收费全文 | 3077篇 |
免费 | 512篇 |
国内免费 | 331篇 |
专业分类
化学 | 2127篇 |
晶体学 | 25篇 |
力学 | 180篇 |
综合类 | 21篇 |
数学 | 429篇 |
物理学 | 1138篇 |
出版年
2024年 | 9篇 |
2023年 | 73篇 |
2022年 | 110篇 |
2021年 | 138篇 |
2020年 | 136篇 |
2019年 | 130篇 |
2018年 | 104篇 |
2017年 | 108篇 |
2016年 | 180篇 |
2015年 | 165篇 |
2014年 | 162篇 |
2013年 | 210篇 |
2012年 | 288篇 |
2011年 | 284篇 |
2010年 | 191篇 |
2009年 | 204篇 |
2008年 | 182篇 |
2007年 | 157篇 |
2006年 | 151篇 |
2005年 | 133篇 |
2004年 | 103篇 |
2003年 | 82篇 |
2002年 | 70篇 |
2001年 | 71篇 |
2000年 | 58篇 |
1999年 | 58篇 |
1998年 | 51篇 |
1997年 | 49篇 |
1996年 | 55篇 |
1995年 | 44篇 |
1994年 | 30篇 |
1993年 | 20篇 |
1992年 | 23篇 |
1991年 | 25篇 |
1990年 | 26篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1974年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有3920条查询结果,搜索用时 0 毫秒
1.
2.
Geng Sheng WANG 《数学学报(英文版)》2005,21(5):1005-1014
This work is concerned with Pontryagin's maximum principle of optimal control problems governed by some non-well-posed semilinear heat equations. A type of approach to the non-well-posed optimal control problem is given. 相似文献
3.
弱拓扑和强可容许拓扑之间的一个关系 总被引:2,自引:0,他引:2
本文对局部凸空间X及其对偶X′,建立了弱拓扑σ(X,X′)和强拓扑β(X,X′)之间的一个新关系,改进了有关(X,X′)--可容许拓扑全体上的不变性结果。 相似文献
4.
Settling of a large solid particle in bioconvection flow caused by gyrotactic microorganisms is investigated. The particle is released from the top of the bioconvection chamber; its settling pattern depends on whether it is released in the centre of the bioconvection plume or at its periphery. The Chimera method is utilized; a subgrid is generated around a moving particle. The method suggested by Liu and Wang (Comput. Fluid 2004; 33 :223–255) is further developed to account for the presence of a moving boundary in the streamfunction‐vorticity formulation using the finite‐difference method. A number of cases for different release positions of the particle are computed. It is demonstrated that bioconvection can either accelerate or decelerate settling of the particle depending on the initial position of the particle relative to the plume centre. It is also shown that the particle impacts bioconvection plume by changing its shape and location in the chamber. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
5.
Liang Liao Yi Pang Liming Ding Frank E. Karasz 《Journal of polymer science. Part A, Polymer chemistry》2003,41(20):3149-3158
A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λmax ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003 相似文献
6.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
7.
8.
9.
用区域分解算法结合蒙特卡罗法求坦克温度场和红外辐射出射度 总被引:3,自引:0,他引:3
本文将区域分解算法和蒙特卡罗法相结合,求坦克温度场和红外辐射出射度.采用蒙特卡罗法计算辐射传递系数,可以考虑界面的复杂辐射特性,如:镜反射、各向异性发射、各向异性反射等;可直接考虑界面的复杂几何特性,如:相互遮挡、太阳入射方向上的投影面积等.引入辐射传递系数,分离了计算的难点,使得在时间域(计算步骤)上能把整个问题分解为若干个子问题并行处理、在空间域(计算区域)上将坦克分解为若干个子区域,缩小计算规模,并可使用多个处理器并行计算;同时减轻了蒙特卡罗法编程的难度,缩短了计算时间. 相似文献
10.
The kinetics of C6H5 reactions with n‐CnH2n+2 (n = 3, 4, 6, 8) have been studied by the pulsed laser photolysis/mass spectrometric method using C6H5COCH3 as the phenyl precursor at temperatures between 494 and 1051 K. The rate constants were determined by kinetic modeling of the absolute yields of C6H6 at each temperature. Another major product C6H5CH3 formed by the recombination of C6H5 and CH3 could also be quantitatively modeled using the known rate constant for the reaction. A weighted least‐squares analysis of the four sets of data gave k (C3H8) = (1.96 ± 0.15) × 1011 exp[?(1938 ± 56)/T], and k (n‐C4H10) = (2.65 ± 0.23) × 1011 exp[?(1950 ± 55)/T] k (n‐C6H14) = (4.56 ± 0.21) × 1011 exp[?(1735 ± 55)/T], and k (n?C8H18) = (4.31 ± 0.39) × 1011 exp[?(1415 ± 65)T] cm3 mol?1 s?1 for the temperature range studied. For the butane and hexane reactions, we have also applied the CRDS technique to extend our temperature range down to 297 K; the results obtained by the decay of C6H5 with CRDS agree fully with those determined by absolute product yield measurements with PLP/MS. Weighted least‐squares analyses of these two sets of data gave rise to k (n?C4H10) = (2.70 ± 0.15) × 1011 exp[?(1880 ± 127)/T] and k (n?C6H14) = (4.81 ± 0.30) × 1011 exp[?(1780 ± 133)/T] cm3 mol?1 s?1 for the temperature range 297‐‐1046 K. From the absolute rate constants for the two larger molecular reactions (C6H5 + n‐C6H14 and n‐C8H18), we derived the rate constant for H‐abstraction from a secondary C? H bond, ks?CH = (4.19 ± 0.24) × 1010 exp[?(1770 ± 48)/T] cm3 mol?1 s?1. © 2003 Wiley Periodicals, Inc. Int J Chem Kinet 36: 49–56, 2004 相似文献