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排序方式: 共有495条查询结果,搜索用时 234 毫秒
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2.
Sarah Josefsson Rikard Westbom Lennart Mathiasson Erland Bjrklund 《Analytica chimica acta》2006,560(1-2):94-102
Pressurized liquid extractions were performed on eight sediments in order to investigate if a modified US EPA method (100 °C, 100 bar, n-heptane/acetone (1:1), 2 × 5 min) provided exhaustive extractions of polychlorinated biphenyls (PCBs) from sediment, and to study if the extractability of PCBs from the different sediments was affected by characteristics of the sediment. The recovery from the eight native sediments, contaminated in nature, was between 96.4% and 98.9%, as an average of the recoveries from 10 PCB congeners. Hundred percent recovery was defined as the sum of two consecutive extractions (2 × 5 min each) at the stated conditions. The recoveries of the individual congeners were above 94%, except for one congener in one sediment, which had a recovery of 92%. When the recoveries and different characteristics of the sediments were compared, no correlation appeared between recoveries and sediment PCB concentration, total organic carbon (TOC), soot carbon (SC) or amorphous carbon (AC). The fact that carbon did not influence the extractions was somewhat surprising, since previous experiments have indicated a connection. Instead, statistically significant (p < 0.05) correlations were observed for water content and carbon/nitrogen (C/N) ratio. The decrease in recoveries with decreased water content was attributed to less access of the solvent to the analytes due to less matrix swelling. The lowered recoveries with increased C/N ratio can indicate that a difference in structure of the organic matter exists, which influences the binding strength between the analytes and the matrix. The difference in structure can possibly be explained by different origin of the organic matter or by aging effects. Overall the method was found to be exhaustive and the excellent recoveries show that sediment characteristics do not influence the extractions markedly. 相似文献
3.
H. Bungener L. Fries und C. O'Sullivan 《Fresenius' Journal of Analytical Chemistry》1885,24(1):116-119
Ohne Zusammenfassung 相似文献
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Wedin P Martinez CJ Lewis JA Daicic J Bergström L 《Journal of colloid and interface science》2004,272(1):1-9
Stress development during drying of coatings produced from aqueous dispersions of calcium carbonate particles in the presence and absence of organic binders was studied using a controlled-environment stress apparatus that simultaneously monitored drying stress, weight loss, and relative humidity. Specifically, the influence of two organic binders on drying stress evolution was investigated: (1) carboxymethylcellulose, a water-soluble viscosifying aid, and (2) a styrene-butadiene latex emulsion of varying glass transition temperature. The stress histories exhibited three distinct regions. First, a period of stress rise was observed, which reflected the capillary tension exerted by the liquid on the particle network. Second, a maximum stress was observed. Third, it was followed by a period of either stress decay or rise depending on the organic species present. Significant differences in stress histories were observed between coatings containing soluble and nonsoluble binders. Maximum drying stresses (sigmamax) of 0.2-0.5 MPa were observed for coatings produced from pure calcium carbonate or calcium carbonate-latex suspensions, whereas coatings with carboxymethylcellulose exhibited substantially higher sigmamax values of 1-2 MPa. Upon drying, these coatings were quite hygroscopic, such that cyclic variations in relative humidity induced large cyclic changes in residual stress. 相似文献
6.
Fries G Wolf J Ilg K Walfort B Stalke D Werner H 《Dalton transactions (Cambridge, England : 2003)》2004,(12):1873-1881
A series of unsymmetrical 1,2-bis(phosphino)ethanes R(2)PCH(2)CH(2)PR'(2) and 1-arsino-2-phosphinoethanes R(2)AsCH(2)CH(2)PR'(2) mainly with bulky substituents R and R' were prepared from the cyclic sulfate by stepwise cleavage of the carbon-oxygen bonds by LiPR(2) and LiPR'(2) or LiAsR(2) and LiPR'(2), respectively. Analogously, racemic mixtures of R(2)PCH(2)CH(Me)PPh(2)(R =iPr, Cy ) as well as the enantiomers (R)-, (R)- and (R)-tBu(2)PCH(2)CH(Me)PPh(2)(R)- were obtained from the corresponding unsymmetrical cyclic sulfates and (S)-. On a similar route, the racemates of the 1,3-bis(phosphino)propanes R(2)PCH(2)CH(2)CH(Me)PPh(2)(R =iPr, tBu ), optically pure (R)- and (S,S)-iPr(2)PCH(Me)CH(2)CH(Me)PPh(2)(S,S)- were prepared. The reaction of [[RhCl([small eta](4)-C(8)H(12))](2)] with chelating ligands L-L, where L-L is R(2)PCH(2)P(men)(2)(R =iPr, Ph; men =(1S,2R,5S)-menthyl), Cy(2)AsCH(2)P(men)(2), or (R)-, (R)-, (R)-, (R)- and (S,S)-, in the presence of AgPF(6), gave the complexes [Rh(eta(4)-C(8)H(12))(L-L)]PF(6) which were used as pre-catalysts in the hydrogenation of the methyl ester of alpha-acetamidocinnamic acid (ACM). Depending on L-L, the solvent, the temperature and the pressure of H(2), optical yields of up to 69% ee were achieved. For two of the rhodium complexes, and, the molecular structures were determined by X-ray crystallography. 相似文献
7.
The two isomeric tris(trichlorothienyl)carbinols have been synthesized. Upon treatment with acid the tris(trichlorothienyl)carbenium ions were formed, which upon reduction with iodide gave the tris(trichlorothienyl)methyl radicals, which were studied by epr-spectroscopy. The β-isomer, the tris(2,4,5-trichloro-3-thienyl)methyl radical, was much more stable than the α-isomer and showed great similarity to the perchlorotrityl radical. 相似文献
8.
Olsson M Joabsson F Piculell L 《Langmuir : the ACS journal of surfaces and colloids》2005,21(4):1560-1567
The influence of added colloidal particles on the phase separation of mixed aqueous polymer solutions is investigated. Two types of particles (polystyrene latex or silica) and different combinations of segregating polymers (dextran of varying molar mass combined with poly(ethylene oxide) (PEO) of varying molar mass, or Ucon, a copolymer of ethylene oxide and propylene oxide) were used. All systems displayed particle-induced instability effects, but the extent of the effect varied strongly between the various combinations and with the amount of added salt. Very large instability effects were seen in certain mixtures. Two mechanisms, both relying on the adsorption of at least one of the polymers to the particle surface, seem to operate. Close to the cloud-point curve of the particle-free polymer1/polymer2/water mixture, adsorption of PEO or Ucon to the particles gives rise to a capillary-induced phase separation. Close to the dextran/water axis of the phase diagram, the adsorbing polymer gives rise to a surface modification of the particles, which then interacts repulsively with the surrounding dextran solution. 相似文献
9.
Bonnet C Gadelle A Pécaut J Fries PH Delangle P 《Chemical communications (Cambridge, England)》2005,(5):625-627
The cyclodextrin derivative (hexakis (2-O-carboxymethyl-3,6-anhydro)-alpha-cyclodextrin) forms mono- and bimetallic complexes with lutetium(III) in aqueous solution; the X-ray structure of the binuclear complex [Lu2(ACX)(H2O)2] is the first example of a lanthanide-cyclodextrin inclusion complex. 相似文献
10.
Egermayer M Karlberg M Piculell L 《Langmuir : the ACS journal of surfaces and colloids》2004,20(6):2208-2214
Previous work has shown that amylose (AM) can cross-link hydrophobically modified polymers by inclusion complexation, whereby thermoreversible cold-setting gels are formed. Here we investigate the complexation of AM with different samples of hydrophobically modified ethyl(hydroxyethyl) cellulose (HMEHEC), distinguished by differences in the architecture of the hydrophobes (the hydrophobic side chains). All hydrophobes, except one, were based on linear alkyl chains, but with varying chain lengths (C12-C14). In addition, some samples contained short hydrophilic "spacers", consisting of 2-5 ethylene oxide units, between the alkyl chains and the EHEC backbone. Gels of varying strength were obtained for the different AM/HMEHEC samples. The alkyl chain length seemed to be the major factor affecting the gel strength, with longer alkyl chains giving stronger gels. For similar alkyl chain lengths, stronger gels were obtained when a spacer was present. Addition of AM caused a small increase of the cloud points of HMEHECs with C14 hydrophobes in water. Time-dependent effects and effects of the sample preparation procedure were also investigated. The reversibility of the gelation with respect to shear was confirmed. A gel destroyed by added surfactant was shown to reform on removal of the surfactant by dialysis. 相似文献