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排序方式: 共有54条查询结果,搜索用时 15 毫秒
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在甲烷氧化偶联制C2烃的研究中,人们发现碱土金属与稀土金属组成的复合氧化物催化剂具有高的催化活性[1,2].稀土化合物作为有希望的工业催化剂之一,已受到广泛的关注.一般认为,它们含有的氧空位对活化甲烷的有效氧物种有利.Debey等在1%Sr/La2O... 相似文献
3.
Zanhong Deng Xiaodong Fang Suzhen Wu Weiwei Dong Jingzhen Shao Shimao Wang Man Lei 《Journal of Sol-Gel Science and Technology》2014,71(2):297-302
Single phase delafossite CuFeO2 thin films were synthesized by a simple sol–gel method. The influence of polyethylene glycol (PEG) on the morphology and optoelectronic properties of the films was studied by addition of 1.0 g PEG in 10 ml precursor solution. The crystal sizes of the derived CuFeO2 films with and without addition of PEG were 49 nm, but the sample with addition of PEG (labeled as CFO-PEG) showed weaker c-axis orientation growth. The sample without addition of PEG (labeled as CFO) showed a compact surface without detectable pores and had a thickness around 50 nm. However, the sample CFO-PEG exhibited a porous surface with worm-like grains in nanometric scale and had a thickness around 310 nm. Enhanced absorbance in UV–vis region was observed for the sample CFO-PEG which might ascribe to both the thickness and porous surface. The optical direct bandgaps at near-UV were estimated to be ~3.0 and 3.38 eV for the sample CFO-PEG and CFO, respectively. Though the porous surface of CFO-PEG has improved the absorbance in UV–vis region, the resistivity has also been increased due to the homogeneous distribution of interspaces between the worm-like grains, which makes the incident photon to current efficiency of CFO-PEG lower than that of CFO. 相似文献
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The polylactic acid (PLA) nanofiber membranes reinforced with hyperbranched PLA‐modified cellulose nanocrystals (H‐PLA‐CNCs) were prepared by electrospinning. The H‐PLA‐CNCs and the nanofiber membranes were researched by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA). The outcomes embodied that the cellulose nanocrystals (CNCs) could be successfully improved by the hyperbranched PLA, which would offer powerful CNCs/matrix interfacial adhesion. Thus, the mechanical and shape memory properties of PLA can be improved by adding the H‐PLA‐CNCs. In particular, when the addition of H‐PLA‐CNCs was 7 wt%, the tensile strength and an ultimate strain of PLA composite nanofiber membranes was 15.56 MPa and 25%, which was 228% and 72.4% higher than that of neat PLA, respectively. In addition, the shape recovery rate of the PLA/5 wt% H‐PLA‐CNCs composite nanofiber membrane was 93%, which was 37% higher than that of neat PLA. We expected that this present study would provide unremitting efforts for the development of more effective approaches to prepare biology basic shape memory membranes with high mechanical properties. 相似文献
5.
Zeng Liangwei Belić Milivoj R. Mihalache Dumitru Shi Jincheng Li Jiawei Li Siqi Lu Xiaowei Cai Yi Li Jingzhen 《Nonlinear dynamics》2022,108(2):1671-1680
Nonlinear Dynamics - We demonstrate the existence of various types of gap localized modes, including one- and two-dimensional (1D and 2D) single solitons and soliton clusters, as well as the... 相似文献
6.
大型火箭起飞横向漂移测量系统研究 总被引:1,自引:0,他引:1
本文论及了大型火箭发射起飞段横向漂移量的近距离高速摄影测量系统和数据处理方法。 相似文献
7.
A Two‐Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis,Structure, and Reactivity 下载免费PDF全文
Jingzhen Du Linbo Wang Prof. Dr. Meihua Xie Prof. Dr. Liang Deng 《Angewandte Chemie (International ed. in English)》2015,54(43):12640-12644
The synthesis, structural characterization, and reactivity of the first two‐coordinate cobalt complex featuring a metal–element multiple bond [(IPr)Co(NDmp)] ( 4 ; IPr=1,3‐bis(2′,6′‐diisopropylphenyl)imidazole‐2‐ylidene; Dmp=2,6‐dimesitylphenyl) is reported. Complex 4 was prepared from the reaction of [(IPr)Co(η2‐vtms)2] (vtms=vinyltrimethylsilane) with DmpN3. An X‐ray diffraction study revealed its linear C? Co? N core and a short Co? N distance (1.691(6) Å). Spectroscopic characterization and calculation studies indicated the high‐spin nature of 4 and the multiple‐bond character of the Co? N bond. Complex 4 effected group‐transfer reactions to CO and ethylene to form isocyanide and imine, respectively. It also facilitated E? H (E=C, Si) σ‐bond activation of terminal alkyne and hydrosilanes to produce the corresponding cobalt(II) alkynyl and cobalt(II) hydride complexes as 1,2‐addition products. 相似文献
8.
有向图的边割(X,Y)中|X|和|Y|的下界与有向图的极大性和超级性 总被引:1,自引:0,他引:1
在已有的极大边连通、超级边连通、极大局部边连通有向图概念的基础上,提出超级局部边连通有向图的概念,对一般的、二部的、基础图的团数至多为p的有向图、定向图分别给出|(X,Y)|<δ(D)的边割(X,Y)、非平凡的最小边割(X,Y)中|X|和|Y|的下界,据此分别得到极大边连通、超级边连通有向图的最小度条件.类似地分别得到... 相似文献
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一阶数≥3的简单连通图叫做1-Hamilton连通的,若对每一对顶点v_1、v_2及任一边v_2v_3(v_1≠v_3),存在连接v_1和v_2,并且经过v_3v_2的Hamilton路.本文中我们证明:连通图的树图或是1-Hamilton连通的,或为一超立方体,或同构于K_2×K_3和W_5之一. 相似文献