全文获取类型
收费全文 | 11912篇 |
免费 | 382篇 |
国内免费 | 15篇 |
专业分类
化学 | 6368篇 |
晶体学 | 84篇 |
力学 | 251篇 |
数学 | 2558篇 |
物理学 | 3048篇 |
出版年
2022年 | 100篇 |
2021年 | 134篇 |
2020年 | 187篇 |
2019年 | 164篇 |
2018年 | 206篇 |
2017年 | 215篇 |
2016年 | 459篇 |
2015年 | 418篇 |
2014年 | 449篇 |
2013年 | 811篇 |
2012年 | 592篇 |
2011年 | 724篇 |
2010年 | 464篇 |
2009年 | 385篇 |
2008年 | 450篇 |
2007年 | 421篇 |
2006年 | 316篇 |
2005年 | 189篇 |
2004年 | 226篇 |
2003年 | 216篇 |
2002年 | 208篇 |
2001年 | 169篇 |
2000年 | 187篇 |
1999年 | 174篇 |
1998年 | 157篇 |
1997年 | 142篇 |
1996年 | 147篇 |
1995年 | 135篇 |
1994年 | 128篇 |
1993年 | 117篇 |
1992年 | 120篇 |
1991年 | 100篇 |
1990年 | 118篇 |
1989年 | 96篇 |
1988年 | 94篇 |
1987年 | 96篇 |
1986年 | 93篇 |
1985年 | 134篇 |
1984年 | 149篇 |
1983年 | 97篇 |
1982年 | 119篇 |
1981年 | 118篇 |
1980年 | 101篇 |
1979年 | 112篇 |
1978年 | 115篇 |
1977年 | 99篇 |
1976年 | 119篇 |
1975年 | 113篇 |
1974年 | 109篇 |
1968年 | 102篇 |
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
1.
Dominik Vítek Prof. Aleš Růžička Lise Vermeersch Dr. Libor Dostál Dr. Jan Turek Prof. Roman Jambor 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(70):e202202639
Reactivity studies of the GeII→B complex L(Cl)Ge⋅BH3 ( 1 ; L=2-Et2NCH2-4,6-tBu2-C6H2) were performed to determine the effect on the GeII→B donation. N-coordinated compounds L(OtBu)Ge⋅BH3 ( 2 ) and [LGe⋅BH3]2 ( 3 ) were prepared. The possible tuning of the GeII→B interaction was proved experimentally, yielding compounds 1-PPh2-8-(LGe)-C10H6 ( 4 ) and L(Cl)Ge⋅GaCl3 ( 5 ) without a GeII→B interaction. In 5 , an unprecedented GeII→Ga coordination was revealed. The experimental results were complemented by a theoretical study focusing on the bonding in 1 − 5 . The different strength of the GeII→E (E=B, Ga) donation was evaluated by using energy decomposition analysis. The basicity of different L(X)Ge groups through proton affinity is also assessed. 相似文献
2.
Dr. Joaquim Torra Dr. Felipe Viela Dr. Diego Megías Dr. Begoña Sot Prof. Cristina Flors 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(19):e202200026
CRANAD-2 is a fluorogenic curcumin derivative used for near-infrared detection and imaging in vivo of amyloid aggregates, which are involved in neurodegenerative diseases. We explore the performance of CRANAD-2 in two super-resolution imaging techniques, namely stimulated emission depletion (STED) and single-molecule localization microscopy (SMLM), with markedly different fluorophore requirements. By conveniently adapting the concentration of CRANAD-2, which transiently binds to amyloid fibrils, we show that it performs well in both techniques, achieving a resolution in the range of 45–55 nm. Correlation of SMLM with atomic force microscopy (AFM) validates the resolution of fine features in the reconstructed super-resolved image. The good performance and versatility of CRANAD-2 provides a powerful tool for near-infrared nanoscopic imaging of amyloids in vitro and in vivo. 相似文献
3.
Zakrajšek Srečko Rajkovič Vladislav Bernik Mojca Jereb Eva Rajkovič Uroš 《Central European Journal of Operations Research》2021,29(3):841-857
Central European Journal of Operations Research - Digital competences are among the most important competences in modern society, with the education system playing a key role in the acquisition of... 相似文献
4.
5.
6.
Marius Lupu Adnana Zaulet Prof. Dr. Francesc Teixidor Prof. Dr. Eliseo Ruiz Prof. Dr. Clara Viñas 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(18):6888-6897
The metallacarborane [3,3′‐Co(1,2‐closo‐C2B9H11)2]? has been synthesized. This species allows the formation of redox couples in which both partners are negatively charged. The E1/2 potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3′‐Co(1,2‐closo‐C2B9H7I4)2]? is the most favorable, as it is isolatable and stable in air. A DFT study on stability and redox potentials of complexes has been performed. 相似文献
7.
Nováková Kateřina Hrdlička Vojtěch Navrátil Tomáš Vyskočil Vlastimil Barek Jiří 《Monatshefte für Chemie / Chemical Monthly》2015,146(5):761-769
Monatshefte für Chemie - Chemical Monthly - The voltammetric behavior of 5-nitroindazole was investigated at polished (p-AgSAE) and at mercury meniscus-modified (m-AgSAE) silver solid amalgam... 相似文献
8.
Formation of porous polymer morphology by microsyneresis during divinylbenzene polymerization
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Libuše Hanková Ladislav Holub Karel Jeřábek 《Journal of Polymer Science.Polymer Physics》2015,53(11):774-781
This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781 相似文献
9.
10.
Mejía Hugo Fernando Giraldo Jiménez-Piqué Emilio Valdés Matías Procaccini Raúl Pellice Sergio 《Journal of Solid State Electrochemistry》2020,24(10):2451-2460
Journal of Solid State Electrochemistry - A novel material was developed using sol-gel chemistry and an environmental-friendly grafting process of clay nanoparticles. In a previous work of our... 相似文献