Stochastic processes of a quantum state

Starting from a quantum state represented by its wave function (x), satisfying the Schrödinger equation, we determine stochastic processes which provide the same time evolution for the probability density(x)=¦(x)¦². The transition probabilities of these processes are explicitly built in two circumstances: in the general case, but in an expansion in the time difference, and exactly, but for Gaussian processes. This allows us to discuss the correspondence between quantum states and stochastic processes, which appears not to be one-to-one, but, on the contrary, to associate with the same state an infinity of processes which differ in the fluctuation correlations of the random variable.     

Insights into the Structure and Energy of DNA Nanoassemblies

Since the pioneering work of Ned Seeman in the early 1980s, the use of the DNA molecule as a construction material experienced a rapid growth and led to the establishment of a new field of science, nowadays called structural DNA nanotechnology. Here, the self-recognition properties of DNA are employed to build micrometer-large molecular objects with nanometer-sized features, thus bridging the nano- to the microscopic world in a programmable fashion. Distinct design strategies and experimental procedures have been developed over the years, enabling the realization of extremely sophisticated structures with a level of control that approaches that of natural macromolecular assemblies. Nevertheless, our understanding of the building process, i.e., what defines the route that goes from the initial mixture of DNA strands to the final intertwined superstructure, is, in some cases, still limited. In this review, we describe the main structural and energetic features of DNA nanoconstructs, from the simple Holliday junction to more complicated DNA architectures, and present the theoretical frameworks that have been formulated until now to explain their self-assembly. Deeper insights into the underlying principles of DNA self-assembly may certainly help us to overcome current experimental challenges and foster the development of original strategies inspired to dissipative and evolutive assembly processes occurring in nature.     

In situ hydrolysis of imine derivatives on Au(111) for the formation of aromatic mixed self-assembled monolayers: multitechnique analysis of this tunable surface modification

This paper presents a novel method for preparing aromatic, mixed self-assembled monolayers (SAMs) with a dilute surface fraction coverage of protonated amine via in situ hydrolysis of C═N double bond on gold surface. Two imine compounds, (4'-(4-(trifluoromethyl)benzylideneamino)biphenyl-4-yl)methanethiol (CF(3)-C(6)H(4)-CH═N-C(6)H(4)-C(6)H(4)-CH(2)-SH, TFBABPMT) and (4'-(4-cyanobenzylideneamino)biphenyl-4-yl)methanethiol (CN-C(6)H(4)-CH═N-C(6)H(4)-C(6)H(4)-CH(2)-SH, CBABPMT), self-assembled on Au(111) to form highly ordered monolayers, which was demonstrated by infrared reflection absorption spectroscopy (IRRAS) and X-ray photoelectron spectroscopy (XPS). A nearly upright molecular orientation for CF(3)- and CN-terminated SAM was detected by near edge X-ray absorption fine structure (NEXAFS) measurements. Afterward, the acidic catalyzed hydrolysis was carried out in chloroform or an aqueous solution of acetic acid (pH = 3). Systematic studies of this hydrolysis process for CN-terminated SAM in acetic acid at 25 °C were performed by NEXAFS measurements. It was found that about 30% of the imine double bonds gradually cleaved in the first 40 min. Subsequently, a larger hydrolysis rate was observed due to the freer penetration of acetic acid in the SAM and resultant more open molecular packing. Furthermore, the molecular orientation in mixed SAMs did not change during the whole hydrolysis process. This partially hydrolyzed surface contains a controlled amount of free amines/ammonium ions which can be used for further chemical modifications.     

Estimation of Macrodispersion by Different Approximation Methods for Flow and Transport in Randomly Heterogeneous Media

We present two- and three-dimensional calculations for the longitudinal and transverse macrodispersion coefficient for conservative solutes derived by particle tracking in a velocity field which is based on the linearized flow equation. The simulations were performed upto 5000 correlation lengths in order to reach the asymptotic regime. We used a simulation method which does not need any grid and therefore allows simulations of very large transport times and distances.Our findings are compared with results obtained from linearized transport, from Corrsin's Conjecture and from renormalization group methods. All calculations are performed with and without local dispersion. The variance of the logarithm of the hydraulic conductivity field was chosen to be one to investigate realistic model cases.While in two dimensions the linear transport approximation seems to be very good even for this high variance of the logarithmic hydraulic conductivity, in three dimensions renormalization group results are closer to the numerical calculations. Here Dagan's theory and the theory of Gelhar and Axness underestimate the transverse macrodispersion by far. Corrsin's Conjecture always overestimates the transverse dispersion. Local dispersion does not significantly influence the asymptotic behavior of the various approximations examined for two-dimensional and three-dimensional calculations.     

Conformal Symmetry and Quantum Relativity

The relativistic conception of space and time is challenged by the quantum nature of physical observables. It has been known for a long time that Poincare symmetry of field theory can be extended to the larger conformal symmetry. We use these symmetries to define quantum observables associated with positions in space-time, in the spirit of Einstein theory of relativity. This conception of localization may be applied to massive as well as massless fields. Localization observables are defined as to obey Lorentz covariant commutation relations and in particular include a time observable conjugated to energy. While position components do not commute in the presence of a nonvanishing spin, they still satisfy quantum relations which generalize the differential laws of classical relativity. We also give of these observables a representation in terms of canonical spatial positions, canonical spin components, and a proper time operator conjugated to mass. These results plead for a new representation not only of space-time localization but also of motion.     

Single-pion production in pp collisions at 0.95 GeV/c (I)

The single-pion production reactions pp → dπ⁺, pp → npπ⁺ and pp → ppπ⁰ were measured at a beam momentum of 0.95GeV/c ( T _p ≈ 400MeV) using the short version of the COSY-TOF spectrometer. The implementation of a central calorimeter provided particle identification, energy determination and neutron detection in addition to time-of-flight and angle measurements. Thus, all pion production channels were recorded with 1-4 overconstraints. The total and differential cross-sections obtained are compared to previous data and theoretical calculations. Main emphasis is put on the discussion of the ppπ⁰ channel, where we obtain angular distributions different from previous experimental results, however, partly in good agreement with recent phenomenological and theoretical predictions. In particular, we observe very large anisotropies for the π⁰ angular distributions in the kinematical region of small relative proton momenta revealing there a dominance of proton spinflip transitions associated with π⁰ s and d partial waves and emphasizing the important role of π⁰ d-waves.     

Gravitational decoherence of atomic interferometers

We study the decoherence of atomic interferometers due to the scattering of stochastic gravitational waves. We evaluate the “direct” gravitational effect registered by the phase of the matter waves as well as the “indirect” effect registered by the light waves used as beam-splitters and mirrors for the matter waves. Considering as an example the space project HYPER, we show that both effects are negligible for the presently studied interferometers. Received 15 February 2002 / Received in final form 12 April 2002 Published online 19 July 2002     

Selectivity optimization in liquid chromatography via stationary phase tuning

In striving for the best possible separation, the selectivity of stationary phases as an optimization parameter is often underestimated although there are many ways to influence this powerful tool. This review serves to provide an insight into the various ways of adapting the selectivity of a separation in liquid chromatography. Approaches via temperature and flow rate tuning are discussed as a basis followed by focusing on the stationary phase as the superior optimization parameter. Highly selective stationary phases hereby provide an advantage for groups of similar analytes. For more complex mixtures, separations can be improved using mixed-mode technologies where different retention mechanisms are combined. Serial coupling, mixed-bed columns, and stationary phase optimized selectivity liquid chromatography provide solutions to various degrees. Finally, the advantages of stationary phase tuning over adaption of mobile phase and/or temperature are presented in terms of optimum application range.     

Single-pion production in pp collisions at 0.95 GeV/c (II)

The single-pion production reactions pp d , pp np and pp pp were measured at a beam momentum of 0.95GeV/c ( T _p 400 MeV) using the short version of the COSY-TOF spectrometer. The central calorimeter provided particle identification, energy determination and neutron detection in addition to time-of-flight and angle measurements from other detector parts. Thus all pion production channels were recorded with 1-4 overconstraints. The main emphasis is put on the presentation and discussion of the np channel, since the results on the other channels have already been published previously. The total and differential cross-sections obtained are compared to theoretical calculations. In contrast to the pp channel we observe in the np channel a strong influence of the excitation. In particular, the pion angular distribution exhibits a (3 cos² + 1) -dependence, typical for a pure s -channel excitation and identical to that observed in the d channel. Since the latter is understood by a s -channel resonance in the ¹ D ₂ pn partial wave, we discuss an analogous scenario for the pn channel.