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1.
2.
Admissible slopes for monotone and convex interpolation 总被引:1,自引:0,他引:1
Summary In many applications, interpolation of experimental data exhibiting some geometric property such as nonnegativity, monotonicity or convexity is unacceptable unless the interpolant reflects these characteristics. This paper identifies admissible slopes at data points of variousC
1 interpolants which ensure a desirable shape. We discuss this question, in turn for the following function classes commonly used for shape preserving interpolations: monotone polynomials,C
1 monotone piecewise polynomials, convex polynomials, parametric cubic curves and rational functions. 相似文献
3.
Ioana Dumitriu Alan Edelman 《Annales de l'Institut Henri Poincaré (B) Probabilités et Statistiques》2005,41(6):1083-1099
In this paper we examine the zero and first order eigenvalue fluctuations for the β-Hermite and β-Laguerre ensembles, using tridiagonal matrix models, in the limit as β→∞. We prove that the fluctuations are described by multivariate Gaussians of covariance O(1/β), centered at the roots of a corresponding Hermite (Laguerre) polynomial. The covariance matrix itself is expressed as combinations of Hermite or Laguerre polynomials respectively.We show that the approximations are of real value even for small β; we can use them to approximate the true functions even for the traditional β=1,2,4 values. 相似文献
4.
Inna Bumagina 《Geometriae Dedicata》2004,106(1):211-230
A group is said to be Hopfian if every surjective endomorphism of the group is injective. We show that finitely generated subgroups of torsion-free hyperbolic groups are Hopfian. Our proof generalizes a theorem of Sela (Topology
35 (2) 1999, 301–321). 相似文献
5.
Consider a labeled convex n-gon in the plane and a point x in general position in the interior. We associate with this a collection (x) of 3-element sets, namely those 3-element subsets of the vertices which contain x in their interior. We investigate the problem of characterizing those collections of subsets which can be represented in this matter. We give a complete characterization of this and a related problem.School of Mathematics, University of Minnesota, Minneapolis, MN 55455. This work was supported in part by NSF grant DMS-8700995.Department of Mathematics, University College London, Gower Street, London, WC1E 6BT, England. Work done while Hill Visiting Professor at the University of Minnesota. 相似文献
6.
Fireman-Shoresh S Popov I Avnir D Marx S 《Journal of the American Chemical Society》2005,127(8):2650-2655
Enantioselective surfactant-templated thin films were fabricated through the sol-gel (SG) process. The enantioselectivity is general in the sense that it discriminates between pairs of enantiomers not used for the imprinting process. The chiral cationic surfactant (-)-N-dodecyl-N-methylephedrinium bromide (1) was used as the surfactant template, and after its extraction chiral domains were created. The chiral discriminative feature of these films was examined by challenging with pure enantiomer solutions for rebinding. Selective adsorption was shown using (R)- and (S)-propranolol, (R)-2 and (S)-2, respectively, and (R)- and (S)-2,2,2-trifluoro-1-(9-anthryl)ethanol, (R)-3 and (S)-3, respectively, as the chiral probes. The selective adsorption was measured by fluorescence analysis, and the chiral selectivity factors were found to be 1.6 for 2 and 2.25 for 3. In both cases, (R)-enantiomer was adsorbed preferably. The resulting material was characterized by transmission electron microscopy, by diffraction, and by surface area measurements, and was found to be semicrystalline with short-range ordered domains (50 A) of hexagonal symmetry. 相似文献
7.
Let Z be a centrally symmetric polygon with integer side lengths. We answer the following two questions:
- When is the associated discriminantal hyperplane arrangementfree in the sense of Saito and Terao?
- When areall of the tilings of Z by unit rhombicoherent in the sense of Billera and Sturmfels?
8.
Nikolai N. Brandt Andrey Yu. Chikishev Inna K. Sakodinskaya 《Journal of Molecular Structure》2003,648(3):177-182
Raman spectroscopy is employed to study tris-(hydroxymethyl)aminomethane and its complexes with 18-crown-6. The results obtained are used to interpret the known effect of α-chymotrypsin activation by crown ether in organic solvents. Raman spectra of the samples lyophilized from aqueous solutions at various pH values are measured in solid state, acetonitrile and cyclohexane. 相似文献
9.
Kocher N Henn J Gostevskii B Kost D Kalikhman I Engels B Stalke D 《Journal of the American Chemical Society》2004,126(17):5563-5568
The concept of hypervalency in molecules, which hold more than eight valence electrons at the central atom, still is a topic of constant debate. There is general interest in silicon compounds with more than four substituents at the central silicon atom. The dispute, whether this silicon is hypervalent or highly coordinated, is enlightened by the first experimental charge density determination and subsequent topological analysis of three different highly polar Si-E (E = N, O, F) bonds in a hexacoordinated compound. The experiment reveals predominantly ionic bonding and much less covalent contribution than commonly anticipated. For comparison gas-phase ab initio calculations were performed on this compound. The results of the theoretical calculations underline the findings of the experiment. 相似文献
10.