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1.
Sulfated zirconia catalysts were prepared by sol-gel process using a new method allowing the control of the hydrolysis step of zirconium alkoxides. Prepared samples were characterized by N2 adsorption (desorption) at 77 K, XRD, chemical analysis of total sulfur and XPS. Catalytic properties have been evaluated in n-butane and n-hexane isomerization reactions. Obtained results show that time necessary for gelation is significant and depends considerably on the nature of the zirconium precursor. Concerning the properties of the solids obtained by this method, it has been noted that the use of the zirconium propoxide led to a better retention of the sulfate species, which improves activity during isomerization reactions. It has been found also that an initial S/Zr molar ratio equal to 0.5 allowed to obtain an optimal sulfur content and a high specific surface area.  相似文献   
2.
In this work, the metal dispersion of the Pd/Al2O3 catalyst prepared by sol-gel method is improved by an adequate optimisation of the preparative variables. First, the gelation temperature and the ageing time are selected, in order to avoid the reduction of the metal precursor (palladium acetylacetonate, Pd(acac)2) by the solvent (sec-butanol, sB). The metal sintering effect on the catalysts treated in oxygen at 500°C is then minimized when the alumina pore size is controlled by the variation of the alumium alkoxide (AsB) concentration and the acetic acid amount ([AcA]/[AsB]). The appearance of new palladium particles on the alumina surface and the matching between the particle diameters and the pore sizes were also effective for the metallic surface area improvement on the samples treated in oxygen at 800°C. Compared to the reference catalysts, the higher metal dispersion obtained on the sol-gel ones was the determinant factor for their higher catalytic activity in methane combustion.  相似文献   
3.
Kamoun  N.  Younes  M. K.  Ghorbel  A.  Mamede  A. S.  Rives  A. 《Ionics》2015,21(1):221-229
Ionics - A series of Ni/ZrO2–SO4 2− and Ni/ZrO2–Al2O3–SO4 2− catalysts were prepared in one step by the sol–gel method and dried in hypercritical conditions of...  相似文献   
4.
Catalysts based on chromium supported by sulphated and unsulphated zirconia have been synthesised, in one step, by sol–gel method and dried in hypercritical solvent conditions. Comparative study of their catalytic properties shows that dispersed Cr3+ seems to be the active species in the n-hexane aromatisation reaction. However, the acidity generated by sulphate groups acts as coke eliminator of the layers deposed on the surface mainly when catalyst is calcined at high temperature.  相似文献   
5.
Najar  H.  Saïd Zina  M.  Ghorbel  A. 《Kinetics and Catalysis》2010,51(4):602-608
Palladium-based catalysts were prepared by the ion-exchange method with dealuminated HY zeolite as support. The support dealumination was realised using acid solution of HNO3, HCl or H2SiF6. The high activity of prepared catalysts for methane combustion was observed. This activity was dependent on the Al concentration, structural and textural properties of the support changed after the dealumination. Especially, Pd loaded on supports developing a second pore system, and having the highest Si/Al ratio, was more active than that on unmodified supports. It was also expected that the active sites in the methane combustion, which are suspected to be PdO, were influenced by the acidic properties of the support.  相似文献   
6.
In this work, we investigate the following inhomogeneous model of fragmentation with an exponential splitting probability: suppose that an initial particle having a mass x0>0 (large enough) is broken, with a size-dependent probability , into b>1 pieces. With probability 1−p(x0), this fragment is left unchanged for ever. The process of fragmentation is repeated recursively for all pieces.Some statistical features are studied, chiefly the fragment size distribution, number of fragments and partition function of the random fragmentation tree. Also, we give details of the numerical analysis of these features.  相似文献   
7.
This work is a continuation of the paper [9], where a particular fragmentation process of a unit interval II, according to a β-size-biased picking procedure (β ∈ ℝ) is investigated. It results from the splitting process, the production of a random countable partition of unity together with another random partitioning of some random quantity Z > 0.  相似文献   
8.
Journal of Thermal Analysis and Calorimetry - Thermal decomposition (2 K min?1) of ammonium heptamolybdate tetrahydrate, performed between room temperature and...  相似文献   
9.
An extracellular, endo-??-1,4-xylanase was purified to homogeneity from the culture filtrate of the filamentous fungus Penicillium occitanis Pol6, grown on oat spelt xylan. The purified enzyme (PoXyn2) showed a single band on SDS?CPAGE with an apparent molecular weight of 30?kDa. The xylanase activity was optimal at pH?3.0 and 65?°C. The specific activity measured for oat spelt xylan was 2,368?U?mg?1. The apparent K m and V max values were 8.33?mg?ml?1 and 58.82???mol?min?1?ml?1, respectively, as measured on oat spelt xylan. Thin-layer chromatography experiments revealed that purified PoXyn2 degrades xylan in an endo-fashion releasing xylobiose as main end product. The genomic DNA and cDNA encoding this protein were cloned and sequenced. This PoXyn2 presents an open reading frame of 962?bp, not interrupted by any introns and encoding for a mature protein of 320 amino acids and 29.88?kDa.  相似文献   
10.
In this paper, two speech enhancement algorithms (SEAs) based on spectral subtraction (SS) principle have been evaluated for bilateral cochlear implant (BCI) users. Specifically, dual-channel noise power spectral estimation algorithm using power spectral densities (PSD) and cross power spectral density (CPSD) of the observed signals was studied. The enhanced speech signals were obtained using either Dual Channel Non Linear Spectral Subtraction ‘DC-NLSS’ or Dual-Channel Multi-Band Spectral Subtraction ‘DC-MBSS’ algorithms. For performance evaluation, some objective speech assessment tests relying on Perceptual Evaluation of Speech Quality (PESQ) score and speech Itakura-Saito (IS) distortion measurement were performed to fix the optimal number of frequency band needed in DC-MBSS algorithm. In order to evaluate the speech intelligibility, subjective listening tests were assessed with 50 normal hearing listeners using a specific BCI simulator and with three deafened BCI patients. Experimental results, obtained using French Lafon database corrupted by an additive babble noise at different Signal-to-Noise Ratios (SNR), showed that DC-MBSS algorithm improves speech understanding better than DC-NLSS algorithm for single and multiple interfering noise sources.  相似文献   
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