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Dmitry S. Zimnitsky Tatiana L. Yurkshtovich Pavel M. Bychkovsky 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4785-4791
Samples of oxidized cellulose (OC) with various carboxyl contents and degrees of crystallinity were obtained by the oxidation of native and mercerized cellulose with a solution of nitrogen(IV) oxide in CCl4. A detailed characterization of these OC samples was performed. The effect of oxidation conditions (concentration of N2O4 in the solution and oxidation time) and starting cellulose material on OC characteristics (carboxyl, carbonyl and nitrogen content, degree of crystallinity and polymerization, surface area and swelling, and acidic properties) was investigated. Reactivity in the oxidation process was higher in mercerized cellulose than in native cellulose. The action of dilute solutions (10–15%) of N2O4 did not affect the degree of crystallinity of cellulose samples. Under these conditions, the oxidation took place mainly in amorphous regions and on the surface of crystallites. Oxidation in a concentrated (40%) N2O4 solution led to the destruction of crystallites, which increased the surface area and swelling of cellulose in water. The surface area and the swelling of OC samples increased with a decrease in the index of crystallinity. The acidic properties of OC were shown to increase with an increase of swelling in water. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4785–4791, 2004 相似文献
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Dmitry Panchenko 《Random Structures and Algorithms》2004,24(1):65-74
Using Talagrand's concentration inequality on the discrete cube {0, 1}m we show that given a real‐valued function Z(x) on {0, 1}m that satisfies certain monotonicity conditions one can control the deviations of Z(x) above its median by a local Lipschitz norm of Z at the point x. As one application, we obtain a deviation inequality for the number of k‐cycles in a random graph. © 2003 Wiley Periodicals, Inc. Random Struct. Alg., 2004 相似文献
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Alexander N Shivanyuk Dmitry M Rudkevich David N Reinhoudt 《Tetrahedron letters》1996,37(52):9341-9344
An assembly of cation receptor 1 and anion receptor 2 via the hydrogen bonding melamine-barbiturate structural motif complexes sodium thiocyanate, sodium iodide, and sodium azide in apolar solvents. 相似文献
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The dependencies of the effective Hall properties on a scale, obtained by means of an iterative averaging method, manifest their fractal character. The influence of an intensity of the Hall effect on the fractal character of the Hall properties was considered. Scale ranges and dimensional characteristics of the effective Hall properties behavior were calculated and discussed. 相似文献
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Dmitry Dolgopyat 《Transactions of the American Mathematical Society》2004,356(4):1637-1689
We consider a large class of partially hyperbolic systems containing, among others, affine maps, frame flows on negatively curved manifolds, and mostly contracting diffeomorphisms. If the rate of mixing is sufficiently high, the system satisfies many classical limit theorems of probability theory.
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We obtain asymptotic lower bounds for the spectral function of the Laplacian and for the remainder in local Weyl’s law on
manifolds. In the negatively curved case, thermodynamic formalism is applied to improve the estimates. Key ingredients of
the proof include the wave equation parametrix, a pretrace formula and the Dirichlet box principle. Our results develop and
extend the unpublished thesis of A. Karnaukh [Ka].
The first author was supported by NSERC, FQRNT, Alfred P. Sloan Foundation Fellowship and Dawson Fellowship. The second author
was supported by NSERC and FQRNT.
Received: April 2006 Revision: October 2006 Accepted: October 2006 相似文献
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Dmitry Yu. Murzin 《Reaction Kinetics and Catalysis Letters》2007,90(2):225-232
Reaction route analysis is applied to visualize reaction networks in several heterogeneous catalytic reactions. Combination
of the theory of complex reactions with the notion of catalytic cycles results in a topological representation of complex
mechanisms with the nodes comprising all possible surface species including free sites and branches indicating interconnections
between reactions. 相似文献