Nachweis und Bestimmung des Mangans sowie seine Trennung von anderen Elementen

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Thermal Neutron damage in cadmium

The isochronal annealing of the damage produced by thermal neutron irradiation of cadmium at 3.6 °K has been studied for several initial doses which vary by a factor of 1000. The recovery results show a strong dependence upon initial dose. This effect, which is not seen to this extent in the fcc metals, cannot be accounted for by an irradiation annealing mechanism. In contrast to the observation of two processes involving long range defect migration for several fcc metals only one process, at high temperatures, is discernable from isochronal annealing of Cd. The presence of another process at low temperatures is clearly established by other means. Irradiation annealing effects observed during the production of damage at high defect concentrations indicate that the spontaneous annihilation volume between the defects of a new capture event and the defects from an earlier event is 80 atomic volumes. Other results suggest that damage production and recovery mechanisms may be associated with the anisotropic nature of the cadmium hexagonal lattice.     

Arsen, Antimon und Zinn

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Stored energy recovery of irradiated copper

Abstract

The stored energy released in Stage I recovery of reactor neutron irradiated copper was measured by differential thermal analysis calorimetry for three fluences up to a maximum of 3.5 × 10¹⁸ n/cm² (E>0.1 MeV) after irradiation at temperatures of less than 10 K. The stored energy dependence upon fluence, and a tendency toward saturation, were observed. Theoretical reaction rate processes were compared directly to the experimental rates of stored energy release, and the parameters associated with the theory were compared with results from previous resistivity measurements. Good agreement was found in several parameters, but major differences with previous D + E substage results lead to the conclusion that the point defect model may not describe materials experiencing severe neutron damage. Computer studies of warmup rates were made for first and second order and for correlated recovery processes as a function of defect concentration and of external power input. First and second order processes show definite distortion in their recovery rate curves for high defect concentrations; the correlated recovery process shows a much less pronounced effect.

This investigation of stored energy used several new approaches. The use of one sample in both experimental and control roles was not unique, but the use of induced radioactivity within the sample as the heating source, and the use of computer generated theoretical stored energy release curves to analyze the data were unique.     

Jet offset, harmonic content, and warble in the flute

The effects of jet offset in the flute, directing the jet above or below the edge, were explored by two distinct means-experiments with a Boehm flute sounded by an artificial blower, and time domain simulation. Very large changes in harmonic content and dynamics were observed, changing greatly with blowing pressure. Warble, a modulation of the tone at frequencies of the order of 20 Hz, was observed both in the experiment and in the simulation. The phenomenon is explained as a beat between the frequency of a second harmonic generated by nonlinearity in the jet current and a neighboring partial sustained by jet feedback near the second mode resonance. A second type of warble, in which amplitude modulation occurs in all partials but with different phases, is yet to be explained.     

Porosity–Permeability Relations for Evolving Pore Space: A Review with a Focus on (Bio-)geochemically Altered Porous Media

Reactive transport processes in a porous medium will often both cause changes to the pore structure, via precipitation and dissolution of biomass or minerals, and be affected by these changes, via changes to the material’s porosity and permeability. An understanding of the pore structure morphology and the changes to flow parameters during these processes is critical when modeling reactive transport. Commonly applied porosity–permeability relations in simulation models on the REV scale use a power-law relation, often with slight modifications, to describe such features; they are often used for modeling the effects of mineral precipitation and/or dissolution on permeability. To predict the reduction in permeability due to biomass growth, many different and often rather complex relations have been developed and published by a variety of authors. Some authors use exponential or simplified Kozeny–Carman relations. However, many of these relations do not lead to fundamentally different predictions of permeability alteration when compared to a simple power-law relation with a suitable exponent. Exceptions to this general trend are only few of the porosity–permeability relations developed for biomass clogging; these consider a residual permeability even when the pore space is completely filled with biomass. Other exceptions are relations that consider a critical porosity at which the porous medium becomes impermeable; this is often used when modeling the effect of mineral precipitation. This review first defines the scale on which porosity–permeability relations are typically used and aims at explaining why these relations are not unique. It shows the variety of existing approaches and concludes with their essential features.     

Aspects of pedagogy supporting metacognition and self-regulation in mathematical learning of young children: evidence from an observational study

This article reports on evidence collected within a UK study concerning metacognition in young children in the 3–5-year age range within mathematical contexts. Young children were video-recorded on a number of occasions in the naturalistic context of their Foundation Stage settings and classrooms, including both nursery and reception classes. The children were engaged in mathematical activities designed by practitioners to facilitate metacognitive processes. Metacognitive ‘events’ were identified and the children’s behaviour was analysed for indications of metacognitive thinking. At the same time, the pedagogical context of the activities, including interventions by adult practitioners, was analysed in relation to the metacognitive opportunities afforded. Findings were that the young children did indeed show evidence, through their talk, and their non-verbal actions, of emergent metacognitive processes, and that the nature and frequency of these processes were influenced by pedagogical aspects of the mathematical activities. In particular, pedagogical interactions which provided children in this age range with emotionally contingent support, which gave them feelings of autonomy and control, which provided them with cognitive challenges and the opportunity to articulate their thinking appeared to provoke and support metacognitive and self-regulatory behaviours.     

Die Anwendung der Jodidmethode zur Bestimmung des Kupfers bei Gegenwart von Zinn

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