A phenomenological model of electrorheological fluids

The fundamental assumption of the paper is that the extra stress tensor of an electrorheological fluid is an isotropic tensor valued function of the rate of strain tensor D and the vector n (which characterizes the orientation and length N of the fibers formed by application of an electric field). The resulting constitutive equation for is supplemented by the solution of the previously studied time evolution equation for n. Plastic behavior for the shear and normal stresses is predicted. Anticipating that the action of increasing shear rate is i) to orient the fibers more and more in the direction of flow and ii) simultaneously to break up the fibers leads to the conclusion that for the same behavior is encountered as without an electric field. Using realistically possible approximation formulas for the dependence of and N on leads to the Bingham behavior for and power law behavior for large shear rates.

Effects of electrode morphology on the slit flow of an electrorheological fluid

In this work the effects of electrode morphology on the slit flow of an electrorheological (ER) fluid via laser Doppler anemometry (LDA) are studied. For this purpose, oblique and corrugated electrodes were used. Under a.c.-conditions the ER-effect with the oblique and corrugated electrodes is greater in comparison to the case of smooth electrodes at the same voltage and pressure drop. An average factor of 2.0 and 2.5 (in the range 1–5 kV) describes the increase in the ER-effect for the oblique and corrugated electrodes, respectively. This increase in ER-effect is accompanied by a decrease in electric current. Under d.c.-conditions the ER-effect with the oblique and corrugated electrodes is somewhat better than with the smooth electrodes but only at a very low field strength. Increasing the field strength leads to a decreased ER-effect (in comparison to the smooth electrodes). This decrease of the ER-effect is always accompanied by a decrease in electric current (d.c.-field).     

Carbanion reactivity, kinetic and equilibrium studies of sigma-adduct formation and elimination in the reactions of 4-nitrobenzofurazan derivatives with nitroalkane anions

1H NMR studies are reported of the reactions in [2H(6)]-DMSO of 4-nitrobenzofurazan, 2a, and its 7-chloro- and 7-methoxy-derivatives, 2b and 2c respectively, with anions derived from nitromethane, 3, nitroethane, 4, and 2-nitropropane, 5. The initial reactions result in sigma-adduct formation by carbanion attack at the 5-position of 2a-c and in the case of reaction of 2a with 5 the adduct at the 7-position is also observed. These reactions may be followed by base catalysed elimination of nitrous acid to yield anionic alkene derivatives. Kinetic and equilibrium measurements of these reactions were made spectrophotometrically in methanol. The carbon nucleophilicities of the carbanions decrease in the order 3> 4> 5, as also found in their reactions with benzhydrylium cations, and are much lower than the nucleophilicities of some cyano-substituted carbanions. Comparison with corresponding sigma-adduct forming reactions of 1,3,5-trinitrobenzene, TNB, show that here 2 and TNB have similar electrophilicity, although the value of the intrinsic rate coefficient k(o) = 0.05, for reaction of 2 is rather lower than that, k(o) = 0.20, for the TNB reactions. Literature data suggest that for reaction with a variety of nucleophiles 2 and TNB show similar electrophilicities. Measurements of the rates of elimination of nitrous acid from some 5-adducts in methanol catalysed by methoxide ions are reported. Values of rate constants may be influenced both by steric requirements at the reaction centre and by the electronic effects of the 7-substituent.     

Evaluation of spectral dispersion of optical constants of a-Se films from their normal-incidence transmittance spectra using Swanepoel algebraic envelope approach

Spectral dispersions of index of refraction \({n(\lambda )}\) and extinction coefficient \({\kappa (\lambda )}\) of undoped amorphous selenium (a-Se) films of three thicknesses (d?≈?0.5, 0.75, and 1.0 µm) were evaluated by analyzing experimental room-temperature normal-incidence transmittance-wavelength (\({{T_{{\text{exp}}}}(\lambda )} - \lambda\)) data (λ =?400–1100 µm) of their air-supported {a-Se film/thick glass slide}-stacks using Swanepoel’s transmission envelope theory of uniform films. Above a wavelength \({{\lambda _c}\,\, \approx \,\,640\;{\text{nm}}}\), as-measured \({{T_{{\text{exp}}}}(\lambda )}\,\, - \,\lambda\) spectra display well-resolved maxima and minima, with minor shrinkage in transparent and weak absorption regions (750–1100 nm). Below \({\lambda _{\text{c}}}\), a smeared sharp decline of \({{T_{{\text{exp}}}}(\lambda )}\) with decreasing λ, signifying strong absorption in a-Se films and existence of band-tail localized states. For λ > λ _c, the \({n\,(\lambda )}\, - \,\lambda\) data retrieved from algebraic envelope procedures followed a Sellmeier-like dispersion relation, with the best-fit values of high-frequency dielectric constant \({{\varepsilon _\infty }\, \approx \,\,{\text{4.9}}}\), static index of refraction \({{n_{\text{0}}} = n\left( {E\, \to \,{\text{0}}} \right)\,\, \approx \,\,{\text{2.43}}}\), and resonance wavelength \({{\lambda _0}\, \approx \,490\,\,{\text{nm}}}\), which may be assigned to onset of photogeneration in a-Se. Urbach-like dependency of absorption coefficient \({\alpha (h{{\nu }})}\) of a-Se films on photon energy \({h{{\nu }}}\) was realized with an Urbach-tail breadth of 85 meV. All achieved optical parameters were found to be slightly dependent on film thickness. Findings of present algebraic analysis are consistent with reported literature results obtained on the basis of other optical analytical approaches.     

1H NMR and kinetics studies of the reaction of 4-methyl, 4-bromo and 3-trifluoromethyl benzyltriflones with aromatic nitro-compounds

Rate measurements are reported for the reactions in methanol of carbanions derived from benzyltriflones, 2a–c, with 4-nitrobenzofurazan derivatives, 4a and 4b, to give anionic σ-adducts. ¹H NMR studies in DMSO-d₆ of the reaction of benzyltriflones, 2, and 4-nitrobenzofurazan, 4a, in the presence of triethylamine are consistent with products formed by the elimination of trifluoromethyl sulfinic acid from σ-adducts initially formed by carbanion attack at the 5-position of 4a. Evidence for the high steric requirements of the benzyltriflone anions come from the low value of β; the slope of the linear plot of values of log k₅ versus pK_a.     

Benchmarking of maintenance performance: a case study in two manufacturers of furniture

When profit margins of a plant are decreasing, the need forreliable and efficient maintenance policy becomes more important.Measuring maintenance performance is important for companiesto recognize whether their planned goals are achieved or not.Also, such measurements can be utilized for benchmarking, whichis one of the tools for never-ending improvement. But, theseobjectives cannot be achieved without well-documented data ofthe relevant variables. Better data coverage and quality isnecessary for following maintenance performance developmentand it would, in many cases, clarify the ambiguity concerningthe main problem in the context, namely that neither the productionnor maintenance department can show what effect maintenancehas on profitability. A more effective maintenance policy indirectly implies improvementsin product quality and manufacturing process effectiveness.Elongation of the production time, i.e. reducing the downtimedue to failures, planned replacements and repair, in additionto the improvement in the total maintenance activities, arealso some of the results that can be expected when an efficientmaintenance policy is used. Measuring and monitoring maintenanceperformance measures is required partly for detecting, and eventuallytreating as soon as possible, undesirable changes and partlyto make benchmarking with the best in the branch, which savesappreciable economic losses for companies. In this paper, a model for how to identify the measurable variables,which are needed to develop measures for monitoring maintenanceperformance behaviour systematically, is developed. Five maintenanceperformance measures are proposed and applied. An additionalmodel for systematically analysing the trend of maintenanceperformance measures, for an overall assessment of the company'ssituation, is presented. Two case studies in manufacturers offurniture are conducted to verify these models.     

Photochromism of tetrahydroindolizines. Part XIV: synthesis of cis-fixed conjugated photochromic pyridazinopyrrolo[1,2-b]isoquinolines incorporating carbon-rich linkers

New carbon-rich photochromic tetrahydroindolizines (THIs) bearing dihydroisoquinoline derivatives as heterocyclic bases (region B) have been synthesized via different chemical and photochemical pathways. Three alternative pathways for the synthesis of the target photochromic THI-based pyridazinopyrrolo[1,2-b]isoquinolines via in situ trapping with hydrazine hydrate have been established. In order to obtain high product yields, different Sonogashira-mediated coupling reactions have been optimized. Low temperature multichannel UV–vis and flash photolysis techniques were used to detect the photochromic and kinetic properties of the synthesized system.     

Quantum dot semiconductor laser with optoelectronic feedback

The optoelectronic feedback (OEF) in quantum dot semiconductor lasers (QD SLs) is studied theoretically where a model includes wetting layer ground state and excited state for QDs are included separating electrons and holes in their dynamics. Both positive and negative OEF are studied. The time series of photon density, the phase portraits of carriers in the states are studied. The parameters affecting OEF are examined where an excitability is seen. The QD SL is found to be more sensitive to the changes in time delay compared with other SLs and a complicated routs are seen in the behavior of QD SL.     

Role of interaction forces in controlling the stability and polishing performance of CMP slurries

Chemical mechanical polishing (CMP) is an essential step in metal and dielectric planarization in multilayer microelectronic device fabrication. In the CMP process it is necessary to minimize the extent of surface defect formation while maintaining good planarity and optimal material removal rates. These requirements are met through the control of chemical and mechanical interactions during the polishing process by engineering the slurry chemistry, particulate properties, and stability. In this study, the performance of surfactant-stabilized silica CMP slurries at high pH and high ionic strengths are investigated with particular emphasis on the particle-particle and particle-substrate interactions. It is shown that for the design of consistently high performing slurries, stability of abrasive particles must be achieved under the dynamic processing conditions of CMP while maintaining sufficient pad-particle-wafer interactions.     

Rate-limiting proton-transfer in the sigma-adduct forming reactions of 1,3,5-trinitrobenzene and 4-nitrobenzofuroxan with substituted anilines in dimethyl sulfoxide

Kinetic and equilibrium results are compared for the reactions in dimethyl sulfoxide of 1,3,5-trinitrobenzene, 1, and 4-nitrobenzofuroxan, 4, with a series of substituted anilines in the presence of Dabco or in, some cases, quinuclidine. pKa values for the corresponding anilinium ions are reported. The reactions of 1and 4 are likely to proceed through nucleophilic attack by the aniline to yield zwitterionic intermediates which may transfer an acidic proton to the bases present to yield the anionic adducts 9 or 12 respectively. In the formation of 9 from 1 the proton transfer step is rate-limiting; however, the slower interconversion of 4 and its zwitterion leads to only partial rate-limiting proton transfer in the formation of 12. Results with substituted anilines including 2-substituted and N-methyl aniline indicate that steric effects are not a major factor in determining rates of proton-transfer in these systems. Contrary to previous reports no evidence was found for a strong interaction between 1 and Dabco in DMSO.