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1.
Mahboobeh Behnam Dehkordi Majid M. Heravi Parviz Khosrofar Ahmad Ziafat Mitra Ghassemzadeh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):2595-2598
Hexamethylenetetramine-bromine supported onto[3pc] silica gel rapidly converts trimethylsilyl ethers to their corresponding carbonyl compounds under microwave irradiation in solventless system. 相似文献
2.
Aurica Farcas Giulia Tregnago Ana‐Maria Resmerita Sarah Taleb Dehkordi Sophie Cantin Fabrice Goubard Pierre‐Henri Aubert Franco Cacialli 《Journal of polymer science. Part A, Polymer chemistry》2014,52(4):460-471
The photophysical properties of two polyrotaxanes ( PFBTh?PSβCD and PFBTh?PMeβCD ) composed of fluorene and bithiophene encapsulated into permodified β‐cyclodextrin cavities have been investigated and compared with those of the reference PFBTh . Rotaxane formation results in improvements of the thermal stability, solubility in common organic solvents, as well as better film forming ability combined with a high transparency. As expected PFBTh and its encapsulated forms absorb at wavelengths beyond 510 nm, and time‐resolved photoluminescence (PL) in solution shows a well‐define vibronic structures with a predominance of the 0‐0 transitions and an energy difference of 0.16 eV. The fluorescence lifetimes follow a monoexponential decay with a value τ = 630 ± 30 ps. Atomic force microscopy, AFM, indicated a tendency of polyrotaxanes to organize into fibers. The advancing contact angles indicated higher surface hydrophobicity and lower surface free‐energy values for polyrotaxanes compared with their unthreaded analogues. The device based on PFBTh?PSβCD: PCBM in a 1/1 w/w ratio under simulated AM 1.5G illumination at 100 mW cm?2 exhibited improved photovoltaic parameters of cells, resulted in high Voc (0.68 V), Jsc (1.65 mA cm?2), FF (31.6%), and PCE (0.35) values, compared with PFBTh or PFBTh?PMeβCD , respectively. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 460–471 相似文献
3.
A. Babakhani 《Journal of Mathematical Analysis and Applications》2003,278(2):434-442
Existence of positive solutions for the nonlinear fractional differential equation Dsu(x)=f(x,u(x)), 0<s<1, has been studied (S. Zhang, J. Math. Anal. Appl. 252 (2000) 804-812), where Ds denotes Riemann-Liouville fractional derivative. In the present work we study existence of positive solutions in case of the nonlinear fractional differential equation:
L(D)u=f(x,u),u(0)=0,0<x<1, 相似文献
4.
S. Nobakhtian A. Raeisi Dehkordi 《4OR: A Quarterly Journal of Operations Research》2018,16(4):343-377
In this paper, we consider a multi-source Weber problem of m new facilities with respect to n demand regions in order to minimize the sum of the transportation costs between these facilities and the demand regions. We find a point on the border of each demand region from which the facilities serve the demand regions at these points. We present an algorithm including a location phase and an allocation phase in each iteration for solving this problem. An algorithm is also proposed for carrying out the location phase. Moreover, global convergence of the new algorithm is proved under mild assumptions, and some numerical results are presented. 相似文献
5.
Dehkordi S. Saeid Saei Albadi Jalal Jafari Abbas Ali Samimi Heshmat Allah 《Research on Chemical Intermediates》2021,47(6):2527-2538
A copper-based magnetic nanocatalyst has been prepared by co-precipitation method and characterized by FESEM, EDS, TEM, XRD, XRF, ICP–OES, FTIR, and BET analysis. This new nanocatalyst displays a good activity toward the aerobic oxidation of a wide range of alcohols in water. Moreover, it is recyclable up to five following runs by simple filtration without any significant loss of its catalytic activity.
相似文献6.
Babakhani A Gorfe AA Kim JE McCammon JA 《The journal of physical chemistry. B》2008,112(34):10528-10534
A variety of biomolecules mediate physiological processes by inserting and reorganizing in cell membranes, and the thermodynamic forces responsible for their partitioning are of great interest. Recent experiments provided valuable data on the free energy changes associated with the transfer of individual amino acids from water to membrane. However, a complete picture of the pathways and the associated changes in energy of peptide insertion into a membrane remains elusive. To this end, computational techniques supplement the experimental data with atomic-level details and shed light on the energetics of insertion. Here, we employed the technique of umbrella sampling in a total 850 ns of all-atom molecular dynamics simulations to study the free energy profile and the pathway of insertion of a model hexapeptide consisting of a tryptophan and five leucines (WL5). The computed free energy profile of the peptide as it travels from bulk solvent through the membrane core exhibits two minima: a local minimum at the water-membrane interface or the headgroup region and a global minimum at the hydrophobic-hydrophilic interface close to the lipid glycerol region. A rather small barrier of roughly 1 kcal mol (-1) exists at the membrane core, which is explained by the enhanced flexibility of the peptide when deeply inserted. Combining our results with those in the literature, we present a thermodynamic model for peptide insertion and aggregation which involves peptide aggregation upon contact with the membrane at the solvent-lipid headgroup interface. 相似文献
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Ras GTPases become functionally active when anchored to membranes by inserting their lipid modified side chains. Their role in cell division, development, and cancer has made them targets of extensive research efforts, yet the mechanism of membrane insertion and the structure of the resulting complex remain elusive. Recently, the structure of the full-length H-ras protein in a DMPC bilayer has been computationally characterized. Here, the atomic interactions between the H-ras membrane anchor and the DMPC bilayer are investigated in detail. We find that the palmitoylated cysteines and Met182 have dual contributions to membrane affinity: hydrogen bonding by their amides and van der Waals interaction by their hydrophobic side chains. The polar side chains help maintain the orientation of the anchor. Although the overall structure of the bilayer is similar to that of a pure DMPC, there are localized perturbations. These perturbations depend on the insertion depth and backbone localization of the anchor, which in turn is modulated by the catalytic domain and the linker. The pattern of anchor amide-DMPC phosphate/carbonyl hydrogen bonds and the flexibility of Palm184 are important in discriminating between different modes of ras-DMPC interactions. The results provide structural arguments in support of the proposed participation of ras in the organization of membrane nanoclusters. 相似文献
9.
Stochastic convexity and its applications are very important in mathematics and probability (Aequationes Mathematicae 20:184–197, 1980). There are two well-known inequalities for convex stochastic processes: Jensen’s inequality and Hermite–Hadamard’s inequality. Recently, Hafiz (Stoch Anal Appl 22:507–523, 2004) has provided fractional calculus for some stochastic processes. The problem is how to formulate these inequalities for stochastic processes in the class of fractional calculus and that is what is done in this paper. Our results generalize the corresponding ones in the literature. 相似文献
10.
In this paper, we deal with determining the exact values for the complexity of the five graph access structures on six participants, which remained as open problems in van Dijk’s paper (Des Codes Cryptogr 6:143–169, 1995). We prove that the complexity for each of the five graph access structures is equal to 7/4. 相似文献