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排序方式: 共有699条查询结果,搜索用时 15 毫秒
1.
M. A. Katkova V. A. Ilichev A. N. Konev M. N. Bochkarev 《Russian Chemical Bulletin》2008,57(11):2281-2284
Rare-earth metal 8-hydroxyquinolinates (q) were studied as emission layers for organic light-emitting diodes. Compounds Dyq3, Tbq3, and Smq3 possess weak electroluminescence due to the emission of the ligand, and the electroluminescence of Hoq3, Tmq3, and Ybq3 is due to electronic transitions of the lanthanide ion. The best electroluminescence characteristics were demonstrated by
Scq3 and Yq3. The power efficiency of the organic light emitter based on ITO/TPD/Scq3/Yb (ITO is tin-alloyed indium oxide, TPD is N,N′-bis(3-methylphenyl)-N,N′-diphenylbenzidine) is 2.6 lm W−1 at a luminance of the device of 300 cd m−2. 相似文献
2.
This paper considers the estimation problem for a trigonometric regression model with the noise specified by the Ornstein–Uhlenbeck
process with unknown parameter. We propose a sequential procedure which ensures a prescribed mean square precision uniformly
in the nuisance parameter. The asymptotic behaviour of the procedure duration mean has been studied.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
3.
Alexei Yu. Lukin Sergei V. Shevyakov Alexei V. Laptev Olga I. Davydova Vitali I. Shvets Olga V. Demina Yury P. Strokach Valery A. Barachevsky Michail V. Alfimov Sergei P. Gromov Artem I. Vedernikov Johan Lugtenburg Andrey A. Khodonov 《Journal of inclusion phenomena and macrocyclic chemistry》2004,49(1-2):153-161
An effective synthetic approach to the preparation of a new crown-ether vinylogs involving the Horner–Emmons olefination of carbonyl precursors with the use of C2- and C5-phosphonates was proposed. The effects of the conjugation chain length and the nature of the terminal polar functions in the phosphonate reagent on the yield and process stereoselectivity were discussed. 相似文献
4.
In contrast to the classical method where a single molecule is designed to extract metal cations under specific conditions, dynamic covalent chemistry provides an approach based on the implementation of an adaptive dynamic covalent library for inducing the generation of the extractant species. This approach has been applied to the liquid–liquid extraction of copper(ii) nitrate based on a dynamic library of acylhydrazones constituents that self-build and distribute through the interface of a biphasic system. The addition of copper(ii) cations to this library triggers a modification of its composition and the up-regulation of the ligand molecules driven by coordination to the metal cations. Among these, one species has proven to be sufficiently lipophilic to play the role of carrier agent and its formation by component exchange enables the partial extraction of the copper(ii). The study of different pathways to generate the dynamic covalent library demonstrates the complete reversibility and the adaptability of the system. The detailed analytical investigation of the system provides a means to assess the mechanism of the dynamic extraction process.Phase transfer of Cu(ii) cations is achieved by component exchange in a dynamic covalent library of acylhydrazone ligands. B1/B2 component exchange leads to the generation of a lipophilic carrier agent that extracts Cu(ii) into chloroform. 相似文献
5.
Artem Malakho Marc Dussauze Bogdan Lazoryak Frederic Adamietz 《Journal of solid state chemistry》2005,178(6):1888-1897
Crystallization of glasses with compositions (1−x)(0.95 NaPO3+0.05 Na2B4O7)+xNb2O5, x=0.4, 0.43, 0.45, 0.48 was investigated by differential scanning calorimetry and X-ray powder diffraction. Crystallization of two phases was observed in the glasses with x=0.43-0.48. First phase is a sodium niobate with the structure of tetragonal tungsten bronze () and second phase is Na4Nb8P4O32 (). The crystallization of sodium niobate is correlated with increasing of nonlinear optical efficiency reported for thermally poled glasses with x>0.4. The results of Raman spectroscopy show the formation of three-dimensional (3D) niobium oxide framework in the glasses with increase of niobium concentration. This framework is supposed to have tetragonal tungsten bronze structure and to be responsible for nonlinear optical properties of the glass. Second harmonic generation signals of as prepared and crystallized glass after thermal poling are compared. The nucleation and crystallization do not improve the NLO properties of the glasses under study. 相似文献
6.
Unimolecular phototautomeric reactions in 4-thiouracil, 1-methyl-4-thiouracil and 6-aza-4-thiouracil were studied using the matrix-isolation technique combined with infrared absorption spectroscopy. For monomers of these compounds, isolated in solid argon at 10 K, an intramolecular proton-transfer photoreaction was observed. Upon UV (lambda > 345 nm) irradiation, the initial oxo-thione forms of 4-thiouracils were converted into the corresponding oxo-thiol tautomers. The photogenerated oxo-thiol isomers were identified by comparing their experimental IR spectra with the spectra theoretically calculated at the DFT(B3LYP)/6-311++G(2d,p) level. Good agreement between the observed and predicted pattern of spectral bands allowed a reliable identification. This is the first report on experimental observation of isomeric forms of 4-thiouracils other than the canonical oxo-thione tautomers. 相似文献
7.
8.
Acylation through Ketene Intermediates 总被引:1,自引:0,他引:1
Carboxylic acids possessing a strong electron-withdrawing group in the alpha-position undergo facile dehydration upon reaction with carbodiimides to form the corresponding substituted ketenes that can react in situ with alcohols providing esters in a high yield. The ketene formed by the treatment of ethyl 2-methylmalonate with DCC was trapped in situ by a [4+2] cycloaddition with a second DCC molecule. The chemoselectivity of the acylation through the ketene intermediates was found to be substantially different from that of conventional acylation reagents showing a very low sensitivity toward the steric bulk of alcohols. A comparison of the sensitivity of the acylation to the steric bulk of alcohols supports the presence of a pseudopericyclic pathway for the nucleophilic addition of alcohols to ketenes derived from ethyl malonic and diethylphosphonoacetic acid. 相似文献
9.
D. V. Konev T. A. Kravchenko A. I. Kalinichev V. A. Krysanov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2007,81(2):259-264
The paper presents a physicochemical model of the redox sorption of molecular oxygen from water by a metal-containing electron-ion exchanger. The model takes into account the dispersity of metal particles, the special features of their chemical oxidation, and interrelation between the total process rate and the properties of the ion-exchange matrix. This model was used to formulate the problem mathematically, obtain a numerical solution, and theoretically analyze it as depending on the main parameters of the sorption system. A criterion was introduced for estimating the contributions of the diffusion and kinetic stages taking into account the dispersity of metal particles. 相似文献
10.
Artem S. Agarkov Anna A. Nefedova Elina R. Gabitova Alexander S. Ovsyannikov Syumbelya K. Amerhanova Anna P. Lyubina Alexandra D. Voloshina Pavel V. Dorovatovskii Igor A. Litvinov Svetlana E. Solovieva Igor S. Antipin 《Molecules (Basel, Switzerland)》2022,27(22)
A series of new thiazolo[3,2-a]pyrimidines different by aryl substituents in 2 and 5 positions are synthesized and characterized in solution as well as in the crystalline phase using 1H and 13C NMR-, IR-spectroscopies, mass-spectrometry methods, and single crystal X-ray diffraction (SCXRD). The SCXRD study revealed the role of intermolecular H-bonding in the formation of supramolecular architectures (racemic monomers, centrosymmetric racematic dimers, or homochiral 1D chains) of obtained thiazolo[3,2-a]pyrimidines derivatives depending on solvents (aprotic DMSO or protic EtOH) used upon the crystallization process. Moreover, the in vitro study of cytotoxicity toward different tumor cells showed their high or moderate efficiency with moderate cytotoxicity against normal liver cells which allows to consider the obtained thiazolo[3,2-a]pyrimidine derivatives as promising candidates for application as antitumor agents. 相似文献